Characterization and Processing of Nanocellulose Thermosetting Composites

Fiber-reinforced polymer composites have gained popularity through their advantages over conventional metallic materials. Most polymer composites are traditionally made with reinforcing fibers such as carbon or glass. However, there has been recent interest in sourcing these reinforcing fibers from renewable, natural resources. Nanocellulose-based reinforcements constitute a new class of these naturally sourced reinforcements. Some unique behavior of nanocellulose creates both opportunities and challenges. This chapter reviews the progress and some of the remaining issues related to the materials, processing, and performance of nanocellulose reinforced thermosetting composites.

[1]  S. Eichhorn Cellulose nanowhiskers: promising materials for advanced applications , 2011 .

[2]  J. Araki,et al.  Characterization of the poly(vinyl alcohol)/cellulose whisker gel spun fibers , 2011 .

[3]  A. Błędzki,et al.  Composites reinforced with cellulose based fibres , 1999 .

[4]  H. Yano,et al.  Optically transparent nanofiber sheets by deposition of transparent materials: A concept for a roll-to-roll processing , 2009 .

[5]  Shigenori Kuga,et al.  Surface acylation of cellulose whiskers by drying aqueous emulsion. , 2006, Biomacromolecules.

[6]  A. Błędzki,et al.  Processing techniques for natural- and wood-fibre composites , 2008 .

[7]  R. El-Hajjar,et al.  Mechanical characterization of cellulose nanofiber and bio-based epoxy composite , 2012 .

[8]  A. Hult,et al.  Surface grafting of microfibrillated cellulose with poly(e-caprolactone) - Synthesis and characterization , 2008 .

[9]  J. Seppälä,et al.  Effect of moisture on electrospun nanofiber composites of poly(vinyl alcohol) and cellulose nanocrystals. , 2010, Biomacromolecules.

[10]  Kristin Syverud,et al.  Strength and barrier properties of MFC films , 2009 .

[11]  M. Skrifvars,et al.  Development of Flax Fibre based Textile Reinforcements for Composite Applications , 2006 .

[12]  N. Uddin Blast protection of civil infrastructures and vehicles using composites , 2010 .

[13]  A. N. Nakagaito,et al.  Optically transparent bionanofiber composites with low sensitivity to refractive index of the polymer matrix , 2005 .

[14]  L. Heux,et al.  Nonflocculating and Chiral-Nematic Self-ordering of Cellulose Microcrystals Suspensions in Nonpolar Solvents , 2000 .

[15]  H. M. Azeredo Nanocomposites for food packaging applications , 2009 .

[16]  Kentaro Abe,et al.  Property enhancement of optically transparent bionanofiber composites by acetylation , 2006 .

[17]  Hiroyuki Yano,et al.  The effect of morphological changes from pulp fiber towards nano-scale fibrillated cellulose on the mechanical properties of high-strength plant fiber based composites , 2004 .

[18]  A. Dufresne,et al.  Modification of cellulose fibers with functionalized silanes : Effect of the fiber treatment on the mechanical performances of cellulose-thermoset composites , 2005 .

[19]  Richard P. Wool,et al.  Natural fiber composites with plant oil-based resin , 2004 .

[20]  L. Berglund,et al.  Structure and Properties of Cellulose Nanocomposite Films Containing Melamine Formaldehyde , 2007 .

[21]  D. Gray,et al.  Solid cholesteric films cast from aqueous (hydroxypropyl)cellulose , 1987 .

[22]  L. Berglund,et al.  Biomimetic polysaccharide nanocomposites of high cellulose content and high toughness. , 2007, Biomacromolecules.

[23]  S. Girois,et al.  Polym. Degrad. Stab. , 1996 .

[24]  Reza Masoodi,et al.  Numerical simulation of LCM mold-filling during the manufacture of natural fiber composites , 2012 .

[25]  O. Rojas,et al.  Nanofiber composites of polyvinyl alcohol and cellulose nanocrystals: manufacture and characterization. , 2010, Biomacromolecules.

[26]  A. Dufresne,et al.  Cellulose whiskers versus microfibrils: influence of the nature of the nanoparticle and its surface functionalization on the thermal and mechanical properties of nanocomposites. , 2009, Biomacromolecules.

