A microporous lanthanide-tricarboxylate framework with the potential for purification of natural gas.

A novel robust three-dimensional lanthanide organic framework with high thermal stability has been demonstrated to exhibit the potential for purification of natural gas in nearly pure form from an 8-component gas mixture at room temperature.

[1]  Rajamani Krishna,et al.  Metal–organic frameworks with potential for energy-efficient adsorptive separation of light hydrocarbons , 2012 .

[2]  P. Falcaro,et al.  Doping light emitters into metal-organic frameworks. , 2012, Angewandte Chemie.

[3]  R. Krishna,et al.  Cu-TDPAT, an rht-type dual-functional metal-organic framework offering significant potential for use in H2 and natural gas purification processes operating at high pressures , 2012 .

[4]  Rajamani Krishna,et al.  A robust doubly interpenetrated metal-organic framework constructed from a novel aromatic tricarboxylate for highly selective separation of small hydrocarbons. , 2012, Chemical communications.

[5]  Rajamani Krishna,et al.  Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites , 2012, Science.

[6]  Mian Li,et al.  High-spin versus spin-crossover versus low-spin: geometry intervention in cooperativity in a 3D polymorphic iron(II)-tetrazole MOFs system. , 2012, Chemical communications.

[7]  Rajamani Krishna,et al.  A comparison of the CO2 capture characteristics of zeolites and metal-organic frameworks , 2012 .

[8]  Zhiyong Guo,et al.  A luminescent mixed-lanthanide metal-organic framework thermometer. , 2012, Journal of the American Chemical Society.

[9]  Rajamani Krishna,et al.  High separation capacity and selectivity of C2 hydrocarbons over methane within a microporous metal-organic framework at room temperature. , 2012, Chemistry.

[10]  Michael O'Keeffe,et al.  Deconstructing the crystal structures of metal-organic frameworks and related materials into their underlying nets. , 2012, Chemical reviews.

[11]  Yanfeng Yue,et al.  Luminescent functional metal-organic frameworks. , 2012, Chemical Reviews.

[12]  R. Krishna,et al.  A microporous metal-organic framework for highly selective separation of acetylene, ethylene, and ethane from methane at room temperature. , 2012, Chemistry.

[13]  T. Golden,et al.  Binary adsorption behaviour of methane and nitrogen gases , 2012, Journal of Porous Materials.

[14]  R. Krishna,et al.  MaxwellStefan modeling of slowing-down effects in mixed gas permeation across porous membranes , 2011 .

[15]  Linhua Xie,et al.  Crystallographic studies into the role of exposed rare earth metal ion for guest sorption , 2011 .

[16]  R. Krishna,et al.  Investigating the potential of MgMOF-74 membranes for CO2 capture , 2011 .

[17]  G. Qian,et al.  A new approach to construct a doubly interpenetrated microporous metal-organic framework of primitive cubic net for highly selective sorption of small hydrocarbon molecules. , 2011, Chemistry.

[18]  Rajamani Krishna,et al.  Screening metal–organic frameworks by analysis of transient breakthrough of gas mixtures in a fixed bed adsorber , 2011 .

[19]  R. Krishna,et al.  In silico screening of metal-organic frameworks in separation applications. , 2011, Physical chemistry chemical physics : PCCP.

[20]  Rajamani Krishna,et al.  Metal-organic frameworks as adsorbents for hydrogen purification and precombustion carbon dioxide capture. , 2011, Journal of the American Chemical Society.

[21]  K. Thomas,et al.  Rationally tuned micropores within enantiopure metal-organic frameworks for highly selective separation of acetylene and ethylene. , 2011, Nature communications.

[22]  Qiang Xu,et al.  A series of (6,6)-connected porous lanthanide−organic framework enantiomers with high thermostability and exposed metal sites: scalable syntheses, structures, and sorption properties. , 2010, Inorganic chemistry.

[23]  Guodong Qian,et al.  Metal-organic frameworks with functional pores for recognition of small molecules. , 2010, Accounts of chemical research.

[24]  M. O'keeffe,et al.  The Reticular Chemistry Structure Resource (RCSR) database of, and symbols for, crystal nets. , 2008, Accounts of chemical research.

[25]  Hong‐Cai Zhou,et al.  A coordinatively linked Yb metal-organic framework demonstrates high thermal stability and uncommon gas-adsorption selectivity. , 2008, Angewandte Chemie.

[26]  Young Kwan Park,et al.  Crystal structure and guest uptake of a mesoporous metal-organic framework containing cages of 3.9 and 4.7 nm in diameter. , 2007, Angewandte Chemie.

[27]  C. Cahill,et al.  An unusually high thermal stability within a novel lanthanide 1,3,5-cyclohexanetricarboxylate framework: synthesis, structure, and thermal data. , 2006, Chemical communications.

[28]  A. Blake,et al.  Triggered ligand release coupled to framework rearrangement: generating crystalline porous coordination materials. , 2006, Inorganic chemistry.

[29]  C. Serre,et al.  MIL-103, a 3-D lanthanide-based metal organic framework with large one-dimensional tunnels and a high surface area. , 2005, Journal of the American Chemical Society.

[30]  Tapas Kumar Maji,et al.  Porous lanthanide-organic framework with zeolite-like topology. , 2005, Chemical communications.

[31]  M. Eddaoudi,et al.  Rod packings and metal-organic frameworks constructed from rod-shaped secondary building units. , 2005, Journal of the American Chemical Society.

[32]  Kristie M. Adams,et al.  Porous lanthanide-organic frameworks: synthesis, characterization, and unprecedented gas adsorption properties. , 2003, Journal of the American Chemical Society.

[33]  Anthony L. Spek,et al.  Journal of , 1993 .

[34]  Reineke,et al.  A Microporous Lanthanide-Organic Framework. , 1999, Angewandte Chemie.

[35]  Alan L. Myers,et al.  Thermodynamics of mixed‐gas adsorption , 1965 .