Development of a Diversity-Based Approach for the Discovery of Stereoselective Polymerization Catalysts: Identification of a Catalyst for the Synthesis of Syndiotactic Polypropylene This work was supported by the Cornell Center for Materials Research (CCMR), a Materials Research Science and Engineer

[1]  P. Corradini,et al.  CRYSTALLINE HIGH POLYMERS OF α-OLEFINS , 1955 .

[2]  M. Mitani,et al.  Post-Metallocenes: A New Bis(salicylaldiminato) Zirconium Complex for Ethylene Polymerization , 1999 .

[3]  Howard Turner,et al.  Kombinatorische Materialforschung und Katalyse , 1999 .

[4]  van der Linden HJ,et al.  Combinatorial Chemistry for Ligand Development in Catalysis: Synthesis and Catalysis Screening of Peptidosulfonamide Tweezers on the Solid Phase. , 2000, The Journal of organic chemistry.

[5]  R. Fröhlich,et al.  Formation and structural properties of salicylaldiminato complexes of zirconium and titanium , 2000 .

[6]  Thomas R. Boussie,et al.  Festphasensynthese und Kodierung von Katalysatorbibliotheken für Olefinpolymerisationen , 1998 .

[7]  J. Newsam,et al.  Combinatorial approaches as a component of high‐throughput experimentation (HTE) in catalysis research , 1999, Biotechnology and bioengineering.

[8]  M. Brookhart,et al.  Polymerization of Propylene by a New Generation of Iron Catalysts: Mechanisms of Chain Initiation, Propagation, and Termination , 1999 .

[9]  Michael Becker,et al.  Eine Methode zum High‐Throughput‐Screening von enantioselektiven Katalysatoren , 1999 .

[10]  Scott J. Miller,et al.  A Chemosensor-Based Approach to Catalyst Discovery in Solution and on Solid Support , 1999 .

[11]  T. Nakano,et al.  New Bis(salicylaldiminato) Titanium Complexes for Ethylene Polymerization , 1999 .

[12]  M. Brookhart,et al.  Synthesis of a Stereoblock Polyketone through Ancillary Ligand Exchange , 1996 .

[13]  J. Ewen.  Mechanisms of stereochemical control in propylene polymerizations with soluble Group 4B metallocene/methylalumoxane catalysts , 1984 .

[14]  M. Sigman,et al.  A General Catalyst for the Asymmetric Strecker Reaction This work was supported by the NIH (GM-43214). A postdoctoral fellowship to M.S.S. (NIH), and a predoctoral fellowship to P.V. sponsored by Alfred Bader are gratefully acknowledged. , 2000, Angewandte Chemie.

[15]  Kevin Burgess,et al.  Durch Screening ermittelte Katalysatoren und Reaktionsbedingungen für eine C‐H‐Insertionsreaktion , 1996 .

[16]  L. Resconi,et al.  1-olefin polymerization at bis(pentamethylcyclopentadienyl)zirconium and -hafnium centers : enantioface selectivity , 1992 .

[17]  S. Bromidge,et al.  A parallel combinatorial approach to locating homochiral Lewis acid catalysts for the asymmetric aza-Diels-Alder reaction of an imino dienophile , 1998 .

[18]  Eric D. Carlson,et al.  PARALLEL SOLID-PHASE SYNTHESIS, SCREENING, AND ENCODING STRATEGIES FOR OLEFIN-POLYMERIZATION CATALYSTS , 1999 .

[19]  Eric N. Jacobsen,et al.  ENTDECKUNG NEUER KATALYSATOREN FUR DIE ALKENEPOXIDIERUNG DURCH METALLBINDENDE KOMBINATORISCHE BIBLIOTHEKEN , 1999 .

[20]  Y. Doi.  Correlation between Regio- and Syndiotactic Specificity of Soluble Vanadium-Based Catalysts for Propene Polymerization , 1979 .