[27]  Sabu Thomas,et al.  Enhancement of thermal stability, strength and extensibility of lipid-based polyurethanes with cellulose-based nanofibers , 2012 .

[28]  M. Hughes,et al.  FLAX AND HEMP FIBRES: A NATURAL SOLUTION FOR THE COMPOSITE INDUSTRY , 2012 .

[29]  M. Nogi,et al.  Optically transparent composites reinforced with plant fiber-based nanofibers , 2005 .

[30]  Frederick R. Phelan,et al.  Simulation of the injection process in resin transfer molding , 1997 .

[31]  PCG solver and its computational complexity for implicit control-volume finite-element method of RTM mold filling simulation , 2007 .

[32]  Lynn A. Capadona,et al.  A versatile approach for the processing of polymer nanocomposites with self-assembled nanofibre templates. , 2007, Nature nanotechnology.

[33]  Mikael Gällstedt,et al.  Oxygen and oil barrier properties of microfibrillated cellulose films and coatings , 2010 .

[34]  A. Shojaei,et al.  Numerical simulation of three-dimensional mold filling process in resin transfer molding using quasi-steady state and partial saturation formulations , 2002 .

[35]  Honglai Liu,et al.  Chemistry and Applications of Nanocrystalline Cellulose and its Derivatives: a Nanotechnology Perspective , 2011 .

[36]  Anand R. Sanadi,et al.  Preparation and Characterization of Cellulose Nanofibers from Two Commercial Hardwood and Softwood Pulps , 2009 .

[37]  Satoshi Miyaguchi,et al.  Optically transparent wood-cellulose nanocomposite as a base substrate for flexible organic light-emitting diode displays , 2009 .

[38]  Xiaolin Luo,et al.  Integrated production of nano-fibrillated cellulose and cellulosic biofuel (ethanol) by enzymatic fractionation of wood fibers , 2011 .

[39]  Anthony Kelly,et al.  Comprehensive composite materials , 1999 .

[40]  J. Araki,et al.  Toward "strong" green nanocomposites: polyvinyl alcohol reinforced with extremely oriented cellulose whiskers. , 2011, Biomacromolecules.

[41]  L. Simon,et al.  Influences of cellulose nanofiber on the epoxy network formation , 2008 .

[42]  Louis Godbout,et al.  Solid self-assembled films of cellulose with chiral nematic order and optically variable properties , 1998 .

[43]  J. W. Farrent,et al.  High-performance composites from low-cost plant primary cell walls , 2005 .

[44]  T. Roeder,et al.  Mechanical Properties of Regenerated Cellulose Fibres for Composites , 2006 .

[45]  M. Skrifvars,et al.  Processing of Structural Composites from Biobased Thermoset Resins and Natural Fibres by Compression Moulding , 2009 .

[46]  A. Dufresne,et al.  Water sorption behavior and gas barrier properties of cellulose whiskers and microfibrils films , 2011 .

[47]  E. Thostenson,et al.  Multi-scale hybrid biocomposite: Processing and mechanical characterization of bamboo fiber reinforced PLA with microfibrillated cellulose , 2009 .

[48]  Z. Cai,et al.  HIGH-PERFORMANCE CELLULOSE NANOFIBRIL COMPOSITE FILMS , 2012 .

[49]  T. Iwata,et al.  Structure and mechanical properties of wet-spun fibers made from natural cellulose nanofibers. , 2011, Biomacromolecules.

[50]  Qasim Chaudhry,et al.  Applications of nanomaterials in food packaging with a consideration of opportunities for developing countries , 2011 .

[51]  L. Lucia,et al.  Cellulose nanocrystals: chemistry, self-assembly, and applications. , 2010, Chemical reviews.

[52]  A. N. Nakagaito,et al.  The effect of fiber content on the mechanical and thermal expansion properties of biocomposites based on microfibrillated cellulose , 2008 .

[53]  J. Keckes,et al.  Drawing of self‐reinforced cellulose films , 2007 .

