Challenges of non-aqueous Li–O2 batteries: electrolytes, catalysts, and anodes

A lot of attention has been paid to Li–O2 batteries in recent years, due to the huge potential specific energy and energy density, and they are extensively studied around the world. Much advance has been achieved, however, the fundamental understanding is still insufficient and challenges remain. Here, we provide a specific perspective on the development of non-aqueous Li–O2 batteries excluding those with aqueous, ionic liquid, hybrid, and solid-state electrolytes, because non-aqueous Li–O2 batteries possess a relatively simple configuration and the research on non-aqueous Li–O2 batteries is the most active of all Li–O2 batteries. The discussion will be focused on non-aqueous electrolytes, cathode catalysts, and anodes, and corresponding perspectives are provided at the end.

[1]  K. M. Abraham,et al.  A Polymer Electrolyte‐Based Rechargeable Lithium/Oxygen Battery , 1996 .

[2]  Hun‐Gi Jung,et al.  An improved high-performance lithium-air battery. , 2012, Nature chemistry.

[3]  P. Bruce,et al.  Reactions in the rechargeable lithium-O2 battery with alkyl carbonate electrolytes. , 2011, Journal of the American Chemical Society.

[4]  Hubert A. Gasteiger,et al.  The Effect of Water on the Discharge Capacity of a Non-Catalyzed Carbon Cathode for Li-O2 Batteries , 2012 .

[5]  T. Maiyalagan,et al.  Review on Recent Progress in Nitrogen-Doped Graphene: Synthesis, Characterization, and Its Potential Applications , 2012 .

[6]  In-Hwan Oh,et al.  A transmission electron microscopy study of the electrochemical process of lithium-oxygen cells. , 2012, Nano letters.

[7]  Mario Blanco,et al.  Computational Study of the Mechanisms of Superoxide-Induced Decomposition of Organic Carbonate-Based Electrolytes , 2011 .

[8]  Gang Wu,et al.  High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt , 2011, Science.

[9]  Haoshen Zhou,et al.  Electrochemical performance and reaction mechanism of all-solid-state lithium–air batteries composed of lithium, Li1+xAlyGe2−y(PO4)3 solid electrolyte and carbon nanotube air electrode , 2012 .

[10]  Yang Shao-Horn,et al.  Chemical and Morphological Changes of Li–O2 Battery Electrodes upon Cycling , 2012 .

[11]  K. Amine,et al.  A metal-free, lithium-ion oxygen battery: a step forward to safety in lithium-air batteries. , 2012, Nano letters.

[12]  Jun Chen,et al.  Metal-air batteries: from oxygen reduction electrochemistry to cathode catalysts. , 2012, Chemical Society reviews.

[13]  Jean-Marie Tarascon,et al.  Li-O2 and Li-S batteries with high energy storage. , 2011, Nature materials.

[14]  Jasim Ahmed,et al.  A Critical Review of Li/Air Batteries , 2011 .

[15]  Hui Li,et al.  Nitrogen-doped carbon nanotubes as air cathode catalysts in zinc-air battery , 2011 .

[16]  Jagjit Nanda,et al.  Spectroscopic Characterization of Solid Discharge Products in Li–Air Cells with Aprotic Carbonate Electrolytes , 2011 .

[17]  J. Tarascon,et al.  Rechargeable Li1 + x Mn2 O 4 / Carbon Cells with a New Electrolyte Composition Potentiostatic Studies and Application to Practical Cells , 1993 .

[18]  Kang Xu,et al.  Nonaqueous liquid electrolytes for lithium-based rechargeable batteries. , 2004, Chemical reviews.

[19]  H. Hng,et al.  Fe2O3 nanocluster-decorated graphene as O2 electrode for high energy Li–O2 batteries , 2012 .

[20]  Hubert A. Gasteiger,et al.  The Influence of Catalysts on Discharge and Charge Voltages of Rechargeable Li–Oxygen Batteries , 2010 .

[21]  Wei Qu,et al.  A review on air cathodes for zinc–air fuel cells , 2010 .

[22]  R M Shelby,et al.  Solvents' Critical Role in Nonaqueous Lithium-Oxygen Battery Electrochemistry. , 2011, The journal of physical chemistry letters.

[23]  Jiujun Zhang,et al.  Carbon-Supported Fe–Nx Catalysts Synthesized by Pyrolysis of the Fe(II)–2,3,5,6-Tetra(2-pyridyl)pyrazine Complex: Structure, Electrochemical Properties, and Oxygen Reduction Reaction Activity , 2011 .

[24]  Xiao‐Qing Yang,et al.  High Rate Oxygen Reduction in Non-aqueous Electrolytes with the Addition of Perfluorinated Additives , 2011 .

