Attribution and evolution of ozone from Asian wild fires using satellite and aircraft measurements during the ARCTAS campaign

Abstract. We use ozone and carbon monoxide measurements from the Tropospheric Emission Spectrometer (TES), model estimates of Ozone, CO, and ozone pre-cursors from the Real-time Air Quality Modeling System (RAQMS), and data from the NASA DC8 aircraft to characterize the source and dynamical evolution of ozone and CO in Asian wildfire plumes during the spring ARCTAS campaign 2008. On the 19 April, NASA DC8 O 3 and aerosol Differential Absorption Lidar (DIAL) observed two biomass burning plumes originating from North-Western Asia (Kazakhstan) and South-Eastern Asia (Thailand) that advected eastward over the Pacific reaching North America in 10 to 12 days. Using both TES observations and RAQMS chemical analyses, we track the wildfire plumes from their source to the ARCTAS DC8 platform. In addition to photochemical production due to ozone pre-cursors, we find that exchange between the stratosphere and the troposphere is a major factor influencing O 3 concentrations for both plumes. For example, the Kazakhstan and Siberian plumes at 55 degrees North is a region of significant springtime stratospheric/tropospheric exchange. Stratospheric air influences the Thailand plume after it is lofted to high altitudes via the Himalayas. Using comparisons of the model to the aircraft and satellite measurements, we estimate that the Kazakhstan plume is responsible for increases of O 3 and CO mixing ratios by approximately 6.4 ppbv and 38 ppbv in the lower troposphere (height of 2 to 6 km), and the Thailand plume is responsible for increases of O 3 and CO mixing ratios of approximately 11 ppbv and 71 ppbv in the upper troposphere (height of 8 to 12 km) respectively. However, there are significant sources of uncertainty in these estimates that point to the need for future improvements in both model and satellite observations. For example, it is challenging to characterize the fraction of air parcels from the stratosphere versus those from the fire because of the low sensitivity of the TES CO estimates used to mark stratospheric air versus air parcels affected by the smoke plume. Model transport uncertainties, such as too much dispersion, results in a broad plume structure from the Kazakhstan fires that is approximately 2 km lower than the plume observed by aircraft. Consequently, the model and TES data do not capture the photochemical production of ozone in the Kazakhstan plume that is apparent in the aircraft in situ data. However, ozone and CO distributions from TES and RAQMS model estimates of the Thailand plume are within the uncertainties of the TES data. Therefore, the RAQMS model is better able to characterize the emissions from this fire, the mixing of ozone from the stratosphere to the plume, and the photochemical production and transport of ozone and ozone pre-cursors as the plume moves across the Pacific.

[1]  Glenn E. Shaw,et al.  The Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) mission: design, execution, and first results , 2010 .

[2]  Susan S. Kulawik,et al.  Lightning NO x emissions over the USA constrained by TES ozone observations and the GEOS-Chem model , 2010 .

[3]  Glenn S. Diskin,et al.  Source attribution and interannual variability of Arctic pollution in spring constrained by aircraft (ARCTAS, ARCPAC) and satellite (AIRS) observations of carbon monoxide , 2009 .

[4]  John C. Gille,et al.  A global comparison of carbon monoxide profiles and column amounts from Tropospheric Emission Spectrometer (TES) and Measurements of Pollution in the Troposphere (MOPITT) , 2009 .

[5]  Dylan B. A. Jones,et al.  Observed vertical distribution of tropospheric ozone during the Asian summertime monsoon , 2009 .

[6]  Dylan B. A. Jones,et al.  The zonal structure of tropical O 3 and CO as observed by the Tropospheric Emission Spectrometer in November 2004 – Part 2: Impact of surface emissions on O 3 and its precursors , 2009 .

[7]  Dylan B. A. Jones,et al.  The zonal structure of tropical O 3 and CO as observed by the Tropospheric Emission Spectrometer in November 2004 – Part 1: Inverse modeling of CO emissions , 2009 .

[8]  K. Sudo,et al.  Temporal and spatial variations of carbon monoxide over the western part of the Pacific Ocean , 2009 .

[9]  Jassim A. Al-Saadi,et al.  Impacts of background ozone production on Houston and Dallas, Texas, air quality during the Second Texas Air Quality Study field mission , 2009 .

[10]  Dylan B. A. Jones,et al.  Analysis of the summertime buildup of tropospheric ozone abundances over the Middle East and North Africa as observed by the Tropospheric Emission Spectrometer instrument , 2009 .

