Sandstone alterations triggered by fire-related temperatures

Abstract The aim of the study was to identify and describe changes in two different sandstone types when undergoing different environmental and extreme temperature regimes to assess the possibility of finding insolation weathering and how these sandstones would behave during and after a fire. The first step was the simulation in the laboratory of temperature regimes up to 60 °C which would correspond to extreme events that could be found in insolation cycles even in Central Europe and the second one was the temperature above 200 °C simulating in laboratory conditions the thermal regime of a potential fire situation at temperatures up to 200, 400, 600 and 800 °C. Heating the samples above 400 °C led to gradual changes in mineral composition, colour, surface roughness and physical properties reaching, eventually, total rock breakdown through spalling and granular disaggregation. The different behaviour of sandstones exposed to high temperatures is mainly caused by their different mineral composition with various ratios of minerals that are more or less chemically stable at high temperatures as well as by the differences in the porosity.

[1]  Kevin Hall,et al.  The thermal responses of rock art pigments: Implications for rock art weathering in southern Africa , 2007 .

[2]  Carlos Molpeceres,et al.  Calentamiento por láser: una técnica mínimamente invasiva para el estudio del calentamiento producido por el fuego en materiales pétreos de construcción , 2008 .

[3]  M. Gómez-Heras,et al.  Experimental studies of near-surface temperature cycling and surface wetting of stone and its implications for salt weathering , 2008 .

[4]  Erhard M. Winkler,et al.  Stone in Architecture , 1994 .

[5]  É. Kristóf-Makó,et al.  The effect of mechanical treatment on the crystal structure and thermal decomposition of dolomite , 1999 .

[6]  Birbhushan Chakrabarti,et al.  Effect of fire damage on natural stonework in buildings , 1996 .

[7]  J. M. Logan,et al.  A case study of the properties of marble as building veneer , 1993 .

[8]  Rafael Fort,et al.  Influence of surface heterogeneities of building granite on its thermal response and its potential for the generation of thermoclasty , 2008 .

[9]  Robert S. Boynton Chemistry and Technology of Lime and Limestone , 1966 .

[10]  Siegfried Siegesmund,et al.  Physical weathering of marbles caused by anisotropic thermal expansion , 2000 .

[11]  Ákos Török,et al.  Evolution of porosity in Hungarian building stones after simulated burning , 2006 .

[12]  G. Simmons,et al.  The effect of cracks on the thermal expansion of rocks , 1977 .

[13]  Raymond Siever,et al.  Sand and sandstone , 1972 .

[14]  Amélia Dionísio,et al.  Clay minerals and iron oxides-oxyhydroxides as fingerprints of firing effects in a limestone monument , 2009 .

[15]  Erhard M. Winkler,et al.  Stone in Architecture: Properties, Durability , 2013 .

[16]  Amélia Dionísio,et al.  Stone decay induced by fire on historic buildings: the case of the cloister of Lisbon Cathedral (Portugal) , 2007, Geological Society, London, Special Publications.

[17]  Patricia Warke,et al.  A legacy of mistreatment: conceptualizing the decay of medieval sandstones in NE Ireland , 2010 .

[18]  V. Farmer The Infrared spectra of minerals , 1974 .

[19]  K. Hall,et al.  Rock albedo and monitoring of thermal conditions in respect of weathering: some expected and some unexpected results , 2005 .

[20]  M. Hajpál,et al.  Einfluss von Temperaturänderungen auf die mineralogischen und physikalischen Eigenschaften von Sandstein. Ergebnisse von Untersuchungen im Labor / Effect of Temperature Changes on the Mineralogy and Physical Properties of Sandstones. A Laboratory Study , 2005 .

[21]  Á. Török,et al.  Mineralogical and colour changes of quartz sandstones by heat , 2004 .

[22]  B. R. Stanmore,et al.  Review—calcination and carbonation of limestone during thermal cycling for CO2 sequestration , 2005 .

[23]  Patricia Warke,et al.  Exploitation of inherited weakness in fire-damaged building sandstone: the ‘fatiguing’ of ‘shocked’ stone , 2010 .

[24]  A. Goudie,et al.  The relations between modulus of elasticity and temperature in the context of the experimental simulation of rock weathering by fire , 1992 .

[25]  S. Siegesmund,et al.  Decay of natural stones caused by fire damage , 2007, Geological Society, London, Special Publications.

[26]  Bernard Smith,et al.  Impacts of Fire on Stone-Built Heritage , 2009 .

[27]  Kevin Hall,et al.  Light penetration into Clarens sandstone and implications for deterioration of San rock art , 2010 .

[28]  Ákos Török,et al.  Effect of Temperature Changes on the Mineralogy and Physical Proper- ties of Sandstones. A Laboratory Study. , 2005 .

[29]  P. Komadel,et al.  Baseline studies of the clay minerals society source clays: Infrared methods , 2001 .

[30]  L. P. Sarma,et al.  Thermal expansion of a few Indian granitic rocks , 1980 .

[31]  Mónika Hajpál,et al.  Changes in Sandstones of Historical Monuments Exposed to Fire or High Temperature , 2002 .

[32]  S. Kourkoulis Fracture and Failure of Natural Building Stones , 2006 .

[33]  Jürgen Göske,et al.  Fire damage of trachyte: investigations of the Teplá monastery building stones , 2010 .