[25]  J. Baldwin,et al.  Nitrogen-doped graphene-rich catalysts derived from heteroatom polymers for oxygen reduction in nonaqueous lithium-O2 battery cathodes. , 2012, ACS nano.

[26]  Haoshen Zhou,et al.  Enhanced Cycling Performance of Li‐O2 Batteries by the Optimized Electrolyte Concentration of LiTFSA in Glymes , 2013 .

[27]  M. E. Peover,et al.  Electrolytic reduction of oxygen in aprotic solvents: The superoxide ion , 1966 .

[28]  Yang Shao-Horn,et al.  Evidence of catalyzed oxidation of Li2O2 for rechargeable Li-air battery applications. , 2012, Physical chemistry chemical physics : PCCP.

[29]  Lei Zhang,et al.  Nitrogen-doped graphene nanosheet-supported non-precious iron nitride nanoparticles as an efficient electrocatalyst for oxygen reduction , 2011 .

[30]  Nancy J. Dudney,et al.  Current Collectors for Rechargeable Li-Air Batteries , 2011 .

[31]  N. Imanishi,et al.  Aqueous Lithium/Air Rechargeable Batteries , 2011 .

[32]  Yongyao Xia,et al.  The effect of oxygen pressures on the electrochemical profile of lithium/oxygen battery , 2009 .

[33]  G. Graff,et al.  Investigation of the rechargeability of Li–O2 batteries in non-aqueous electrolyte , 2011 .

[34]  L. Krause,et al.  Corrosion of aluminum at high voltages in non-aqueous electrolytes containing perfluoroalkylsulfonyl imides; new lithium salts for lithium-ion cells , 1997 .

[35]  James W. Evans,et al.  Aluminum Corrosion in Lithium Batteries An Investigation Using the Electrochemical Quartz Crystal Microbalance , 2000 .

[36]  B. Scrosati,et al.  Study of a Li–air battery having an electrolyte solution formed by a mixture of an ether-based aprotic solvent and an ionic liquid , 2012 .

[37]  S. Seki,et al.  Oxidative-stability enhancement and charge transport mechanism in glyme-lithium salt equimolar complexes. , 2011, Journal of the American Chemical Society.

[38]  M. Giordano,et al.  Molecular Oxygen Electroreduction at Pt and Au Electrodes in Acetonitrile Solutions , 1983 .

[39]  D. Bethune,et al.  On the efficacy of electrocatalysis in nonaqueous Li-O2 batteries. , 2011, Journal of the American Chemical Society.

[40]  B. McCloskey,et al.  Lithium−Air Battery: Promise and Challenges , 2010 .

[41]  Si Hyoung Oh,et al.  Synthesis of a metallic mesoporous pyrochlore as a catalyst for lithium–O2 batteries. , 2012, Nature chemistry.

[42]  P. Bruce,et al.  A Reversible and Higher-Rate Li-O2 Battery , 2012, Science.

[43]  Haoshen Zhou,et al.  Electrochemical Performance of Solid‐State Lithium–Air Batteries Using Carbon Nanotube Catalyst in the Air Electrode , 2012 .

[44]  Ping He,et al.  Li‐Redox Flow Batteries Based on Hybrid Electrolytes: At the Cross Road between Li‐ion and Redox Flow Batteries , 2012 .

[45]  Kang Xu,et al.  Reaction mechanisms for the limited reversibility of Li–O2 chemistry in organic carbonate electrolytes , 2011 .

[46]  J. Goodenough,et al.  Surface protonation and electrochemical activity of oxides in aqueous solution , 1990 .

[47]  Y. Liu,et al.  Nitrogen-doped graphene as efficient metal-free electrocatalyst for oxygen reduction in fuel cells. , 2010, ACS nano.

[48]  Haoshen Zhou,et al.  To draw an air electrode of a Li–air battery by pencil , 2011 .

[49]  R. McCreery,et al.  Elucidation of the Mechanism of Dioxygen Reduction on Metal‐Free Carbon Electrodes , 2000 .

[50]  N. Dudney,et al.  Influence of Lithium Salts on the Discharge Chemistry of Li-Air Cells. , 2012, The journal of physical chemistry letters.

[51]  Stefan A. Freunberger,et al.  Li-O2 battery with a dimethylformamide electrolyte. , 2012, Journal of the American Chemical Society.

[52]  Z. Wen,et al.  A tubular polypyrrole based air electrode with improved O2 diffusivity for Li–O2 batteries , 2012 .

[53]  M. Armand,et al.  Issues and challenges facing rechargeable lithium batteries , 2001, Nature.

[54]  Bruno Scrosati,et al.  Investigation of the O2 electrochemistry in a polymer electrolyte solid-state cell. , 2011, Angewandte Chemie.

[55]  Tao Zhang,et al.  A novel high energy density rechargeable lithium/air battery. , 2009, Chemical communications.