[11]  Dylan B. A. Jones,et al.  Ozone production in boreal fire smoke plumes using observations from the Tropospheric Emission Spectrometer and the Ozone Monitoring Instrument , 2009 .

[12]  Joshua P. Schwarz,et al.  Biomass burning in Siberia and Kazakhstan as an important source for haze over the Alaskan Arctic in April 2008 , 2009 .

[13]  Mian Chin,et al.  A multi-model assessment of pollution transport to the Arctic , 2008 .

[14]  David P. Edwards,et al.  CO emission and export from Asia: an analysis combining complementary satellite measurements (MOPITT, SCIAMACHY and ACE-FTS) with global modeling , 2008 .

[15]  Lance E. Christensen,et al.  TES carbon monoxide validation during two AVE campaigns using the Argus and ALIAS instruments on NASA's WB‐57F , 2008 .

[16]  K. Bowman,et al.  Validation of Tropospheric Emission Spectrometer (TES) measurements of the total, stratospheric, and tropospheric column abundance of ozone , 2008 .

[17]  Christine Wiedinmyer,et al.  Intercomparison of near-real-time biomass burning emissions estimates constrained by satellite fire data , 2008 .

[18]  Glenn S. Diskin,et al.  TES carbon monoxide validation with DACOM aircraft measurements during INTEX‐B 2006 , 2007 .

[19]  F. S. Chapin,et al.  Energy feedbacks of northern high‐latitude ecosystems to the climate system due to reduced snow cover during 20th century warming , 2007 .

[20]  R. Martin,et al.  Chemical data assimilation estimates of continental U.S. ozone and nitrogen budgets during the Intercontinental Chemical Transport Experiment–North America , 2007 .

[21]  John Methven,et al.  Processes influencing ozone levels in Alaskan forest fire plumes during long-range transport over the , 2007 .

[22]  Paul W. Stackhouse,et al.  Climate-induced boreal forest change: Predictions versus current observations , 2007 .

[23]  Reinhard Beer,et al.  Comparisons of Tropospheric Emission Spectrometer (TES) ozone profiles to ozonesondes: Methods and initial results , 2007 .

[24]  P. Quinn,et al.  Arctic haze: current trends and knowledge gaps , 2007 .

[25]  H. Worden,et al.  Validation of Tropospheric Emission Spectrometer (TES) nadir ozone profiles , 2008 .

[26]  A. Stohl,et al.  Alaskan and Canadian forest fires exacerbate ozone pollution over Houston, Texas, on 19 and 20 July 2004 , 2006 .

[27]  M. Val Martin,et al.  Significant enhancements of nitrogen oxides, black carbon, and ozone in the North Atlantic lower free troposphere resulting from North American boreal wildfires , 2006 .

[28]  K. Bowman,et al.  Ozone‐CO correlations determined by the TES satellite instrument in continental outflow regions , 2006 .

[29]  J. Randerson,et al.  Interannual variability in global biomass burning emissions from 1997 to 2004 , 2006 .

[30]  A. Stohl.  Characteristics of atmospheric transport into the Arctic troposphere , 2006 .

[31]  G. Pfister,et al.  Evidence of significant large‐scale impacts of boreal fires on ozone levels in the midlatitude Northern Hemisphere free troposphere , 2006 .

[32]  Reinhard Beer,et al.  Tropospheric emission spectrometer: retrieval method and error analysis , 2006, IEEE Transactions on Geoscience and Remote Sensing.

[33]  Reinhard Beer,et al.  TES on the aura mission: scientific objectives, measurements, and analysis overview , 2006, IEEE Transactions on Geoscience and Remote Sensing.

[34]  J. Haywood,et al.  The direct radiative effect of biomass burning aerosols over southern Africa , 2005 .

[35]  A. Stohl,et al.  Extreme CO concentrations in the upper troposphere over northeast Asia in June 2003 from the in situ MOZAIC aircraft data , 2005 .

[36]  J. Lamarque,et al.  Quantifying CO emissions from the 2004 Alaskan wildfires using MOPITT CO data , 2005 .

[37]  Philippe Ciais,et al.  A burning question. Can recent growth rate anomalies in the greenhouse gases be attributed to large-scale biomass burning events? , 2005 .

[38]  E. Vermote,et al.  The MODIS Aerosol Algorithm, Products, and Validation , 2005 .

[39]  I. Bertschi,et al.  Long-range transport of ozone, carbon monoxide, and aerosols to the NE Pacific troposphere during the summer of 2003: Observations of smoke plumes from Asian boreal fires , 2005 .

