Emerging Perovskite Nanocrystals-Enhanced Solid-State Lighting and Liquid-Crystal Displays

Recent advances in perovskite nanocrystals-enhanced solid-state lighting (SSL) and liquid-crystal displays (LCDs) are reviewed. We first discuss the development, optical properties, and stability issue of materials, and then we evaluate the performance of SSL and LCDs with perovskite downconverters adopted. In SSL performance evaluation, we investigate the fitting-curve effect in calculations and optimizations where simple Gaussian fitting and precise fitting are compared in detail, and we further optimize for highly efficient, good color-rendering, and human-healthy SSL sources. For LCD performance evaluation, we study the intrinsic tradeoffs between total light efficiency and color gamut coverage. Through optimizations using real line shapes, Rec. 2020 standard coverage as large as 92.8% can be achieved through hybrid integration. Finally, we briefly discuss two future challenges: materials development and device integration. We believe the emerging perovskite nanocrystals are highly promising for next-generation SSL and LCDs.

[1]  F. Giustino,et al.  Toward Lead-Free Perovskite Solar Cells , 2016 .

[2]  Felix Deschler,et al.  Bright light-emitting diodes based on organometal halide perovskite. , 2014, Nature nanotechnology.

[3]  Takamitsu Okumura,et al.  Highly-efficient backlight for liquid crystal display having no optical films , 2003 .

[4]  Wiep Folkerts 41.3: Invited Paper: LED Backlighting Concepts with High Flux LEDs , 2004 .

[5]  Shin-Tson Wu,et al.  Emerging Quantum-Dots-Enhanced LCDs , 2014, Journal of Display Technology.

[6]  Meng-Che Tsai,et al.  Organometal halide perovskite solar cells: degradation and stability , 2016 .

[7]  Jeffrey Y. Tsao,et al.  Limits on the maximum attainable efficiency for solid-state lighting , 2007, SPIE/COS Photonics Asia.

[8]  Shin-Tson Wu,et al.  Hybrid downconverters with green perovskite-polymer composite films for wide color gamut displays. , 2017, Optics express.

[9]  Qingfeng Dong,et al.  Highly narrowband perovskite single-crystal photodetectors enabled by surface-charge recombination , 2015, Nature Photonics.

[10]  Munisamy Anandan Progress of LED backlights for LCDs , 2008 .

[11]  S. M. Pauley Lighting for the human circadian clock: recent research indicates that lighting has become a public health issue. , 2004, Medical hypotheses.

[12]  Yoshihiro Ohno,et al.  Color quality scale , 2010 .

[13]  Feng Gao,et al.  Colloidal metal halide perovskite nanocrystals: synthesis, characterization, and applications , 2016 .

[14]  Karin Dipl.-Ing. Bieske,et al.  Definition and measurement of circadian radiometric quantities , 2006 .

[15]  L. Etgar,et al.  Two Dimensional Organometal Halide Perovskite Nanorods with Tunable Optical Properties. , 2016, Nano letters.

[16]  X. Ren,et al.  20‐mm‐Large Single‐Crystalline Formamidinium‐Perovskite Wafer for Mass Production of Integrated Photodetectors , 2016 .

[17]  Oleg B. Shchekin,et al.  Toward commercial realization of quantum dot based white light-emitting diodes for general illumination , 2017 .

[18]  H. Snaith Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells , 2013 .

[19]  Christopher H. Hendon,et al.  Nanocrystals of Cesium Lead Halide Perovskites (CsPbX3, X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut , 2015, Nano letters.

[20]  K. Kimoto,et al.  Characterization and properties of green-emitting β-SiAlON:Eu2+ powder phosphors for white light-emitting diodes , 2005 .

[21]  Guanjun Tan,et al.  Enlarging the color gamut of liquid crystal displays with a functional reflective polarizer. , 2017, Optics express.

