Periodic open cellular structures with ideal cubic cell geometry: Effect of porosity and cell orientation on pressure drop behavior

Abstract Periodic open cellular structures (POCS) with ideal cubic cell geometry (icPOCS) were manufactured via the selective electron beam melting technique (SEBM). Depending on the cell dimensions (cell length, strut diameter) and cell orientation in respect to the main axis of the cylindrical structures, the icPOCS investigated in this work exhibit different porosities and/or tortuosities. The structures were characterized with respect to their morphological and geometrical parameters such as strut and cell dimension, specific surface area, and porosity using different techniques (e.g., micro-computed tomography and helium pycnometry). Additionally, a model for the calculation of the specific surface area is presented which takes surface roughness into account. The model enables the determination of the specific surface area on the basis of only two geometrical parameters, i.e., the strut diameter and the cell length, which are both easy to determine for such highly regular open cellular structures. The pressure drop of the icPOCS was measured with air as working fluid. A correlation allowing for the prediction of the pressure drop of icPOCS was developed based on the Ergun equation in its basic form. The presented correlation reflects the porosity and cell orientation and is solely based on the geometric properties of the structures. As the correlation does not rely on the use of empirical fitting parameters it is fully predictive.

[1]  Jacob A. Moulijn,et al.  Structured Catalysts and Reactors , 2005 .

[2]  B. Kraushaar-Czarnetzki,et al.  Ceramic Foam Monoliths as Catalyst Carriers. 1. Adjustment and Description of the Morphology , 2003 .

[3]  R. Singer,et al.  Periodic open-cell foams: Pressure drop measurements and modeling of an ideal tetrakaidecahedra packing , 2011 .

[4]  David Edouard,et al.  Pressure drop measurements and modeling on SiC foams , 2007 .

[5]  Bettina Kraushaar-Czarnetzki,et al.  CO oxidation over structured carriers : A comparison of ceramic foams, honeycombs and beads , 2007 .

[6]  Bettina Kraushaar-Czarnetzki,et al.  Mass transfer and pressure drop in ceramic foams: A description for different pore sizes and porosities , 2008 .

[7]  Enrico Bianchi,et al.  An appraisal of the heat transfer properties of metallic open-cellfoams for strongly exo-/endo-thermic catalytic processes in tubular reactors , 2012 .

[8]  H. Freund,et al.  Determining the specific surface area of ceramic foams: The tetrakaidecahedra model revisited , 2011 .

[9]  B. Kraushaar-Czarnetzki,et al.  Preparation and characterization of ceramic foam supported nanocrystalline zeolite catalysts , 2001 .

[10]  Michael Stingl,et al.  Mechanical characterisation of a periodic auxetic structure produced by SEBM , 2012 .

[11]  S. Pratsinis,et al.  Ceramic foams directly-coated with flame-made V2O5/TiO2 for synthesis of phthalic anhydride , 2006 .

[12]  Dimos Poulikakos,et al.  Metal foams as compact high performance heat exchangers , 2003 .

[13]  R. Singer,et al.  Design of Auxetic Structures via Mathematical Optimization , 2011, Advanced materials.

[14]  Changying Zhao Review on thermal transport in high porosity cellular metal foams with open cells , 2012 .

[15]  T. Lu,et al.  Heat transfer in open-cell metal foams , 1998 .

[16]  Enrico Bianchi,et al.  Heat transfer properties of metal foam supports for structured catalysts: Wall heat transfer coefficient , 2013 .

[17]  Suresh T. Gulati,et al.  The application of monoliths for gas phase catalytic reactions , 2001 .

[18]  Howard P. Hodson,et al.  Measurement and interpretation of the heat transfer coefficients of metal foams , 2005 .

[19]  Matthias Kind,et al.  Pressure drop measurements of ceramic sponges—Determining the hydraulic diameter , 2009 .

[20]  Jimmie L. Williams,et al.  Monolith structures, materials, properties and uses , 2001 .

[21]  R. M. Fand,et al.  Resistance to the Flow of Fluids Through Simple and Complex Porous Media Whose Matrices Are Composed of Randomly Packed Spheres , 1987 .

[22]  R. Singer,et al.  Process specific catalyst supports—Selective electron beam melted cellular metal structures coated with microporous carbon , 2012 .

[23]  J. P. D. Plessis Saturated crossflow through a two-dimensional porous medium , 1991 .

[24]  Robert F. Singer,et al.  Cellular Titanium by Selective Electron Beam Melting , 2007 .

[25]  H. Freund,et al.  Predicting the Specific Surface Area and Pressure Drop of Reticulated Ceramic Foams Used as Catalyst Support , 2011 .

[26]  Mostafa Odabaee,et al.  Metal foam heat exchangers for heat transfer augmentation from a tube bank , 2012 .

[27]  O. Harrysson,et al.  Direct metal fabrication of titanium implants with tailored materials and mechanical properties using electron beam melting technology , 2008 .

[28]  B. Dietrich Pressure drop correlation for ceramic and metal sponges , 2012 .

[29]  K. Hooman,et al.  A Theoretical Model with Experimental Verification to Predict Hydrodynamics of Foams , 2013, Transport in Porous Media.

[30]  Jouane Ahmed,et al.  A predictive model based on tortuosity for pressure drop estimation in ‘slim’ and ‘fat’ foams , 2011 .

[31]  N. Dukhan Correlations for the pressure drop for flow through metal foam , 2006 .

[32]  G. Groppi,et al.  Mass-Transfer Characterization of Metallic Foams as Supports for Structured Catalysts , 2005 .

[33]  S. Ergun Fluid flow through packed columns , 1952 .

[34]  H. Martin,et al.  Morphological Characterization of Ceramic Sponges for Applications in Chemical Engineering , 2009 .

[35]  F. Patcas The methanol-to-olefins conversion over zeolite-coated ceramic foams , 2005 .

[36]  S. Mullens,et al.  The benefit of design of support architectures for zeolite coated structured catalysts for methanol-to-olefin conversion , 2013 .

[37]  S. Ergun,et al.  Fluid Flow through Randomly Packed Columns and Fluidized Beds , 1949 .

[38]  David Edouard,et al.  Pressure drop modeling on SOLID foam: State-of-the art correlation , 2008 .

[39]  J. Richardson,et al.  Properties of ceramic foam catalyst supports: pressure drop , 2000 .

[40]  J. Vicente,et al.  Volume Image Analysis of Ceramic Sponges , 2008 .