[54]  Akira Isogai,et al.  Transparent and high gas barrier films of cellulose nanofibers prepared by TEMPO-mediated oxidation. , 2009, Biomacromolecules.

[55]  Hans Lilholt,et al.  1.10 – Natural Organic Fibers , 2000 .

[56]  Calvin Woodings,et al.  Regenerated cellulose fibres , 2001 .

[57]  A. N. Nakagaito,et al.  Fiber-content dependency of the optical transparency and thermal expansion of bacterial nanofiber reinforced composites , 2006 .

[58]  C. Woodings 1 – A brief history of regenerated cellulosic fibres , 2001 .

[59]  K. Oksman,et al.  Dispersion and characteristics of surfactant modified cellulose whiskers nanocomposites , 2007 .

[60]  F. Doghieri,et al.  Investigation of mass transport properties of microfibrillated cellulose (MFC) films , 2010 .

[61]  D. Rentsch,et al.  Preparation and characterization of water-redispersible nanofibrillated cellulose in powder form , 2010 .

[62]  David Plackett,et al.  Microfibrillated cellulose and new nanocomposite materials: a review , 2010 .

[63]  R. Umer,et al.  Wood Fiber Mats as Reinforcements for Thermosets , 2007 .

[64]  L. Nyholm,et al.  A Nanocellulose Polypyrrole Composite Based on Microfibrillated Cellulose from Wood , 2010, The journal of physical chemistry. B.

[65]  D. Gray,et al.  Dispersion of cellulose nanocrystals in polar organic solvents , 2007 .

[66]  A. Dufresne,et al.  Extrusion of Nanocellulose‐Reinforced Nanocomposites Using the Dispersed Nano‐Objects Protective Encapsulation (DOPE) Process , 2011 .

[67]  Akira Isogai,et al.  Individualization of nano-sized plant cellulose fibrils by direct surface carboxylation using TEMPO catalyst under neutral conditions. , 2009, Biomacromolecules.

[68]  M. Gabr,et al.  Effect of microfibrillated cellulose on mechanical properties of plain-woven CFRP reinforced epoxy , 2010 .

[69]  Hiroyuki Yano,et al.  Novel high-strength biocomposites based on microfibrillated cellulose having nano-order-unit web-like network structure , 2005 .

[70]  M. Skrifvars,et al.  Preparation of thermoset composites from natural fibres and acrylate modified soybean oil resins , 2009 .

[71]  Matteo Pasquali,et al.  Carbon nanotube-based neat fibers , 2008 .

[72]  M. Misra,et al.  Natural, Fibers, Biopolymers and Biocomposites , 2009 .

[73]  Kentaro Abe,et al.  Review: current international research into cellulose nanofibres and nanocomposites , 2010, Journal of Materials Science.

[74]  Suresh G. Advani,et al.  RTM : filling simulation of complex three dimensional shell-like structures , 1991 .

[75]  Masaya Nogi,et al.  Transparent Nanocomposites Based on Cellulose Produced by Bacteria Offer Potential Innovation in the Electronics Device Industry , 2008 .

[76]  P. Lu,et al.  Cellulose nanocrystal-filled poly(acrylic acid) nanocomposite fibrous membranes , 2009, Nanotechnology.

[77]  S. Alavi,et al.  Recent advances in starch, polyvinyl alcohol based polymer blends, nanocomposites and their biodegradability , 2011 .

[78]  T. Nishino,et al.  Cellulose nanofiber orientation in nanopaper and nanocomposites by cold drawing. , 2012, ACS applied materials & interfaces.

[79]  Wen-Bin Young,et al.  Analysis of resin injection molding in molds with preplaced fiber mats. II: Numerical simulation and experiments of mold filling , 1991 .

[80]  Marielle Henriksson,et al.  Cellulose nanopaper structures of high toughness. , 2008, Biomacromolecules.

[81]  L. J. Lee,et al.  Liquid flow in molds with prelocated fiber mats , 1989 .

[82]  Ulrich Riedel,et al.  Activities in biocomposites , 2003 .

[83]  P. Askeland,et al.  Surface modification of microfibrillated cellulose for epoxy composite applications , 2008 .

