Study of the thermomechanical and electrical properties of conducting composites containing natural rubber and carbon black

This work shows the preparation and characterization of composites obtained by mixing natural rubber (NR) and carbon black (CB) in different percentages aiming suitable mechanical properties, processability and electrical conductivity for future applications as transducers in pressure sensors. The composites NR/CB are characterized through dc conductivity, thermal analysis using differential scanning calorimetry (DSC), dynamic mechanical thermal analysis (DMA), thermogravimetry (TGA) and stress-strain test. The electrical conductivity changed from 10/sup -9/ to 10 Sm/sup -1/ depending on the percentage of CB in the composite. Besides, it was found a linear (and reversible) dependence of the conductivity on the applied pressure in the range from 0 to 1.6 MPa for the sample 80/20 (NR/CB wt%).

[1]  E. Sichel,et al.  Carbon black-polymer composites : the physics of electrically conducting composites , 1982 .

[2]  R. L. Elsenbaumer,et al.  Handbook of conducting polymers , 1986 .

[3]  J. C. Bevington European polymer journal: A brief history , 1988 .

[4]  R. Newnham,et al.  Critical Volume Fractions in Conductive Composites , 1992 .

[5]  A. Subramaniam,et al.  The chemistry of natural rubber latex , 1995 .

[6]  Hao Tang,et al.  Studies on the electrical conductivity of carbon black filled polymers , 1996 .

[7]  M. H. Ali,et al.  Percolation concept and the electrical conductivity of carbon black-polymer composites 2: Non-crystallisable chloroprene rubber mixed with HAF carbon black , 1997 .

[8]  Jaromír Volf,et al.  Using of tactile transducer for pressure-distribution measurement on the sole of the foot , 1997 .

[9]  T. K. Chaki,et al.  The change in conductivity of a rubber-carbon black composite subjected to different modes of pre-strain , 1998 .

[10]  S. Iijima,et al.  Electrical and elastic properties of conductor-polymer composites , 1999 .

[11]  P. Ghosh,et al.  Conducting carbon black filled EPDM vulcanizates: assessment of dependence of physical and mechanical properties and conducting character on variation of filler loading , 2000 .

[12]  Yadong Jiang,et al.  Morphology and gas-sensitive properties of polymer based composite films , 2000 .

[13]  Neri Alves,et al.  Conductive composites of natural rubber and carbon black for pressure sensors , 2003 .