[22]  Shin-Tson Wu,et al.  Recent Advances on Quantum-Dot-Enhanced Liquid-Crystal Displays , 2017, IEEE Journal of Selected Topics in Quantum Electronics.

[23]  Yukihiro Nishida,et al.  Design of Primaries for a Wide-Gamut Television Colorimetry , 2010, IEEE Transactions on Broadcasting.

[24]  J. Y. Tsao,et al.  LEDs for photons, physiology and food , 2018, Nature.

[25]  Haibo Zeng,et al.  Amino‐Mediated Anchoring Perovskite Quantum Dots for Stable and Low‐Threshold Random Lasing , 2017, Advanced materials.

[26]  Tsunemasa Taguchi Present Status of Energy Saving Technologies and Future Prospect in White LED Lighting , 2008 .

[27]  Luoxi Hao,et al.  Spectral optimization simulation of white light based on the photopic eye-sensitivity curve , 2016 .

[28]  Ernie Lee,et al.  66.1: Distinguised Paper: A High‐Efficiency Wide‐Color‐Gamut Solid‐State Backlight System for LCDs Using Quantum Dot Enhancement Film , 2012 .

[29]  Guanjun Tan,et al.  18‐4: Converting Light Diffusing Polymer Powders into Stable Perovskite‐Based Tunable Downconverters , 2018 .

[30]  S. Mhaisalkar,et al.  Perovskite Materials for Light‐Emitting Diodes and Lasers , 2016, Advanced materials.

[31]  Christoph G. A. Hoelen,et al.  LP‐2: High Performance LCD Backlighting using High Intensity Red, Green and Blue Light Emitting Diodes , 2001 .

[32]  H. Zeng,et al.  Heterogeneous Nucleation toward Polar‐Solvent‐Free, Fast, and One‐Pot Synthesis of Highly Uniform Perovskite Quantum Dots for Wider Color Gamut Display , 2018 .

[33]  Kerstin Vogler,et al.  Applications Of Multi Objective Evolutionary Algorithms , 2016 .

[34]  Guanjun Tan,et al.  High dynamic range liquid crystal displays with a mini-LED backlight. , 2018, Optics express.

[35]  D. H. Mash,et al.  Light-emitting diodes , 1977, Nature.

[36]  Guoxing He,et al.  Spectral optimization of color temperature tunable white LEDs with excellent color rendering and luminous efficacy. , 2014, Optics letters.

[37]  He Huang,et al.  Lead Halide Perovskite Nanocrystals in the Research Spotlight: Stability and Defect Tolerance , 2017, ACS energy letters.

[38]  Chung-Hao Tien,et al.  Multispectral mixing scheme for LED clusters with extended operational temperature window. , 2012, Optics express.

[39]  He Huang,et al.  Control of Emission Color of High Quantum Yield CH3NH3PbBr3 Perovskite Quantum Dots by Precipitation Temperature , 2015, Advanced science.

[40]  Chuang‐Chuang Tsai,et al.  Planar Lighting System Using Array of Blue LEDs to Excite Yellow Remote Phosphor Film , 2011, Journal of Display Technology.

[41]  A Paul Alivisatos,et al.  Highly Luminescent Colloidal Nanoplates of Perovskite Cesium Lead Halide and Their Oriented Assemblies. , 2015, Journal of the American Chemical Society.

[42]  Shin-Tson Wu,et al.  Going beyond the limit of an LCD’s color gamut , 2017, Light: Science & Applications.

[43]  Angela S. Wochnik,et al.  Narrow-band red-emitting Sr[LiAl₃N₄]:Eu²⁺ as a next-generation LED-phosphor material. , 2014, Nature materials.

[44]  Yoshihiro Ohno Spectral Design Considerations for Color Rendering of White LED Light Sources , 2005 .

[45]  M. Shur,et al.  Spectral optimization of phosphor-conversion light-emitting diodes for ultimate color rendering , 2008 .

[46]  Edward H. Sargent,et al.  Perovskite photonic sources , 2016, Nature Photonics.

