The evaluation of alternative thermochemical cycles – Part II: The down-selection process

The Nuclear Hydrogen Initiative (NHI) of the U.S. Department of Energy's Office of Nuclear Energy Science and Technology is supporting an effort to reevaluate thermochemical cycles reported in the literature as having both promising efficiencies and proof-of-concept results. Nine cycles were identified. A group of universities was tasked with the evaluation of these cycles using the NHI consistent methodology for calculating efficiency and for recommending and conducting critical research needed to help in the down-selection process. Argonne National Laboratory coordinated these activities. This paper provides an overview of the program and summarizes the results of the down-selection process. Individual papers that contain the details of the research are provided by the universities.

[1]  R. J. Remick,et al.  A hybrid water-splitting cycle using copper sulfate and mixed copper oxides , 1980 .

[2]  K. F. Knoche,et al.  Feasibility studies of chemical reactions for thermochemical water splitting cycles of the iron-chlorine, iron-sulfur and manganese-sulfur families , 1977 .

[3]  K. F. Knoche,et al.  Thermochemical production of hydrogen by a vanadium/chlorine cycle. Part 2: Experimental investigation of the individual reactions , 1984 .

[4]  Michele A. Lewis,et al.  Evaluation of alternative thermochemical cycles - Part I the methodology. , 2009 .

[5]  Yuji Shindo,et al.  Kinetics of the catalytic decomposition of hydrogen iodide in the thermochemical hydrogen production , 1984 .

[6]  Michele A. Lewis,et al.  Evaluation of alternative thermochemical cycles-part III further development of the Cu-Cl cycle. , 2009 .

[7]  Atsushi Tsutsumi,et al.  Solar UT-3 thermochemical cycle for hydrogen production , 1996 .

[8]  Kunio Yoshida Present Status of R&D for Thermochemical Hydrogen Production. , 1991 .

[9]  K. F. Knoche,et al.  Thermochemical production of hydrogen by a vanadium/chlorine cycle. Part 1: An energy and exergy analysis of the process , 1984 .

[10]  Kinjiro Fujii,et al.  The thermochemical decomposition of water using bromine and iodine , 1978 .

[11]  J. Pangborn,et al.  Experimental demonstration of an iron chloride thermochemical cycle for hydrogen production , 1976 .

[12]  James E. Funk,et al.  Thermochemical hydrogen production , 1987 .

[13]  Nigel P. Brandon,et al.  A critical pathway energy efficiency analysis of the thermochemical UT-3 cycle , 2005 .

[14]  John W. Weidner,et al.  Electrochemical hydrogen production from thermochemical cycles using a proton exchange membrane electrolyzer , 2007 .