Performance evaluation of reverse osmosis (RO) pre-treatment technologies for in-land brackish water treatment

Integration of renewable energy with desalination technologies has emerged as an attractive solution to augment fresh water supply sustainably. Fouling and scaling are still considered as limiting factors in membrane desalination processes. For brackish water treatment, pre-treatment of reverse osmosis (RO) feed water is a key step in designing RO plants avoiding membrane fouling. This study aims to compare at pilot scale the rejection efficiency of RO membranes with multiple pre-treatment options at different water recoveries (30, 35, 40, 45 and 50%) and TDS concentrations (3500, 4000, and 4500mg/L). Synthetic brackish water was prepared and performance evaluation were carried out using brackish water reverse osmosis (BWRO) membranes (Filmtec LC-LE-4040 and Hydranautics CPA5-LD-4040) preceded by 5 and 1μm cartridge filters, 0.02μm ultra-filtration (UF) membrane, and forward osmosis (FO) membrane using 0.25M NaCl and MgCl2 as draw solutions (DS). It was revealed that FO membrane with 0.25M MgCl2 used as a draw solution (DS) and Ultra-filtration (UF) membrane followed by Filmtec membrane gave overall 98% rejection but UF facing high fouling potential due to high applied pressure. Use of 5 and 1μm cartridge filter prior to Filmtec membrane also showed effective results with 95% salt rejection.

[1]  M. Pérez,et al.  Comparison of MF/UF pretreatment with conventional filtration prior to RO membranes for surface seawater desalination , 2002 .

[2]  Benny D. Freeman,et al.  Reverse osmosis desalination: water sources, technology, and today's challenges. , 2009, Water research.

[3]  Noreddine Ghaffour,et al.  Technical review and evaluation of the economics of water desalination: Current and future challenges for better water supply sustainability , 2013 .

[4]  Jack Gilron,et al.  Seawater desalination for agriculture by integrated forward and reverse osmosis: Improved product water quality for potentially less energy , 2012 .

[5]  A. Hamou,et al.  Performance evaluation of BWRO desalination plant - a case study. , 2009 .

[6]  J. C. van Dijk,et al.  Zero liquid discharge: Heading for 99% recovery in nanofiltration and reverse osmosis , 2009 .

[7]  M. Pontiéa,et al.  Novel approach combining physico-chemical characterizations and mass transfer modelling of nanofiltration and low pressure reverse osmosis membranes for brackish water desalination intensification , 2007 .

[8]  Ahmad Fauzi Ismail,et al.  Seawater Reverse Osmosis (SWRO) desalination by thin-film composite membrane—Current development, challenges and future prospects , 2012 .

[9]  L. Zou,et al.  Using FO as pre-treatment of RO for high scaling potential brackish water: Energy and performance optimisation , 2015 .

[10]  Tzahi Y Cath,et al.  A comparative life cycle assessment of hybrid osmotic dilution desalination and established seawater desalination and wastewater reclamation processes. , 2012, Water research.

[11]  Noreddine Ghaffour,et al.  Capacity building strategies and policy for desalination using renewable energies in Algeria , 2009 .

[12]  Graeme Pearce SWRO pre-treatment: Markets and experience , 2010 .

[13]  Abul Kalam Hossain,et al.  Development of an integrated reverse osmosis-greenhouse system driven by solar photovoltaic generators , 2010 .

[14]  M. N. Bhutta,et al.  Prospective and limits of groundwater use in Pakistan , 2006 .

[15]  Abel Riaza,et al.  Comparative study of brine management technologies for desalination plants , 2014 .

[16]  Ali Altaee,et al.  High recovery rate NF–FO–RO hybrid system for inland brackish water treatment , 2015 .

[17]  Philip Davies,et al.  Comparison of Configurations for High-Recovery Inland Desalination Systems , 2012 .

[18]  Michael Flynn,et al.  Membrane contactor processes for wastewater reclamation in space Part I. Direct osmotic concentration as pretreatment for reverse osmosis , 2005 .

[19]  Bjarne Nicolaisen,et al.  Developments in membrane technology for water treatment , 2003 .

[20]  J. Croué,et al.  A comparative study of boron and arsenic (III) rejection from brackish water by reverse osmosis membranes , 2013 .

[21]  Amy E. Childress,et al.  Forward osmosis: Principles, applications, and recent developments , 2006 .

[22]  Carlos Garcia,et al.  7 year operation of a BWRO plant with raw water from a coastal aquifer for agricultural irrigation , 2011 .

[23]  Joseph Alcamo,et al.  21 issues for the 21st Century: results of the UNEP Foresight Process on Emerging Environmental issues , 2012 .

[24]  D.J.H. Harmsen,et al.  Membrane fouling and process performance of forward osmosis membranes on activated sludge , 2008 .

[25]  Tzahi Y Cath,et al.  Forward osmosis for concentration of anaerobic digester centrate. , 2007, Water research.

[26]  Noreddine Ghaffour,et al.  The challenge of capacity-building strategies and perspectives for desalination for sustainable water use in MENA , 2009 .

[27]  Robert L McGinnis,et al.  Desalination by ammonia–carbon dioxide forward osmosis: Influence of draw and feed solution concentrations on process performance , 2006 .

[28]  Soteris A. Kalogirou,et al.  Seawater desalination using renewable energy sources , 2005 .

[29]  M. S. Gadiwala,et al.  Empirical Models for the Estimation of Global Solar Radiation with Sunshine Hours on Horizontal Surface in Various Cities of Pakistan , 2013 .

[30]  J. Ruijter,et al.  Desalination of brackish groundwater and concentrate disposal by deep well injection , 2013 .

[31]  Himanshu Joshi,et al.  Optimization and economic analysis of small scale nanofiltration and reverse osmosis brackish water system powered by photovoltaics , 2014 .

[32]  Chuyang Y. Tang,et al.  Removal of boron and arsenic by forward osmosis membrane: Influence of membrane orientation and organic fouling , 2012 .

[33]  Shadi W. Hasan,et al.  A short review on reverse osmosis pretreatment technologies , 2014 .

[34]  Kai Yu Wang,et al.  Polybenzimidazole (PBI) nanofiltration hollow fiber membranes applied in forward osmosis process , 2007 .

[35]  Tzahi Y. Cath,et al.  Membrane contactor processes for wastewater reclamation in space: II. Combined direct osmosis, osmotic distillation, and membrane distillation for treatment of metabolic wastewater , 2005 .