Microstructural characterisation and corrosion behaviour of laser cladded Al–12Si alloy onto magnesium AS41/carbon fibre composite

Abstract The quality and properties of laser clad layers are dependent on the microstructure and properties of the interfaces with the substrate. The present paper reports, in details, on the characterisation of microstructure of the coating and interfacial layers evolved as a result of the CO2 laser remelting of previously plasma sprayed Al–12Si alloy onto C short fibres reinforced AS41–Mg composite. Scanning electron microscopy (SEM), wavelength dispersive X-ray (WDX) analysis and X-ray diffraction (XRD) were employed to identify the phases arising in the interfacial layers. The latter are composed mainly of Mg17Al12 and Mg2Si phases. XRD was conducted on the clad layers at different distances from the interface. At the same layers, the potentiodynamic polarisation in sodium chloride solution was measured and it was found that as the Mg content increases in the clad coating, the corrosion resistance decreases. However, the corrosion current of the clad coating is around two orders of magnitude lower than that of the C/Mg composite.

[1]  B. Mordike,et al.  Microstructure and corrosion properties of laser clads of magnesium base alloys for laser generated cylinder liners , 2002 .

[2]  T. Yue,et al.  Improvement of the corrosion resistance of magnesium ZM51/SiC composite by laser cladding , 2001 .

[3]  T. M. Yue,et al.  YAG laser cladding of an Al-Si alloy onto an Mg/SiC composite for the improvement of corrosion resistance , 2001 .

[4]  P. Lukáč,et al.  Interfaces in magnesium‐based composites , 2001 .

[5]  T. Yue,et al.  Laser cladding of stainless steel on magnesium ZK60/SiC composite , 2001 .

[6]  T. Yue,et al.  Corrosion resistance enhancement of magnesium ZK60/SiC composite by Nd:YAG laser cladding , 1999 .

[7]  J. Mazumder,et al.  Laser cladding of Mg-Al alloys , 1993, Journal of Materials Science.

[8]  J. Mazumder,et al.  Laser cladding of zirconium on magnesium for improved corrosion properties , 1991, Journal of Materials Science.

[9]  W. Ferrando Review of corrosion and corrosion control of magnesium alloys and composites , 1989 .

[10]  M. A. Taher,et al.  Profiling of structural members using shadow speckle metrology , 1988 .

[11]  R. Ovarfort,et al.  New electrochemical cell for pitting corrosion testing , 1988 .

[12]  I. W. Hall Corrosion of carbon/magnesium metal matrix composites , 1987 .

[13]  P. Trzaskoma Corrosion Behavior of a Graphite Fiber/Magnesium Metal Matrix Composite in Aqueous Chloride Solution , 1986 .

[14]  R. Stephenson A and V , 1962, The British journal of ophthalmology.