[47]  H. Zeng,et al.  CsPbX3 Quantum Dots for Lighting and Displays: Room‐Temperature Synthesis, Photoluminescence Superiorities, Underlying Origins and White Light‐Emitting Diodes , 2016 .

[48]  Jeffrey Y. Tsao,et al.  LED lighting efficacy: Status and directions , 2017 .

[49]  H. Zeng,et al.  Double-Protected All-Inorganic Perovskite Nanocrystals by Crystalline Matrix and Silica for Triple-Modal Anti-Counterfeiting Codes. , 2017, ACS applied materials & interfaces.

[50]  Yoshihiro Ohno,et al.  Spectral design considerations for white LED color rendering , 2005 .

[51]  Brian Theobald,et al.  Exploring the bounds of narrow-band quantum dot downconverted LEDs , 2017 .

[52]  Cesare Soci,et al.  Lead iodide perovskite light-emitting field-effect transistor , 2015, Nature Communications.

[53]  Shin-Tson Wu,et al.  Liquid crystal display and organic light-emitting diode display: present status and future perspectives , 2017, Light: Science & Applications.

[54]  James S. Speck,et al.  Prospects for LED lighting , 2009 .

[55]  Hee Chang Yoon,et al.  Circadian-tunable Perovskite Quantum Dot-based Down-Converted Multi-Package White LED with a Color Fidelity Index over 90 , 2017, Scientific Reports.

[56]  Shin‐Tson Wu,et al.  Wide color gamut LCD with a quantum dot backlight. , 2013, Optics express.

[57]  M. Kanatzidis,et al.  Strong Electron–Phonon Coupling and Self-Trapped Excitons in the Defect Halide Perovskites A3M2I9 (A = Cs, Rb; M = Bi, Sb) , 2017 .

[58]  Yun-Han Lee,et al.  Tuning the correlated color temperature of white light-emitting diodes resembling Planckian locus. , 2018, Optics express.

[59]  S. Stranks,et al.  Highly Tunable Colloidal Perovskite Nanoplatelets through Variable Cation, Metal, and Halide Composition. , 2016, ACS nano.

[60]  Yun-Han Lee,et al.  Quantum Dots Enhanced Liquid Displays , 2014, Journal of Display Technology.

[61]  J. Teuscher,et al.  Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites , 2012, Science.

[62]  Hongkun Park,et al.  Synthesis of single-crystalline perovskite nanorods composed of barium titanate and strontium titanate. , 2002, Journal of the American Chemical Society.

[63]  Shin-Tson Wu,et al.  Ultrastable, Highly Luminescent Organic–Inorganic Perovskite–Polymer Composite Films , 2016, Advanced materials.

[64]  Zhang Jiang,et al.  In situ synthesis and macroscale alignment of CsPbBr3 perovskite nanorods in a polymer matrix. , 2018, Nanoscale.

[65]  Angshuman Nag,et al.  Beyond Colloidal Cesium Lead Halide Perovskite Nanocrystals: Analogous Metal Halides and Doping , 2017 .

[66]  Takashi Mukai,et al.  High-Power GaN P-N Junction Blue-Light-Emitting Diodes , 1991 .

[67]  K. Käläntär Modified functional light-guide plate for backlighting transmissive LCDs , 2003 .

[68]  Anant Achyut Setlur,et al.  Phosphors for LED-based Solid-State Lighting , 2009 .

[69]  C. Elvidge,et al.  Limiting the impact of light pollution on human health, environment and stellar visibility. , 2011, Journal of environmental management.

[70]  Jie Chen,et al.  Investigation on Three-Hump Phosphor-Coated White Light-Emitting Diodes for Healthy Lighting by Genetic Algorithm , 2019, IEEE Photonics Journal.

[71]  Florian Hoegl,et al.  Brightly Luminescent and Color-Tunable Formamidinium Lead Halide Perovskite FAPbX3 (X = Cl, Br, I) Colloidal Nanocrystals. , 2017, Nano letters.