[84]  M. L. Cerrada,et al.  Surface silylation of cellulose microfibrils: preparation and rheological properties , 2004 .

[85]  C. Graillat,et al.  New waterborne epoxy coatings based on cellulose nanofillers , 2001 .

[86]  T. Röder,et al.  Anisotropy of the modulus of elasticity in regenerated cellulose fibres related to molecular orientation , 2008 .

[87]  H. Fink,et al.  Novel cellulose fibre reinforced thermoplastic materials , 2006 .

[88]  Andong Liu,et al.  Fast preparation procedure for large, flat cellulose and cellulose/inorganic nanopaper structures. , 2010, Biomacromolecules.

[89]  M. Roman,et al.  Effect of reaction conditions on the properties and behavior of wood cellulose nanocrystal suspensions. , 2005, Biomacromolecules.

[90]  Tara H McHugh,et al.  Nanocellulose reinforced chitosan composite films as affected by nanofiller loading and plasticizer content. , 2010, Journal of food science.

[91]  D G Gray,et al.  Helicoidal self-ordering of cellulose microfibrils in aqueous suspension. , 1992, International journal of biological macromolecules.

[92]  D. Gardner,et al.  Drying cellulose nanofibrils: in search of a suitable method , 2012, Cellulose.

[93]  M. Skrifvars,et al.  Biobased composites prepared by compression molding with a novel thermoset resin from soybean oil and a natural‐fiber reinforcement , 2010 .

[94]  L. Berglund Cellulose-Based Nanocomposites , 2005 .

[95]  John Simonsen,et al.  Poly(vinyl alcohol)/cellulose nanocrystal barrier membranes , 2008 .

[96]  Jaakko V. I. Timonen,et al.  Multifunctional High‐Performance Biofibers Based on Wet‐Extrusion of Renewable Native Cellulose Nanofibrils , 2011, Advanced materials.

[97]  Kumar K. Tamma,et al.  On a Pure Finite-Element-Based Methodology for Resin Transfer Mold (RTM) Filling Simulations. , 1999 .

[98]  D. Gray,et al.  Electron microscopic evidence for cholesteric structure in films of cellulose and cellulose acetate , 1988 .

[99]  Z. Cai,et al.  Resin impregnation of cellulose nanofibril films facilitated by water swelling , 2013, Cellulose.

[100]  C. Graillat,et al.  Processing and characterization of new thermoset nanocomposites based on cellulose whiskers , 2000 .

[101]  Ashlie Martini,et al.  Cellulose nanomaterials review: structure, properties and nanocomposites. , 2011, Chemical Society reviews.

[102]  K. Pickering Properties and performance of natural-fibre composites , 2008 .

[103]  Masaya Nogi,et al.  Optically Transparent Nanofiber Paper , 2009 .

[104]  Z. Y. Zhang,et al.  Experimental investigation and flow visualisation of the resin transfer mould filling process for non-woven hemp reinforced phenolic composites , 2000 .

[105]  Alain Dufresne,et al.  Review of recent research into cellulosic whiskers, their properties and their application in nanocomposite field. , 2005, Biomacromolecules.

[106]  H. Chanzy,et al.  Stable suspensions of partially silylated cellulose whiskers dispersed in organic solvents , 2002 .

[107]  O. Ikkala,et al.  Functionalized porous microparticles of nanofibrillated cellulose for biomimetic hierarchically structured superhydrophobic surfaces , 2012 .

[108]  J. Cavaillé,et al.  New nanocomposite materials reinforced with cellulose whiskers in atactic polypropylene: effect of surface and dispersion characteristics. , 2005, Biomacromolecules.

[109]  A. N. Nakagaito,et al.  Nano-fibrillation of pulp fibers for the processing of transparent nanocomposites , 2007 .

[110]  Lucian A. Lucia,et al.  CELLULOSIC NANOCOMPOSITES: A REVIEW , 2008 .

[111]  François Trochu,et al.  Application of the level set method to the simulation of resin transfer molding , 2006 .

[112]  Tanja Zimmermann,et al.  Properties of nanofibrillated cellulose from different raw materials and its reinforcement potential , 2010 .