[56]  Sanjeev Mukerjee,et al.  Studies of Li-Air Cells Utilizing Dimethyl Sulfoxide-Based Electrolyte , 2013 .

[57]  V. Koch Reactions of Tetrahydrofuran and Lithium Hexafluoroarsenate with Lithium , 1979 .

[58]  D. Maricle,et al.  Reducion of Oxygen to Superoxide Anion in Aprotic Solvents. , 1965 .

[59]  Shengbo Zhang,et al.  Partially fluorinated solvent as a co-solvent for the non-aqueous electrolyte of Li/air battery , 2011 .

[60]  Tao Zhang,et al.  From Li-O2 to Li-air batteries: carbon nanotubes/ionic liquid gels with a tricontinuous passage of electrons, ions, and oxygen. , 2012, Angewandte Chemie.

[61]  Haoshen Zhou,et al.  Carbon supported TiN nanoparticles: an efficient bifunctional catalyst for non-aqueous Li-O2 batteries. , 2013, Chemical communications.

[62]  Linda F. Nazar,et al.  Screening for superoxide reactivity in Li-O2 batteries: effect on Li2O2/LiOH crystallization. , 2012, Journal of the American Chemical Society.

[63]  W. Henderson,et al.  Complexes of Lithium Imide Salts with Tetraglyme and Their Polyelectrolyte Composite Materials , 2004 .

[64]  Yang Shao-Horn,et al.  Probing the Reaction Kinetics of the Charge Reactions of Nonaqueous Li-O2 Batteries. , 2013, The journal of physical chemistry letters.

[65]  M. Salomon,et al.  Methoxybenzene as an Electrolyte Solvent for the Primary Lithium Metal Air Battery , 2011 .

[66]  S. Oswald,et al.  XPS investigations of electrolyte/electrode interactions for various Li-ion battery materials , 2011, Analytical and bioanalytical chemistry.

[67]  E. Johnson,et al.  Polarographic Reduction of Oxygen in Dimethylsulfoxide. , 1966 .

[68]  Yang Shao-Horn,et al.  The discharge rate capability of rechargeable Li–O2 batteries , 2011 .

[69]  Gregory V. Chase,et al.  The Identification of Stable Solvents for Nonaqueous Rechargeable Li-Air Batteries , 2012 .

[70]  V. Koch,et al.  Structure‐Reactivity Relationships of Methylated Tetrahydrofurans with Lithium , 1980 .

[71]  Haoshen Zhou,et al.  A lithium-air battery with a potential to continuously reduce O2 from air for delivering energy , 2010 .

[72]  Bryan D. McCloskey,et al.  On the Mechanism of Nonaqueous Li–O2 Electrochemistry on C and Its Kinetic Overpotentials: Some Implications for Li–Air Batteries , 2012 .

[73]  Linda F Nazar,et al.  The role of catalysts and peroxide oxidation in lithium-oxygen batteries. , 2013, Angewandte Chemie.

[74]  Sanjeev Mukerjee,et al.  Elucidating the Mechanism of Oxygen Reduction for Lithium-Air Battery Applications , 2009 .

[75]  Z. Yao,et al.  Sulfur-doped graphene as an efficient metal-free cathode catalyst for oxygen reduction. , 2012, ACS nano.

[76]  Sanjeev Mukerjee,et al.  Rechargeable Lithium/TEGDME- LiPF6 ∕ O2 Battery , 2011 .

[77]  Juan Herranz,et al.  Iron-based cathode catalyst with enhanced power density in polymer electrolyte membrane fuel cells. , 2011, Nature communications.

[78]  Sun Tai Kim,et al.  Metal–Air Batteries with High Energy Density: Li–Air versus Zn–Air , 2010 .

[79]  P. Bruce,et al.  Rechargeable LI2O2 electrode for lithium batteries. , 2006, Journal of the American Chemical Society.

[80]  Dan Xu,et al.  Novel DMSO-based electrolyte for high performance rechargeable Li-O2 batteries. , 2012, Chemical communications.

[81]  D. Stevens,et al.  Thermal degradation of the support in carbon-supported platinum electrocatalysts for PEM fuel cells , 2005 .

[82]  Fujun Li,et al.  Carbonization over PFA-protected dispersed platinum: an effective route to synthesize high performance mesoporous-carbon supported Pt electrocatalysts , 2011 .

[83]  Yuhui Chen,et al.  The lithium-oxygen battery with ether-based electrolytes. , 2011, Angewandte Chemie.

[84]  J. Tarascon,et al.  New electrolyte compositions stable over the 0 to 5 V voltage range and compatible with the Li1+xMn2O4/carbon Li-ion cells , 1994 .