[72]  Yi-Jun Lu,et al.  Spectral Optimization of Three-Primary LEDs by Considering the Circadian Action Factor , 2016, IEEE Photonics Journal.

[73]  Haizheng Zhong,et al.  Brightly Luminescent and Color-Tunable Colloidal CH3NH3PbX3 (X = Br, I, Cl) Quantum Dots: Potential Alternatives for Display Technology. , 2015, ACS nano.

[74]  Aslihan Babayigit,et al.  Intrinsic Thermal Instability of Methylammonium Lead Trihalide Perovskite , 2015 .

[75]  Jeffrey A. Christians,et al.  Transformation of the excited state and photovoltaic efficiency of CH3NH3PbI3 perovskite upon controlled exposure to humidified air. , 2015, Journal of the American Chemical Society.

[76]  Shin-Tson Wu,et al.  LED-Lit LCD TVs , 2008 .

[77]  Anders Hagfeldt,et al.  Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c5ee03874j Click here for additional data file. , 2016, Energy & environmental science.

[78]  S. Mhaisalkar,et al.  Perovskite Materials for Light‐Emitting Diodes and Lasers , 2016 .

[79]  Ziquan Guo,et al.  Spectral Optimization of Candle-Like White Light-Emitting Diodes With High Color Rendering Index and Luminous Efficacy , 2016, Journal of Display Technology.

[80]  Sandeep Kumar Pathak,et al.  Perovskite Crystals for Tunable White Light Emission , 2015 .

[81]  M. Shur,et al.  Color rendition engineering of phosphor-converted light-emitting diodes. , 2013, Optics express.

[82]  D. Berson,et al.  Phototransduction by Retinal Ganglion Cells That Set the Circadian Clock , 2002, Science.

[83]  Henry J. Snaith,et al.  Stability of Metal Halide Perovskite Solar Cells , 2015 .

[84]  P. Holloway,et al.  Stable and efficient quantum-dot light-emitting diodes based on solution-processed multilayer structures , 2011 .

[85]  Luoxi Hao,et al.  Circadian-effect engineering of solid-state lighting spectra for beneficial and tunable lighting. , 2016, Optics express.

[86]  R. Seshadri,et al.  Phosphors for Solid-State White Lighting , 2013 .

[87]  Sisi Liang,et al.  Enhancing the Stability of Perovskite Quantum Dots by Encapsulation in Crosslinked Polystyrene Beads via a Swelling–Shrinking Strategy toward Superior Water Resistance , 2017 .

[88]  Nripan Mathews,et al.  Low-temperature solution-processed wavelength-tunable perovskites for lasing. , 2014, Nature materials.

[89]  Yingbai Yan,et al.  Novel integrated light-guide plates for liquid crystal display backlight , 2005 .

[90]  Hee Chang Yoon,et al.  Study of Perovskite QD Down-Converted LEDs and Six-Color White LEDs for Future Displays with Excellent Color Performance. , 2016, ACS applied materials & interfaces.

[91]  Henry J Snaith,et al.  Metal-halide perovskites for photovoltaic and light-emitting devices. , 2015, Nature nanotechnology.

[92]  Biwu Ma,et al.  Low-Dimensional Organic Tin Bromide Perovskites and Their Photoinduced Structural Transformation. , 2017, Angewandte Chemie.

[93]  T. W. Murphy Maximum spectral luminous efficacy of white light , 2012, 1309.7039.

[94]  Y. Qi,et al.  Thermal degradation of CH3NH3PbI3 perovskite into NH3 and CH3I gases observed by coupled thermogravimetry–mass spectrometry analysis , 2016 .

[95]  Sandeep Kumar Pathak,et al.  High Photoluminescence Efficiency and Optically Pumped Lasing in Solution-Processed Mixed Halide Perovskite Semiconductors. , 2014, The journal of physical chemistry letters.

