论文信息 - Determination of hydroxy compounds by 4-dimethylaminopyridine-catalyzed acetylation.

Determination of hydroxy compounds by 4-dimethylaminopyridine-catalyzed acetylation.

Abstract: 4-Dimethylamlnopyridine is an effective catalyst of analytical acylations by acetic anhydride, having a specific catalytic activity about 10 4 times greater than that of pyridine. The conventional titrimetric determination of hydroxy groups is carried out with 4-dimethylaminopyridine as the catalyst and pyridine as the solvent. Typical reaction times for primary and secondary alcohols are 5–10 min. at 54-70°.

K. A. Connors | K. Albert

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