Reference Correlation of the Thermal Conductivity of Methanol from the Triple Point to 660 K and up to 245 MPa

This paper contains new, representative reference equations for the thermal conductivity of methanol. The equations are based in part upon a body of experimental data that has been critically assessed for internal consistency and for agreement with theory whenever possible. In the case of the dilute-gas thermal conductivity, a theoretically based correlation was adopted in order to extend the temperature range of the experimental data. Moreover, in the critical region, the experimentally observed enhancement of the thermal conductivity is well represented by theoretically based equations containing just one adjustable parameter. The correlation is applicable for the temperature range from the triple point to 660 K and pressures up to 245 MPa. The overall uncertainty (at the 95% confidence level) of the correlation over its range of applicability for the liquid and supercritical phases, excluding the critical region, is estimated to be less than 4.4%. The dilute gas region has an estimated uncertainty of 3...

[1]  D. Coombe,et al.  Some simplified expressions for the thermal conductivity in an external field , 1979 .

[2]  Marcia L. Huber,et al.  Reference Correlation of the Thermal Conductivity of Toluene from the Triple Point to 1000 K and up to 1000 MPa , 2013 .

[3]  Guoqiang Cai,et al.  Thermal conductivity of alcohols with acetonitrile and N,N-dimethylformamide , 1993 .

[4]  E.F.M. Van Der Held,et al.  A method of measuring the thermal conductivity of liquids , 1949 .

[5]  E. F. Johnson,et al.  Thermal Conductivities of Liquids at High Temperatures. , 1961 .

[6]  J. Happe,et al.  The Thermal Conductivities of Some Liquid Nitrate Esters , 1957 .

[7]  L. Riedel.  Wärmeleitfähigkeitsmessungen an Mischungen verschiedener organischer Verbindungen mit Wasser , 1951 .

[8]  H. Poltz.  Die wärmeleitfähigkeit von flüssigkeiten III: Abhängigkeit der wärmeleitfähigkeit von der schichtdicke bei organischen flüssigkeiten , 1965 .

[9]  B. C. Sakiadis,et al.  Studies of thermal conductivity of liquids. Part I , 1955 .

[10]  Rg Vines,et al.  The Thermal Conductivity of Organic Vapours: The Influence of Molecular Interaction , 1953 .

[11]  Marc J. Assael,et al.  New International Formulation for the Thermal Conductivity of H2O , 2012 .

[12]  O. B. Cecil,et al.  Thermal conductivity of some organic liquids , 1956 .

[13]  V. Vesovic,et al.  Thermophysical Properties of Dilute Hydrogen Sulfide Gas , 2012 .

[14]  W. Wakeham,et al.  On the validity of the simplified expression for the thermal conductivity of Thijsse et al. , 1988 .

[15]  H. Xiang,et al.  A New Reference Correlation for the Viscosity of Methanol , 2006 .

[16]  W. Jobst.  Measurement of thermal conductivities of organic aliphatic liquids by an absolute unsteady-state method , 1964 .

[17]  M. Blander,et al.  A study of hydrogen bonding in methanol vapor by measurement of thermal conductivity , 1977 .

[18]  F. W. Dittman,et al.  Thermal Properties of GR-S Latices , 1949 .

[19]  C. Lees.  On the thermal conductivities of single and mixed solids and liquids, and their variation with temperature , 1898, Proceedings of the Royal Society of London.

[20]  E. Vogel,et al.  The initial density dependence of the viscosity of organic vapours: Benzene and methanol , 1986 .

[21]  V. Vesovic,et al.  Calculation of the transport properties of carbon dioxide. II. Thermal conductivity and thermomagnetic effects. , 2004, The Journal of chemical physics.

[22]  N. Hirota,et al.  Thermal diffusivities and sound velocities of supercritical methanol and ethanol measured by the transient grating method , 2001 .

[23]  H. Preston‐Thomas,et al.  The International Temperature Scale of 1990 (ITS-90) , 1990 .

[24]  L. Curtiss,et al.  Thermal conductivity measurements and molecular association in a series of alcohol vapors: Methanol, ethanol, isopropanol, and t-butanol , 1981 .