[96]  Jun Lin,et al.  Recent progress in luminescence tuning of Ce(3+) and Eu(2+)-activated phosphors for pc-WLEDs. , 2015, Chemical Society reviews.

[97]  Yongtian Wang,et al.  In Situ Fabrication of Halide Perovskite Nanocrystal‐Embedded Polymer Composite Films with Enhanced Photoluminescence for Display Backlights , 2016, Advanced materials.

[98]  Jong Kyu Kim,et al.  Solid-State Light Sources Getting Smart , 2005, Science.

[99]  Makoto Izumi,et al.  Highly efficient narrow-band green and red phosphors enabling wider color-gamut LED backlight for more brilliant displays. , 2015, Optics express.

[100]  Shuai Chang,et al.  In Situ Fabricated Perovskite Nanocrystals: A Revolution in Optical Materials , 2018, Advanced Optical Materials.

[101]  S. Lockley,et al.  Lux vs. wavelength in light treatment of Seasonal Affective Disorder , 2009, Acta psychiatrica Scandinavica.

[102]  Q. Akkerman,et al.  Genesis, challenges and opportunities for colloidal lead halide perovskite nanocrystals , 2018, Nature Materials.

[103]  Rimantas Vaicekauskas,et al.  Tunability of the circadian action of tetrachromatic solid-state light sources , 2015 .

[104]  M. Grätzel,et al.  Sequential deposition as a route to high-performance perovskite-sensitized solar cells , 2013, Nature.

[105]  Shin-Tson Wu,et al.  Realizing Rec. 2020 Color Gamut with Quantum Dot Displays Color Shift Reduction of a Multi-domain Ips-lcd Using Rgb-led Backlight, " Opt , 2022 .

[106]  S. Nakamura,et al.  Candela‐class high‐brightness InGaN/AlGaN double‐heterostructure blue‐light‐emitting diodes , 1994 .

[107]  Joshua J Gooley,et al.  Treatment of circadian rhythm sleep disorders with light. , 2008, Annals of the Academy of Medicine, Singapore.

[108]  Shuji Nakamura,et al.  The Roles of Structural Imperfections in InGaN-Based Blue Light-Emitting Diodes and Laser Diodes , 1998 .

[109]  M.H. Crawford,et al.  LEDs for Solid-State Lighting: Performance Challenges and Recent Advances , 2009, IEEE Journal of Selected Topics in Quantum Electronics.

[110]  M. Shur,et al.  Optimization of white polychromatic semiconductor lamps , 2002 .

[111]  Aslihan Babayigit,et al.  Toxicity of organometal halide perovskite solar cells. , 2016, Nature materials.

[112]  Shin-Tson Wu,et al.  Color-tunable light emitting diodes based on quantum dot suspension. , 2015, Applied optics.

[113]  Guangda Niu,et al.  Review of recent progress in chemical stability of perovskite solar cells , 2015 .

[114]  R. Xie,et al.  Critical Review—Narrow-Band Nitride Phosphors for Wide Color-Gamut White LED Backlighting , 2018 .

[115]  Ji Hye Oh,et al.  Healthy, natural, efficient and tunable lighting: four-package white LEDs for optimizing the circadian effect, color quality and vision performance , 2014 .

[116]  Guoxing He,et al.  Optimal spectra of the phosphor-coated white LEDs with excellent color rendering property and high luminous efficacy of radiation. , 2011, Optics express.

[117]  Tsutomu Miyasaka,et al.  Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. , 2009, Journal of the American Chemical Society.

[118]  Daqin Chen,et al.  Silica-Coated Mn-Doped CsPb(Cl/Br)3 Inorganic Perovskite Quantum Dots: Exciton-to-Mn Energy Transfer and Blue-Excitable Solid-State Lighting. , 2017, ACS applied materials & interfaces.

[119]  Richard E. Kronauer,et al.  Dose-response relationships for resetting of human circadian clock by light , 1996, Nature.