[40]  P. Novelli,et al.  Influences of boreal fire emissions on Northern Hemisphere atmospheric carbon and carbon monoxide , 2005 .

[41]  J. Hansen,et al.  Distant origins of Arctic black carbon: A Goddard Institute for Space Studies ModelE experiment , 2005 .

[42]  D. Jaffe,et al.  Long‐range transport of Asian pollution to the northeast Pacific: Seasonal variations and transport pathways of carbon monoxide , 2004 .

[43]  Andrew J. Heymsfield,et al.  TOMS observations of increases in Asian aerosol in winter from 1979 to 2000 , 2004 .

[44]  T. Eck,et al.  A review of biomass burning emissions part III: intensive optical properties of biomass burning particles , 2004 .

[45]  Mian Chin,et al.  A three-dimensional regional modeling study of the impact of clouds on sulfate distributions during TRACE-P , 2004 .

[46]  P. Novelli,et al.  Long‐range transport of Siberian biomass burning emissions and impact on surface ozone in western North America , 2004 .

[47]  W. R. Cofer,et al.  Estimating fire emissions and disparities in boreal Siberia (1998–2002) , 2004 .

[48]  Shepard A. Clough,et al.  Predicted errors of tropospheric emission spectrometer nadir retrievals from spectral window selection , 2004 .

[49]  J. Lamarque,et al.  Observations of carbon monoxide and aerosols from the Terra satellite: Northern Hemisphere variability , 2004 .

[50]  Merritt N. Deeter,et al.  Asian Outflow and Trans-Pacific Transport of Carbon Monoxide and Ozone Pollution: An Integrated Satellite, Aircraft, and Model Perspective , 2003 .

[51]  Mian Chin,et al.  A global aerosol model forecast for the ACE-Asia field experiment , 2003 .

[52]  Edward V. Browell,et al.  Regional Air Quality Modeling System (RAQMS) predictions of the tropospheric ozone budget over east Asia , 2003 .

[53]  John C. Gille,et al.  Transport and Chemical Evolution over the Pacific (TRACE-P) aircraft mission: Design, execution, and first results , 2003 .

[54]  Bryan N. Duncan,et al.  Transport pathways for Asian pollution outflow over the Pacific: Interannual and seasonal variations , 2003 .

[55]  A. Stohl,et al.  Atmospheric Chemistry and Physics the North Atlantic Oscillation Controls Air Pollution Transport to the Arctic , 2003 .

[56]  H. Akimoto,et al.  Carbon monoxide, regional‐scale transport, and biomass burning in tropical continental Southeast Asia: Observations in rural Thailand , 2003 .

[57]  P. M. Lang,et al.  Reanalysis of tropospheric CO trends: Effects of the 1997–1998 wildfires , 2003 .

[58]  T. Berntsen,et al.  Modeling the solar radiative impact of aerosols from biomass burning during the Southern African Regional Science Initiative (SAFARI-2000) experiment , 2003 .

[59]  T. Takemura,et al.  Tropospheric aerosol impacts on trace gas budgets through photolysis , 2003 .

[60]  P. Hess,et al.  Seasonal changes in the transport of pollutants into the Arctic troposphere‐model study , 2003 .

[61]  Thomas F. Eck,et al.  Variability of biomass burning aerosol optical characteristics in southern Africa during the SAFARI , 2003 .

[62]  S. Nilsson,et al.  Boreal forest fires in Siberia in 1998: Estimation of area burned and emissions of pollutants by advanced very high resolution radiometer satellite data , 2002 .

[63]  D. Cahoon,et al.  Determining Effects of Area Burned and Fire Severity on Carbon Cycling and Emissions in Siberia , 2002 .

[64]  Alexander Smirnov,et al.  Development of a Global Validation Package for Satellite Oceanic Aerosol Optical Thickness Retrieval Based on AERONET Observations and Its Application to NOAA/NESDIS Operational Aerosol Retrievals. , 2002 .

[65]  Teruyuki Nakajima,et al.  Tropospheric aerosol optical thickness from the GOCART model and comparisons with satellite and sun photometer measurements , 2002 .

[66]  E. Kasischke,et al.  Emissions of carbon dioxide, carbon monoxide, and methane from boreal forest fires in 1998 , 2002 .

[67]  David G. Streets,et al.  The influence of Siberian forest fires on carbon monoxide concentrations at Happo, Japan , 2002 .

