Performance of dye-sensitized solar cells fabricated with extracts from fruits of ivy gourd and flowers of red frangipani as sensitizers.

Natural dyes extracted from fruits of ivy gourd and flowers of red frangipani were used as sensitizers to fabricate dye sensitized solar cells (DSSCs). The UV-Vis absorption spectroscopy, Fourier transform infrared (FTIR), Fourier transform Raman (FT-Raman) and liquid chromatography-mass spectrometry (LC-MS) studies indicated the presence of β-carotene in the fruits of ivy gourd and anthocyanins in the flowers of red frangipani. The extract of the flowers of red frangipani exhibits higher photosensitized performance compared to the fruits of ivy gourd and this is due to the better charge transfer between the dyes of flowers of red frangipani and the TiO(2) photoanode surface.

[1]  Elena Vigil,et al.  Nanocrystalline TiO2 photosensitized with natural polymers with enhanced efficiency from 400 to 600 nm , 2005 .

[2]  Michael Grätzel,et al.  Highly efficient and thermally stable organic sensitizers for solvent-free dye-sensitized solar cells. , 2008, Angewandte Chemie.

[3]  Greg P. Smestad,et al.  Ultrafast Electron Injection: Implications for a Photoelectrochemical Cell Utilizing an Anthocyanin Dye-Sensitized TiO2 Nanocrystalline Electrode , 1997 .

[4]  Da-Wen Sun,et al.  Modern Techniques for Food Authentication , 2008 .

[5]  A. Magnani,et al.  Increasing photostability and water-solubility of carotenoids: synthesis and characterization of β-carotene-humic acid complexes. , 2010, Journal of photochemistry and photobiology. B, Biology.

[6]  Masayuki Okuya,et al.  Shiso leaf pigments for dye-sensitized solid-state solar cell , 2006 .

[7]  Masaki Murayama,et al.  Utilization of natural carotenoids as photosensitizers for dye-sensitized solar cells , 2007 .

[8]  B W Beadle,et al.  THE PREPARATION AND ABSORPTION SPECTRA OF FIVE PURE CAROTENOID PIGMENTS. , 1942, Plant physiology.

[9]  M. Grätzel Dye-sensitized solar cells , 2003 .

[10]  M. Graetzel,et al.  Artificial photosynthesis. 1. Photosensitization of titania solar cells with chlorophyll derivatives and related natural porphyrins , 1993 .

[11]  J. Rabani,et al.  Photosensitization of nanocrystalline TiO2 films by anthocyanin dyes , 2002 .

[12]  H. Tributsch,et al.  Parameters determining efficiency and degradation of TiO2|dye|CuI solar cells , 2004 .

[13]  Ø. M. Andersen,et al.  Anthocyanins from ornamental flowers of red frangipani, Plumeria rubra , 2011 .

[14]  W. Xu,et al.  New Triphenylamine-Based Dyes for Dye-Sensitized Solar Cells , 2008 .

[15]  H. Edwards,et al.  The effect of spectral resolution on the Raman spectra of polyaromatic hydrocarbons and beta-carotene mixtures , 2011 .

[16]  M. Grätzel,et al.  A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films , 1991, Nature.

[17]  K. Tennakone,et al.  Nano-porous solid-state photovoltaic cell sensitized with tannin , 1998 .

[18]  D. Kuang,et al.  Performance of dye-sensitized solar cells based on novel sensitizers bearing asymmetric double D−π−A chains with arylamines as donors , 2012 .

[19]  Milin Zhang,et al.  From salmon pink to blue natural sensitizers for solar cells: Canna indica L., Salvia splendens, cowberry and Solanum nigrum L. , 2009, Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy.

[20]  S. Karthick,et al.  Performance of Kerria japonica and Rosa chinensis flower dyes as sensitizers for dye-sensitized solar cells. , 2012, Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy.

[21]  U. Goldbourt,et al.  Plants in human health and nutrition policy. , 2003 .

[22]  Qing Wang,et al.  Highly Efficient Porphyrin Sensitizers for Dye-Sensitized Solar Cells , 2007 .

[23]  Sumaeth Chavadej,et al.  Dye-sensitized solar cell using natural dyes extracted from rosella and blue pea flowers , 2007 .

[24]  N. M. Iha,et al.  Blue sensitizers for solar cells: Natural dyes from Calafate and Jaboticaba , 2006 .

[25]  K. D. Seo,et al.  A desirable hole-conducting coadsorbent for highly efficient dye-sensitized solar cells through an organic redox cascade strategy. , 2011, Chemistry.

[26]  Annabella Selloni,et al.  Influence of the sensitizer adsorption mode on the open-circuit potential of dye-sensitized solar cells. , 2007, Nano letters.

[27]  Seeram Ramakrishna,et al.  Metal Oxides for Dye-Sensitized Solar Cells , 2009 .

[28]  Jae Kwan Lee,et al.  Molecular engineering of organic sensitizers for solar cell applications. , 2006, Journal of the American Chemical Society.

[29]  Michael Grätzel,et al.  Highly efficient mesoscopic dye-sensitized solar cells based on donor-acceptor-substituted porphyrins. , 2010, Angewandte Chemie.

[30]  Yunfang Huang,et al.  Natural dyes as photosensitizers for dye-sensitized solar cell , 2006 .

[31]  Gerko Oskam,et al.  Dye-sensitized solar cells with natural dyes extracted from achiote seeds , 2010 .

[32]  E. Kaxiras,et al.  Natural dyes adsorbed on TiO2 nanowire for photovoltaic applications: enhanced light absorption and ultrafast electron injection. , 2008, Nano letters.