PIXE and ionoluminescence — A synergetic analytical combination

The purpose of this paper is to demonstrate that ionoluminescence and PIXE are genuinely complementary techniques and that the combination represents a powerful analytical tool, particularly in geochemistry. Ionoluminescence can be used for imaging and qualitative analysis of elements and chemical compounds. The quantification of ionoluminescence data, however, requires an improved understanding of luminescence physics. The trace element properties of PIXE may be of major importance in this development.

[1]  Arnol'd Sergeevich Marfunin,et al.  Spectroscopy, Luminescence and Radiation Centers in Minerals , 1979 .

[2]  T. Mernagh,et al.  PIXE microanalysis of fluid inclusions and its application to study ore metal segregation between magmatic brine and vapor , 1993 .

[3]  A. Bettiol,et al.  Ion beam induced luminescence from diamond and other crystals from a nuclear microbeam , 1994 .

[4]  G. Dieke,et al.  The Spectra of the Doubly and Triply Ionized Rare Earths , 1963 .

[5]  B. G. Yacobi,et al.  Cathodoluminescence Microscopy of Inorganic Solids , 1990, Springer US.

[6]  D. R. Cousens,et al.  Quantitative analysis of PIXE spectra in geoscience applications , 1990 .

[7]  W. Griffin,et al.  The proton microprobe: a revolution in mineral analysis , 1991 .

[8]  H. Hansson,et al.  Ion beam thermography — analysis of chemical compounds using ion beam techniques , 1988 .

[9]  L. Cabri,et al.  Micro-PIXE as a complement to electron probe microanalysis in mineralogy , 1990 .

[10]  F. Urbach,et al.  Introduction to the Luminescence of Solids , 1950 .

[11]  D. J. Marshall,et al.  Cathodoluminescence of geological materials , 1988 .

[12]  C. Ryan,et al.  Imaging with ionoluminescence (IL) in a nuclear microprobe , 1993 .

[13]  Kawai Jun Chemical effects in the satellites of X-ray emission spectra , 1993 .

[14]  B. Henderson,et al.  Optical spectroscopy of inorganic solids , 1989 .

[15]  K. Malmqvist,et al.  A highly sensitive method for rare-earth element analysis using ionoluminescence combined with PIXE , 1994 .