Organic photodetector with spectral response tunable across the visible spectrum by means of internal optical microcavity

Abstract We demonstrate an organic photodetector (OPD) structure in which the active layers and a thick optical spacer are sandwiched between two metallic electrodes, forming a Fabry–Perot resonant cavity. The second resonant mode of this cavity can be positioned by means of an optical spacer so that its maximum intensity overlaps with the donor–acceptor interface, leading to a peak in the external quantum efficiency (EQE) of the OPD for this resonant wavelength. The photoresponse can thus be tuned across the visible spectrum by adjusting the spacer thickness, while the full width half maximum remains approximately 50 nm. Because the active layers can be thin in this approach, the EQE is not sacrificed, and the device can achieve a relatively high response frequency that does not suffer from the inclusion of the optical spacer. We simulate the photoresponse of OPD structure using transfer matrix optical calculations and an exciton diffusion model; our simulation also explicitly accounts for interface roughness measured by atomic force microscopy. Angular dependence of the OPD’s response is also measured and discussed.

[1]  Chihaya Adachi,et al.  Top Light-Harvesting Organic Solar Cell Using Ultrathin Ag/MgAg Layer as Anode , 2007 .

[2]  Guglielmo Lanzani,et al.  Organic-based tristimuli colorimeter , 2007 .

[3]  N. E. Coates,et al.  Efficient Tandem Polymer Solar Cells Fabricated by All-Solution Processing , 2007, Science.

[4]  Max Shtein,et al.  Enhanced optical field intensity distribution in organic photovoltaic devices using external coatings , 2006 .

[5]  Max Shtein,et al.  Transparent and conductive electrodes based on unpatterned, thin metal films , 2008 .

[6]  X. Tao,et al.  Fluorene-based Tröger's base analogues : Potential electroluminescent materials , 2008 .

[7]  Peter Seitz,et al.  High sensitivity organic photodiodes with low dark currents and increased lifetimes , 2008 .

[8]  Stephen R. Forrest,et al.  Small molecular weight organic thin-film photodetectors and solar cells , 2003 .

[9]  Uli Lemmer,et al.  Organic Microcavity Photodiodes , 2003 .

[10]  Ian Papautsky,et al.  High-sensitivity, disposable lab-on-a-chip with thin-film organic electronics for fluorescence detection. , 2008, Lab on a chip.

[11]  Toshihisa Watabe,et al.  Color Sensors with Three Vertically Stacked Organic Photodetectors , 2007 .

[12]  Stephen R. Forrest,et al.  Efficient, high-bandwidth organic multilayer photodetectors , 2000 .

[13]  Liduo Wang,et al.  A microfluidic device using a green organic light emitting diode as an integrated excitation source. , 2005, Lab on a chip.

[14]  L. S. Roman,et al.  Modeling photocurrent action spectra of photovoltaic devices based on organic thin films , 1999 .

[15]  Sanjiv Sambandan,et al.  Flexible image sensor array with bulk heterojunction organic photodiode , 2008 .

[16]  Xuhua Wang,et al.  Towards microalbuminuria determination on a disposable diagnostic microchip with integrated fluorescence detection based on thin-film organic light emitting diodes. , 2005, Lab on a chip.

[17]  Luke P. Lee,et al.  Innovations in optical microfluidic technologies for point-of-care diagnostics. , 2008, Lab on a chip.

[18]  T. Morimune,et al.  High-Speed Organic Photodetectors Using Heterostructure with Phthalocyanine and Perylene Derivative , 2006 .

[19]  S. Forrest,et al.  Direct transfer patterning on three dimensionally deformed surfaces at micrometer resolutions and its application to hemispherical focal plane detector arrays , 2008 .

[20]  I. Filiński,et al.  The effects of sample imperfections on optical spectra , 1972 .

[21]  D. Lynch,et al.  Handbook of Optical Constants of Solids , 1985 .