[21]  G. Coates.  Precise control of polyolefin stereochemistry using single-site metal catalysts. , 2000, Chemical reviews.

[22]  L. Cavallo,et al.  Selectivity in propene polymerization with metallocene catalysts. , 2000, Chemical reviews.

[23]  T. Nakano,et al.  Post-Metallocenes: Catalytic Perfomance of New Bis(salicylaldiminato) Zirconium Complexes for Ethylene Polymerization , 2000 .

[24]  J. Bercaw,et al.  Mechanisms of Stereocontrol for Doubly Silylene-Bridged Cs- and C1-Symmetric Zirconocene Catalysts for Propylene Polymerization. Synthesis and Molecular Structure of Li2[(1,2-Me2Si)2{C5H2-4-(1R,2S,5R-menthyl)}{C5H-3,5-(CHMe2)2)}]·3THF and [(1,2-Me2Si)2{η5-C5H2-4-(1R,2S,5R-menthyl)}{η5-C5H-3,5-(CHMe2 , 1999 .

[25]  H. Kagan.  New screening methodologies or combinatorial chemistry applied to asymmetric catalysts , 1998 .

[26]  Friedhelm Balkenhohl,et al.  KOMBINATORISCHE SYNTHESE NIEDERMOLEKULARER ORGANISCHER VERBINDUNGEN , 1996 .

[27]  Peter Chen,et al.  Rasches Screening von Olefinpolymerisationskatalysator-Bibliotheken durch Elektrospray-Ionisations-Tandem-Massenspektrometrie , 1999 .

[28]  S. Schreiber,et al.  Target-oriented and diversity-oriented organic synthesis in drug discovery. , 2000, Science.

[29]  J. Ellman,et al.  A General Solid-Phase Synthesis Strategy for the Preparation of 2-Pyrrolidinemethanol Ligands , 1995 .

[30]  Kuiling Ding,et al.  Super‐High‐Throughput‐Screening chiraler Liganden und Aktivatoren: asymmetrische Aktivierung chiraler Diol‐Zink‐Katalysatoren durch chirale Stickstoffaktivatoren für die enantioselektive Addition von Diethylzink an Aldehyde , 1999 .

[31]  A. Razavi,et al.  Syndiospecific propylene polymerizations with Group IVB metallocenes. , 1988, Journal of the American Chemical Society.

[32]  I. Pasquon,et al.  Stereospecific Catalysts for the Head-To-Tail Polymerization of Propylene to a Crystalline Syndiotactic Polymer , 1962 .

[33]  J. Bercaw,et al.  A New Class of Zirconocene Catalysts for the Syndiospecific Polymerization of Propylene and Its Modification for Varying Polypropylene from Isotactic to Syndiotactic , 1996 .

[34]  C. Pellecchia,et al.  Syndiotactic-specific polymerization of propene with a Ni-based catalyst , 1996 .

[35]  S. Gilbertson,et al.  The combinatorial synthesis of chiral phosphine ligands , 1996 .

[36]  K. Shimizu,et al.  High‐Throughput Strategies for the Discovery of Catalysts , 1998 .

[37]  Jonathan A. Ellman,et al.  Synthesis and Applications of Small Molecule Libraries. , 1996, Chemical reviews.

[38]  Ken D. Shimizu,et al.  ENTWICKLUNG VON CHIRALEN KATALYSATOREN DURCH KOMBINATORISCHE LIGANDENVARIATION : TI-KATALYSIERTE ENANTIOSELEKTIVE ADDITION VON TMSCN AN MESO-EPOXIDE , 1996 .

[39]  S. Ceccarelli,et al.  Investigation of a New Family of Chiral Ligands for Enantioselective Catalysis via Parallel Synthesis and High-Throughput Screening , 1998 .

[40]  E. Gallo,et al.  (Hydroxyphenyl)oxazoline: a Novel and Remarkably Facile Entry into the Area of Chiral Cationic Alkylzirconium Complexes Which Serve as Polymerization Catalysts , 1995 .