Positive ion production in halogen negative ion collisions

Presents the results of electron spectroscopy and total cross section measurements of one- and two-electron loss processes in collisions of halogen negative ions with various gases for collision energies below 5 keV. The electron spectroscopy study illustrates that the production of singly excited autoionising states of the halogen atoms can be important for energies as low as 100 eV and is responsible for positive ion production, as has been also recently shown for O- collisions by Penent et al. These conclusions concerning positive ion production should also be applicable to collisions involving the parent atoms, being a characteristic of these systems rather than that of the negative ion.

[1]  V. Esaulov,et al.  Fundamental processes in collisions of O- with atoms and molecules; mechanisms of one- and two-electron loss , 1987 .

[2]  V. Esaulov,et al.  Electron detachment and excitation processes in F--inert-gas collisions , 1986 .

[3]  J. E. Hansen,et al.  Analysis of resonance structure in the photoionization of atomic chlorine , 1984 .

[4]  V. Esaulov,et al.  Electron detachment and charge exchange to shape resonances in F--molecule collisions , 1984 .

[5]  B. Ruscic,et al.  Photoionisation of atomic bromine , 1984 .

[6]  V. N. Sarma,et al.  Absorption spectrum of atomic bromine (Br I) in the vacuum ultraviolet region , 1983 .

[7]  B. Ruscic,et al.  Photoionization of atomic chlorine , 1983 .

[8]  V. Esaulov,et al.  Total electron detachment cross sections for collisions of H- and He and F- with atomic and molecular targets , 1982 .

[9]  V. Esaulov On the dynamics of electron detachment in halogen negative-ion-inert-gas collisions , 1981 .

[10]  J. Berkowitz,et al.  Photoionization of atomic iodine and atomic tellurium , 1981 .

[11]  K. Bethge,et al.  Electron-loss cross sections for negative ions at high energies , 1980 .

[12]  R. Champion,et al.  Total electron-detachment cross sections for collisions of negative halogen ions and rare gases for energies around threshold , 1978 .

[13]  D. Dhuicq,et al.  Study of electron-detachment and inelastic processes in Cl--rare-gas collisions , 1978 .

[14]  V. Esaulov,et al.  Differential study of H--inert-gas collisions , 1978 .

[15]  J. Brunt,et al.  A study of resonance structure in neon, argon, krypton and xenon using metastable excitation by electron impact with high energy resolution , 1976 .

[16]  R. Champion,et al.  Collisional detachment in collisions ofCl−with the rare gases , 1976 .

[17]  R. Geballe,et al.  The physics of electronic and atomic collisions : invited lectures, review papers, and progress reports of the IXth International Conference on the Physics of Electronic and Atomic Collisions, Seattle, 24-30 July 1975 , 1976 .

[18]  A. K. Edwards,et al.  Autodetaching states of Br - and autoionizing states of Br , 1974 .

[19]  A. K. Edwards,et al.  Autodetaching States inI , 1974 .

[20]  A. K. Edwards,et al.  Autodetaching States of Cl , 1973 .

[21]  L. J. Radziemski,et al.  Wavelengths, Energy Levels, and Analysis of Neutral Atomic Chlorine (Cl i) , 1969 .

[22]  J. Tech Analysis of the Spectrum of Neutral Atomic Bromine (Br I) , 1963, Journal of research of the National Bureau of Standards. Section A, Physics and chemistry.