Surface Ozone‐Temperature Relationship: The Meridional Gradient Ratio Approximation

The daily variation of ground‐level ozone (O3), a harmful pollutant, is positively correlated with air temperature (T) in many midlatitude land regions in the summer. The observed temporal regression slope between O3 and T (dO3/dT) is referred to as the “ozone‐climate change penalty” and has been proposed as a way to predict the impact of future climate warming on O3 from observations. Here, we use two chemical transport models to show that the spatial variation of dO3/dT is primarily determined by simultaneous meridional advection of O3 and T. Furthermore, the sign and magnitude of dO3/dT can be approximated by their climatological meridional gradient ratio (O3 gradient divided by T gradient). Consideration of expected changes in the meridional gradients of T and O3 due to climate change indicates that dO3/dT will likely change. Caution is needed when using the observed climate penalty to predict O3 changes.