[68]  D. Jacob,et al.  Continental sources, transoceanic transport, and interhemispheric exchange of carbon , 2001 .

[69]  D. Blake,et al.  Large-scale air mass characteristics observed over the remote tropical Pacific Ocean during March-April 1999: Results from PEM-Tropics B field experiment , 2001 .

[70]  M. Andreae,et al.  Emission of trace gases and aerosols from biomass burning , 2001 .

[71]  Ulla Wandinger,et al.  Transport of boreal forest fire emissions from Canada , 2001 .

[72]  D. Jacob,et al.  Global modeling of tropospheric chemistry with assimilated meteorology : Model description and evaluation , 2001 .

[73]  David M. Rider,et al.  Tropospheric emission spectrometer for the Earth Observing System’s Aura satellite , 2001 .

[74]  P. M. Lang,et al.  Measurements of an anomalous global methane increase during 1998 , 2001 .

[75]  Hajime Akimoto,et al.  The atmospheric impact of boreal forest fires in far eastern Siberia on the seasonal variation of carbon monoxide: Observations at Rishiri, A northern remote island in Japan , 2000 .

[76]  O. Boucher,et al.  Estimates of the direct and indirect radiative forcing due to tropospheric aerosols: A review , 2000 .

[77]  Eric P. Shettle,et al.  Observations of boreal forest fire smoke in the stratosphere by POAM III, SAGE II, and lidar in 1998 , 2000 .

[78]  Trainer,et al.  The influence of canadian forest fires on pollutant concentrations in the united states , 2000, Science.

[79]  O. Arino,et al.  Verification of the consistency of POLDER Aerosol Index over land with ATSR‐2/ERS‐2 fire product , 2000 .

[80]  R. Waller,et al.  33 – Carbon Monoxide1 , 1999 .

[81]  R. Welch,et al.  Satellite Investigations of Fire, Smoke, and Carbon Monoxide during April 1994 MAPS Mission: Case Studies over Tropical Asia , 1998 .

[82]  P. M. Lang,et al.  Distributions and recent changes of carbon monoxide in the lower troposphere , 1998 .

[83]  P. Novelli,et al.  Total column and surface densities of atmospheric carbon monoxide in Alaska, 1995 , 1998 .

[84]  D. Jacob,et al.  Photochemistry in biomass burning plumes and implications for tropospheric ozone over the tropical South Atlantic , 1998 .

[85]  P. Novelli,et al.  Impact of Asian emissions on the remote North Pacific atmosphere: Interpretation of CO data from Shemya, Guam, Midway and Mauna Loa , 1997 .

[86]  J. Roths,et al.  The tropospheric distribution of carbon monoxide as observed during the Tropoz II experiment , 1996 .

[87]  D. Jacob,et al.  Origin of tropospheric ozone at remote high northern latitudes in summer , 1996 .

[88]  G. Shaw.  The Arctic Haze Phenomenon , 1995 .

[89]  Joel S. Levine,et al.  Satellite analysis of the severe 1987 forest fires in northern China and southeastern Siberia , 1994 .

[90]  J. Putaud,et al.  Rice straw burning in Southeast Asia as a source of CO and COS to the atmosphere , 1994 .

[91]  W. Hao,et al.  Methane production from global biomass burning , 1993 .

[92]  John S. Hoffman,et al.  Methane reductions : implications for global warming and atmospheric chemical change , 1992 .

[93]  Joel S. Levine,et al.  Trace Gas and Particulate Emissions from Biomass Burning in Temperate Ecosystems , 1991 .

[94]  P. Crutzen,et al.  Biomass Burning in the Tropics: Impact on Atmospheric Chemistry and Biogeochemical Cycles , 1990, Science.

[95]  Jack Fishman,et al.  Distribution of tropospheric ozone determined from satellite data , 1990 .

[96]  W. D. Hypes,et al.  Middle and upper tropospheric carbon monoxide mixing ratios as measured by a satellite‐borne remote sensor during November 1981 , 1986 .

[97]  M. Andreae.  Soot Carbon and Excess Fine Potassium: Long-Range Transport of Combustion-Derived Aerosols , 1983, Science.

[98]  S. Wofsy,et al.  Tropospheric chemistry: A global perspective , 1981 .

[99]  P. Hanst,et al.  Peroxyacetyl nitrate (PAN) in the unpolluted atmosphere: An important reservoir for nitrogen oxides , 1981 .

[100]  P. Crutzen,et al.  Estimates of gross and net fluxes of carbon between the biosphere and the atmosphere from biomass burning , 1980 .