Pneumoconiosis and quartz content of respirable dusts in the coal mines in Zonguldak, Turkey

Abstract Coal Worker's Pneumoconiosis (CWP) is one of the most important occupational health problems in Turkish coal mining. Despite the decrease in employment and production at Turkish Hardcoal Enterprise (TTK) in the Zonguldak Basin, the occurrence of pneumoconiosis is still very high, particularly among the face workers. This study aims to evaluate the dust concentrations and quartz contents of respirable dusts in coal faces and pneumoconiosis risks related to face workers in TTK collieries. The mean respirable dust exposure experienced by the face workers was evaluated and compared with the occupational exposure limits. The data on the dust samples exhibit great variations. The quartz contents of respirable dusts were determined by a FTIR spectrophotometer. The mean respirable dust concentration in the coal faces varies from 1.6 to 14.5 mg/m 3 while the quartz content varies from 0.7 to 10.4%. The mean respirable dust concentrations in the coal faces in Karadon, Amasra, Armutcuk and Kozlu collieries are above the TLV (5 mg/m 3 ) of Turkey and the percentage of the measurements exceeding the TLV in the coal faces range from 25% to 100. An analysis of variance was performed to investigate the effects of workplace and seam characteristics on respirable dust levels. According to the results of variance analysis (ANOVA), it was seen that there are significant differences between seams and collieries in terms of dust concentration and quartz contents of respirable dust. CWP is still the most important problem in the collieries of TTK. The occurrence of CWP is higher among underground face workers. There have been 200 CWP cases in the last decade with a prevalence rate of 6.3%. CWP rates in the coal faces of the collieries increase as the respirable dust levels and quartz contents increase in general. This finding indicates that the TLV (5 mg/m 3 ) of Turkey should be re-evaluated and additional safety precautions should be taken in the workplaces where high quartz contents of respirable dust exist.

[1]  S. Page,et al.  Relationship of coal seam parameters and airborne respirable dust at longwalls , 1992 .

[2]  A. Zuckerman,et al.  IARC Monographs on the Evaluation of Carcinogenic Risks to Humans , 1995, IARC monographs on the evaluation of carcinogenic risks to humans.

[3]  Aleksandra Maciejewska,et al.  Occupational exposure assessment for crystalline silica dust: approach in Poland and worldwide. , 2008, International journal of occupational medicine and environmental health.

[4]  J. Bennett,et al.  The relationship between coal rank and the prevalence of pneumoconiosis. , 1979, British journal of industrial medicine.

[5]  O. Tüysüz Geology of the Cretaceous sedimentary basins of the Western Pontides , 1999 .

[6]  W. H. Walton,et al.  New Dust Standards for British Coal Mines , 1970, Nature.

[7]  R. Bustin,et al.  Preliminary Hydrocarbon Source Rock Assessment of the Paleozoic and Mesozoic Formations of the Western Black Sea Region of Turkey , 1999 .

[8]  A. Şengör,et al.  Kinematic history of the opening of the Black Sea and its effect on the surrounding regions , 1994 .

[9]  Peter Morfeld,et al.  COMPONENTS OF COAL MINE DUST EXPOSURE AND THE OCCURRENCE OF PRESTAGES OF PNEUMOCONIOSIS , 1997 .

[10]  Peter Morfeld,et al.  What Component of Coal Causes Coal Workers’ Pneumoconiosis? , 2009, Journal of occupational and environmental medicine.

[12]  M. Yalçın,et al.  Pore volume and surface area of the Carboniferous coals from the Zonguldak basin (NW Turkey) and their variations with rank and maceral composition , 2001 .

[13]  M D Attfield,et al.  An investigation into the relationship between coal workers' pneumoconiosis and dust exposure in U.S. coal miners. , 1992, American Industrial Hygiene Association journal.

[14]  Richard A. Johnson,et al.  Statistics: Principles and Methods , 1985 .

[15]  W. H. Walton,et al.  The effect of quartz and other non-coal dusts in coalworkers' pneumoconiosis. Part I: Epidemiological studies. , 1975, Inhaled particles.

[16]  Derek G. Hillis,et al.  Factors Affecting the Accuracy of Airborne Quartz Determination , 2007, Journal of occupational and environmental hygiene.

[17]  W. H. Walton,et al.  Characteristics of the airborne dust in British coal mines. , 1970, Inhaled particles.

[18]  P. Ildefonse,et al.  MULTICOMPONENT ANALYSIS OF FTIR SPECTRA: QUANTIFICATION OF AMORPHOUS AND CRYSTALLIZED MINERAL PHASES IN SYNTHETIC AND NATURAL SEDIMENTS , 1998 .

[19]  Q. Niu,et al.  Coal Workers’ Pneumoconiosis and Related Risk Indices , 1996 .

[20]  C. Karacan,et al.  Fracture/cleat analysis of coals from Zonguldak Basin (northwestern Turkey) relative to the potential of coalbed methane production , 2000 .

[21]  J. Li,et al.  A comparative study of particle size dependency of IR and XRD methods for quartz analysis. , 1994, American Industrial Hygiene Association journal.

[22]  M D Attfield,et al.  Rapidly progressive coal workers’ pneumoconiosis in the United States: geographic clustering and other factors , 2005, Occupational and Environmental Medicine.

[23]  A. Bandopadhyay Determination of quartz content for Indian coals using an FTIR technique , 2010 .

[24]  J. Ojima Determining of Crystalline Silica in Respirable Dust Samples by Infrared Spectrophotometry in the Presence of Interferences , 2003, Journal of occupational health.

[25]  M. Attfield,et al.  Surveillance data on US coal miners' pneumoconiosis, 1970 to 1986. , 1992, American journal of public health.

[26]  P. Walker,et al.  Fourier Transform Infrared study of mineral matter in coal. A novel method for quantitative mineralogical analysis , 1978 .

[27]  Hamit Aydın,et al.  Evaluation of the risk of coal workers pneumoconiosis (CWP): a case study for the Turkish hardcoal mining. , 2010 .

[28]  S. Toprak Petrographic properties of major coal seams in Turkey and their formation , 2009 .

[29]  S. Schatzel Identifying sources of respirable quartz and silica dust in underground coal mines in southern West Virginia, western Virginia, and eastern Kentucky , 2009 .

[30]  L. C. Kenny,et al.  Estimation of the Risk of Contracting Pneumoconiosis in the UK Coal Mining Industry , 2002 .

[31]  J F Hurley,et al.  Coalworkers' simple pneumoconiosis and exposure to dust at 10 British coalmines. , 1982, British journal of industrial medicine.

[32]  H. Schenk,et al.  Modelling of gas generation in coals of the Zonguldak basin (northwestern Turkey) , 1994 .