Geographical controls and anthropogenic impacts on dissolved organic carbon from mountainous rivers: Insights from optical properties and carbon isotopes

. Mountainous rivers (MRs) are one of the critical systems in transporting dissolved organic carbon (DOC) from terrestrial environments to downstream ecosystems. However, how geographical factors and anthropogenic impacts control the composition and export of DOC in mountainous rivers remains largely unclear. Here, we explore DOC dynamics in three 15 subtropical mountainous catchments (i.e., the Yinjiang, Shiqian, and Yuqing catchments) in southwest China which are highly influenced by anthropogenic activities. Water chemistry, stable and radioactive carbon isotopes of DOC (δ 13 C DOC and Δ 14 C DOC ) and optical properties (UV absorbance and fluorescence spectra) for river water were employed to assess the biogeochemical processes and controlling factors of DOC. The radiocarbon ages of the DOC in the Yinjiang River varied widely, ranging from 928 years before present to modern. Both allochthonous and autochthonous sources had an important 20 effect on riverine DOC export. Results from carbon isotopes suggested that in-stream processing of POC is also an important source of DOC. DOC in catchments with higher slope gradients and lower annual air temperature was characterized by lower concentration and more aromatic, which was distinct from those with gentle slopes and higher temperature. Variabilities in DOC concentrations and δ 13 C DOC were also explained by land use, showing that higher DOC concentrations with 13 C-depleted characters were observed in urban and agricultural land use areas. Moreover, DOM was less aromatic, less 25 recently produced and had a higher degree of humification in catchments with a higher proportion of urban and agricultural land use area. This research highlights the significance of incorporating geographical controls and anthropogenic impacts into the MRs to better understand their DOC dynamics and quality of dissolved organic matter (DOM).

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