[25]  V. Vesovic,et al.  Calculation of the transport and relaxation properties of methane. II. Thermal conductivity, thermomagnetic effects, volume viscosity, and nuclear-spin relaxation. , 2009, The Journal of chemical physics.

[26]  J. Raal,et al.  Measurement of alcohol thermal conductivities using a relative strain-compensated hot-wire method , 1981 .

[27]  V. Vesovic,et al.  Ab initio intermolecular potential energy surface and thermophysical properties of hydrogen sulfide. , 2011, Physical chemistry chemical physics : PCCP.

[28]  G. M. Mallan,et al.  Liquid thermal conductivities of organic compounds and petroleum fractions , 1972 .

[29]  M. Fujii,et al.  Simultaneous measurements of thermal conductivity and thermal diffusivity of liquids under microgravity conditions , 1997 .

[30]  Sengers,et al.  Crossover from singular to regular behavior of the transport properties of fluids in the critical region. , 1988, Physical review letters.

[31]  J. D. Lambert,et al.  Thermal conductivities of organic vapours , 1950, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[32]  F. Cruickshank,et al.  The thermal diffusivity and thermal conductivity coefficient of methanol vapour , 1987 .

[33]  H. Berg,et al.  The thermal conductivity of ethane in the critical region , 1989 .

[34]  D. Friend,et al.  The thermal conductivity and heat capacity of fluid nitrogen , 1991 .

[35]  F. Gasser,et al.  Measurement of thermal properties of liquids with an AC heated-wire technique , 1981 .

[36]  Marc J. Assael,et al.  Reference Correlation of the Thermal Conductivity of Benzene from the Triple Point to 725 K and up to 500 MPa , 2012 .

[37]  W. Wakeham,et al.  The Transport Properties of Carbon Dioxide , 1990 .

[38]  Jan V. Sengers,et al.  A simplified representation for the thermal conductivity of fluids in the critical region , 1989 .

[39]  I. Abdulagatov,et al.  Simplified Model for the Critical Thermal-Conductivity Enhancement in Molecular Fluids , 2013, International Journal of Thermophysics.

[40]  Marc J. Assael,et al.  Absolute measurements of the thermal conductivity of alcohols by the transient hot-wire technique , 1988 .

[41]  Marcia L. Huber,et al.  Correlation of the Thermal Conductivity of Normal and Parahydrogen from the Triple Point to 1000 K and up to 100 MPaa) , 2011 .

[42]  E. Schlünder.  Messung der Wärmeleitfähigkeit von Gas/Dampf-Gemischen mit einem Kurzzeitverfahren , 1964 .

[43]  L. Bennett,et al.  The Thermal Conductivity of Organic Vapors. The Relationship between Thermal Conductivity and Viscosity, and the Significance of the Eucken Factor , 1954 .

[44]  A. Nagashima,et al.  Measurement of the Thermal Conductivity of Liquids by Transient Hot-Wire Method : I : Measurement at Atmospheric Pressure , 1978 .

[45]  P. W. Bridgman.  The Thermal Conductivity of Liquids under Pressure , 1923 .

[46]  W. Fritz,et al.  Absolutbestimmung der wärmeleitfähigkeit von flüssigkeiten—I: Kritische versuche an einer neuen plattenapparatur , 1962 .

[47]  Marc J. Assael,et al.  Benzene: A Further Liquid Thermal Conductivity Standard , 1990 .

[48]  M. Yang,et al.  A new calorimeter for measuring rapidly the thermal conductivity of liquids , 1995 .

[49]  I. Abdulagatov,et al.  High-temperature and high-pressure experimental thermal conductivity for the pure methanol and binary systems methanol + n-propanol, methanol + n-octanol, and methanol + n-undecanol , 2004 .

[50]  F. G. Keyes.  Thermal Conductivity of Gases , 1954, Journal of Fluids Engineering.

[51]  Ilmutdin M. Abdulagatov,et al.  Reference Correlation of the Thermal Conductivity of Sulfur Hexafluoride from the Triple Point to 1000 K and up to 150 MPa , 2012 .