Multivariate statistical analysis of botrytised wines of different origin

The study examined several types of compounds can be suitable to characterise wines made from botrytised grapes and to determine their origin and authenticity. Amines, acids, macro- and microelements of botrytised sweet wine specialities, coming from Hungary and different countries, were analysed. Measured values of twenty-one Tokaji aszu wines and twenty-three foreign botrytised wines were compared by multivariate statistical methods. Characterising the effect of Botrytis cinerea and the winemaking technology, amines were the most suitable components for determination of authenticity and origin of wines from the three types of compounds studied. However, in acids and elemental composition, differentiation of wine samples by principal component analysis was not complete but a tendency can be observed for separation according to origin. The knowledge on composition of acids and elements can support the results of amine analysis in reaching the goal to determine the origin of wines.

[1]  F. Beese,et al.  Pesticide and Heavy Metals Residue in Wastewater, Soil and Plants in Wastewater Disposal Site Near Al-Lajoun Valley, Karak / Jordan , 2002 .

[2]  Characterization of elementary wines of Vitis vinifera varieties by pattern recognition of free amino acid profiles , 1989 .

[3]  K. Héberger,et al.  Principal component analysis of biogenic amines and polyphenols in Hungarian wines. , 2002, Journal of agricultural and food chemistry.

[4]  J. Kiss,et al.  Protection of originality of Tokaji Aszú: amines and organic acids in botrytized wines by high-performance liquid chromatography. , 2005, Journal of agricultural and food chemistry.

[5]  E. Bast Über Vorkommen und Entstehung flüchtiger primärer Amine bei Bakterien , 2004, Archiv für Mikrobiologie.

[6]  G. Martin,et al.  Characterization of the Geographic Origin of Bordeaux Wines by a Combined Use of Isotopic and Trace Element Measurements , 1999, American Journal of Enology and Viticulture.

[7]  Pascal Schlich,et al.  Varietal and geographic classification of French red wines in terms of major acids , 1989 .

[8]  W. Brandes,et al.  Einfluss von Traubenfäulnis und Schönungsmitteln auf Gehalte biogener Amine in Mosten und Weinen , 2002 .

[9]  V. Abram,et al.  Determination of Organic Acids in White Wines by RP-HPLC , 2001 .

[10]  G. Laube,et al.  Polyamines increase in sympathetic neurons and non-neuronal cells after axotomy and enhance neurite outgrowth in nerve growth factor-primed PC12 cells , 2004, Neuroscience.

[11]  Carlos Herrero,et al.  Pattern recognition analysis applied to classification of wines from Galicia (northwestern Spain) with certified brand of origin , 1994 .

[12]  P. Lehtonen Determination of Amines and Amino Acids in Wine — A Review , 1996, American Journal of Enology and Viticulture.

[13]  K. Igarashi [Physiological functions of polyamines and regulation of polyamine content in cells]. , 2006, Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan.

[14]  L. Martínez,et al.  Trace element determination of Argentine wines using ETAAS and USN-ICP-OES. , 2005, Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association.

[15]  G. Martin,et al.  Determination of the geographical origin of wine using joint analysis of elemental and isotopic composition. II—Differentiation of the principal production zones in france for the 1990 vintage , 1995 .

[16]  G. Seguin,et al.  Botrytis cinerea in enology , 1980 .

[17]  W. Jarvis,et al.  The biology of Botrytis. , 1983 .

[18]  E. Szerdahelyi,et al.  Study of biologically active amines in grapes and wines by HPLC , 2000 .

[19]  A. P. Marques,et al.  A survey of biogenic amines in commercial Portuguese wines , 2005 .

[20]  Z. Kovács,et al.  Statistical evalution of aroma and metal content in Tokay wines , 2000 .

[21]  Ioannis S. Arvanitoyannis,et al.  Application of quality control methods for assessing wine authenticity : Use of multivariate analysis (chemometrics) , 1999 .

[22]  K. Kashiwagi,et al.  Polyamines: mysterious modulators of cellular functions. , 2000, Biochemical and biophysical research communications.

[23]  Marcela S. Sanchez,et al.  Polyamines as a defense mechanism against lipoperoxidation in Trypanosoma cruzi. , 2006, Acta tropica.

[24]  K. Héberger,et al.  Supervised pattern recognition in food analysis. , 2007, Journal of chromatography. A.

[25]  Károly Héberger,et al.  Principal component and linear discriminant analyses of free amino acids and biogenic amines in hungarian wines. , 2003, Journal of agricultural and food chemistry.

[26]  E. Szerdahelyi,et al.  Changes in biogenic amine content of Tokaj grapes, wines, and Aszu-wines , 2000 .

[27]  Ian Goodall,et al.  The determination of the authenticity of wine from its trace element composition , 1997 .

[28]  Maurizio Aceto,et al.  Statistical investigation of the differences in the distribution of metals in Nebbiolo-based wines , 2003 .

[29]  Sara Bover-Cid,et al.  Ion-pair high-performance liquid chromatographic determination of biogenic amines and polyamines in wine and other alcoholic beverages. , 2003, Journal of chromatography. A.

[30]  E. Bast Biosynthese primärer aliphatischer Monoamine durch Aminosäure-Aldehyd-Transaminierung bei Sarcina lutea , 2004, Archiv für Mikrobiologie.