Detection of heavy metals in Arabian crude oil residue using laser induced breakdown spectroscopy.

Laser induced breakdown spectroscopy (LIBS) was applied for the elemental analysis of Arabian crude oil residue samples. The spectra due to trace elements such as Ca, Fe, Mg, Cu, Zn, Na, Ni, K and Mo were recorded using this technique. The dependence of time delay and laser beam energy on the elemental spectra was also investigated. Prior to quantitative analysis, the LIBS system was calibrated using standard samples containing these trace elements. The results achieved through this method were compared with conventional technique like inductively coupled plasma.

[1]  Eugene T. Kennedy,et al.  Time-integrated laser-induced plasma spectroscopy in the vacuum ultraviolet for the quantitative elemental characterization of steel alloys , 2000 .

[2]  M. Gondal,et al.  Pulsed Laser Photoacoustic Detection of SO(2) Near 225.7 nm. , 2001, Applied optics.

[3]  J. Nriagu,et al.  Quantitative assessment of worldwide contamination of air, water and soils by trace metals , 1988, Nature.

[4]  J. A. Aguilera,et al.  Characterization of a laser-induced plasma by spatially resolved spectroscopy of neutral atom and ion emissions.. Comparison of local and spatially integrated measurements , 2004 .

[5]  M. D. Luque de Castro,et al.  Laser-induced breakdown spectrometry in jewellery industry. Part II: quantitative characterisation of goldfilled interface. , 2003, Talanta.

[6]  I. Schechter Laser Induced Plasma Spectroscopy: Α Review of Recent Advances , 1997 .

[7]  Eugene T. Kennedy,et al.  Optimization of the Emission Characteristics of Laser-Produced Steel Plasmas in the Vacuum Ultraviolet: Significant Improvements in Carbon Detection Limits , 2002 .

[8]  S. Buckley,et al.  Temporal Gating for the Optimization of Laser-Induced Breakdown Spectroscopy Detection and Analysis of Toxic Metals , 2001 .

[9]  J. D. Winefordner,et al.  Variables Influencing the Precision of Laser-Induced Breakdown Spectroscopy Measurements , 1998 .

[10]  Meng-Dawn Cheng,et al.  Detection of Chromium Aerosol Using Time-Resolved Laser-Induced Plasma Spectroscopy , 2000 .

[11]  Mohammed A. Gondal,et al.  Laser Doppler velocimeter for remote measurement of polluted water and aerosols discharges , 2002 .

[12]  M. Gondal,et al.  Laser photoacoustic spectrometer for remote monitoring of atmospheric pollutants. , 1997, Applied optics.

[13]  Leon J. Radziemski,et al.  Time-resolved laser-induced breakdown spectrometry of aerosols , 1983 .

[14]  J. O. Cáceres,et al.  Quantitative analysis of trace metal ions in ice using laser-induced breakdown spectroscopy , 2001 .

[15]  D. Conning,et al.  Experimental toxicology : the basic issues , 1993 .

[16]  M. Gondal,et al.  Lidar system for remote environmental studies. , 2000, Talanta.

[17]  Vincenzo Palleschi,et al.  Detection of mercury in air by time-resolved laser-induced breakdown spectroscopy technique , 1994 .

[18]  E. A. Mackey,et al.  Bioaccumulation of vanadium and other trace metals in livers of Alaskan cetaceans and pinnipeds , 1996, Archives of environmental contamination and toxicology.

[19]  Yong‐Ill Lee,et al.  Laser-Induced Breakdown Spectrometry , 1998 .

[20]  R. Guicherit,et al.  Determination of cadmium, zinc, copper, chromium and arsenic in crude oil cargoes. , 2000, Environmental pollution.

[21]  J. Belliveau,et al.  Laser-Induced Breakdown Spectroscopy of Steels at Atmospheric Pressure and in Air , 1985 .

[22]  Leon J. Radziemski,et al.  Detection of chlorine and fluorine in air by laser-induced breakdown spectrometry , 1983 .