[85]  V. Koch,et al.  2-Methyltetrahydrofuran—Lithium Hexafluoroarsenate: A Superior Electrolyte for the Secondary Lithium Electrode , 1979, Science.

[86]  Frédéric Jaouen,et al.  Iron-Based Catalysts with Improved Oxygen Reduction Activity in Polymer Electrolyte Fuel Cells , 2009, Science.

[87]  Fuminori Mizuno,et al.  Rechargeable Li-Air Batteries with Carbonate-Based Liquid Electrolytes , 2010 .

[88]  M. Balasubramanian,et al.  Fe/N/C composite in Li-O2 battery: studies of catalytic structure and activity toward oxygen evolution reaction. , 2012, Journal of the American Chemical Society.

[89]  V. Koch,et al.  The Stability of the Secondary Lithium Electrode in Tetrahydrofuran‐Based Electrolytes , 1978 .

[90]  Jasim Uddin,et al.  Predicting solvent stability in aprotic electrolyte Li-air batteries: nucleophilic substitution by the superoxide anion radical (O2(•-)). , 2011, The journal of physical chemistry. A.

[91]  Zhongwei Chen,et al.  A review on non-precious metal electrocatalysts for PEM fuel cells , 2011 .

[92]  Julian L. Roberts,et al.  Electrochemistry of oxygen and superoxide ion in dimethylsulfoxide at platinum, gold and mercury electrodes , 1966 .

[93]  H. Wendt,et al.  Electroreduction of oxygen in aprotic media , 1995 .

[94]  W. Bennett,et al.  Hierarchically porous graphene as a lithium-air battery electrode. , 2011, Nano letters.

[95]  P. Bruce,et al.  Nanomaterials for rechargeable lithium batteries. , 2008, Angewandte Chemie.

[96]  A. D. Goolsby,et al.  Electrochemical reduction of superoxide ion and oxidation of hydroxide ion in dimethyl sulfoxide , 1968 .

[97]  Z. Wen,et al.  Mesoporous Co3O4 with different porosities as catalysts for the lithium–oxygen cell , 2012 .

[98]  D. Bethune,et al.  Limitations in Rechargeability of Li-O2 Batteries and Possible Origins. , 2012, The journal of physical chemistry letters.

[99]  Haoshen Zhou,et al.  Li-air rechargeable battery based on metal-free graphene nanosheet catalysts. , 2011, ACS nano.

[100]  James McBreen,et al.  New electrolytes using Li2O or Li2O2 oxides and tris(pentafluorophenyl) borane as boron based anion receptor for lithium batteries , 2008 .

[101]  Stefan A Freunberger,et al.  The carbon electrode in nonaqueous Li-O2 cells. , 2013, Journal of the American Chemical Society.

[102]  Wu Xu,et al.  Optimization of Nonaqueous Electrolytes for Primary Lithium/Air Batteries Operated in Ambient Environment , 2009 .

[103]  Duncan Graham,et al.  Oxygen reactions in a non-aqueous Li+ electrolyte. , 2011, Angewandte Chemie.

[104]  Yuyan Shao,et al.  Making Li‐Air Batteries Rechargeable: Material Challenges , 2013 .

[105]  Hui Li,et al.  Highly active and durable core-corona structured bifunctional catalyst for rechargeable metal-air battery application. , 2011, Nano letters.

[106]  Kazuki Yoshida,et al.  New glyme–cyclic imide lithium salt complexes as thermally stable electrolytes for lithium batteries , 2010 .

[107]  Betar M. Gallant,et al.  All-carbon-nanofiber electrodes for high-energy rechargeable Li–O2 batteries , 2011 .

[108]  Ji‐Guang Zhang,et al.  The stability of organic solvents and carbon electrode in nonaqueous Li-O2 batteries , 2012 .

[109]  Ping He,et al.  A lithium–air capacitor–battery based on a hybrid electrolyte , 2011 .

[110]  Jun Lu,et al.  Increased Stability Toward Oxygen Reduction Products for Lithium-Air Batteries with Oligoether-Functionalized Silane Electrolytes , 2011 .

[111]  Xin-bo Zhang,et al.  Graphene Oxide Gel‐Derived, Free‐Standing, Hierarchically Porous Carbon for High‐Capacity and High‐Rate Rechargeable Li‐O2 Batteries , 2012 .

[112]  L. Nazar,et al.  Decomposition Reaction of Lithium Bis(oxalato)borate in the Rechargeable Lithium-Oxygen Cell , 2011 .

[113]  J. Nørskov,et al.  Twin Problems of Interfacial Carbonate Formation in Nonaqueous Li-O2 Batteries. , 2012, The journal of physical chemistry letters.

[114]  Sanjeev Mukerjee,et al.  Influence of Nonaqueous Solvents on the Electrochemistry of Oxygen in the Rechargeable Lithium−Air Battery , 2010 .