Review on the Processing and Properties of Polymer Nanocomposites and Nanocoatings and Their Applications in the Packaging, Automotive and Solar Energy Fields

For the last decades, nanocomposites materials have been widely studied in the scientific literature as they provide substantial properties enhancements, even at low nanoparticles content. Their performance depends on a number of parameters but the nanoparticles dispersion and distribution state remains the key challenge in order to obtain the full nanocomposites’ potential in terms of, e.g., flame retardance, mechanical, barrier and thermal properties, etc., that would allow extending their use in the industry. While the amount of existing research and indeed review papers regarding the formulation of nanocomposites is already significant, after listing the most common applications, this review focuses more in-depth on the properties and materials of relevance in three target sectors: packaging, solar energy and automotive. In terms of advances in the processing of nanocomposites, this review discusses various enhancement technologies such as the use of ultrasounds for in-process nanoparticles dispersion. In the case of nanocoatings, it describes the different conventionally used processes as well as nanoparticles deposition by electro-hydrodynamic processing. All in all, this review gives the basics both in terms of composition and of processing aspects to reach optimal properties for using nanocomposites in the selected applications. As an outlook, up-to-date nanosafety issues are discussed.

[1]  Tzong‐Ming Wu,et al.  Isothermal and nonisothermal crystallization kinetics of nylon 6/functionalized multi-walled carbon nanotube composites , 2008 .

[2]  Zhiqiang Gao,et al.  Effects of Damkhöler number of evaporation on the morphology of active layer and the performance of organic heterojunction solar cells fabricated by electrospray method , 2015 .

[3]  Donghua Xu,et al.  Role of multi-wall carbon nanotube network in composites to crystallization of isotactic polypropylene matrix , 2008 .

[4]  I. McEwen,et al.  The glass transition and interfacial layer in styrene-butadiene rubber containing silica nanofiller , 2003 .

[5]  Pieter Samyn,et al.  Bio-Based Coatings for Paper Applications , 2015 .

[6]  C. Hsieh,et al.  Contact Angle Hysteresis and Work of Adhesion of Oil Droplets on Nanosphere Stacking Layers , 2009 .

[7]  H. Park,et al.  Graphene and graphene oxide and their uses in barrier polymers , 2014 .

[8]  Jose M. Lagaron,et al.  Novel PET Nanocomposites of Interest in Food Packaging Applications and Comparative Barrier Performance With Biopolyester Nanocomposites , 2007 .

[9]  C. Frias Graphene -Based Thermoplastic Masterbatches for conventional & Additive Manufacturing Processes , 2013, ICCS 2013.

[10]  Hongqiang Yan,et al.  Construction of flame retardant nanocoating on ramie fabric via layer-by-layer assembly of carbon nanotube and ammonium polyphosphate. , 2013, Nanoscale.

[11]  M. R. Kessler,et al.  Thermal expansion of fumed silica/cyanate ester nanocomposites , 2008 .

[12]  T. D. Fornes,et al.  Modeling properties of nylon 6/clay nanocomposites using composite theories , 2003 .

[13]  D. R. Paul,et al.  Processing and Properties of Polymers Modified by Clays , 2007 .

[14]  H. Sugimura,et al.  Transparent ultra water-repellent poly(ethylene terephthalate) substrates fabricated by oxygen plasma treatment and subsequent hydrophobic coating , 2005 .

[15]  K. Kim,et al.  Facile method to functionalize graphene oxide and its application to poly(ethylene terephthalate)/graphene composite. , 2012, ACS applied materials & interfaces.

[16]  G. Odegard,et al.  Molecular modeling of EPON-862/graphite composites: Interfacial characteristics for multiple crosslink densities , 2013 .

[17]  O. Kwon,et al.  Preparation and barrier property of poly(ethylene terephthalate)/clay nanocomposite using clay‐supported catalyst , 2006 .

[18]  R. Avena-Bustillos,et al.  Composite edible films based on hydroxypropyl methylcellulose reinforced with microcrystalline cellulose nanoparticles. , 2010, Journal of agricultural and food chemistry.

[19]  A. Tuteja,et al.  Superomniphobic surfaces: Design and durability , 2013 .

[20]  R. Gavara,et al.  Improving packaged food quality and safety. Part 1: Synchrotron X-ray analysis , 2005, Food additives and contaminants.

[21]  A. Roy,et al.  Multi-scale mechanics of nanocomposites including interface: Experimental and numerical investigation , 2005 .

[22]  Ji Hun Park,et al.  Nanocoating of Single Cells: From Maintenance of Cell Viability to Manipulation of Cellular Activities , 2014, Advanced materials.

[23]  M. Fabra,et al.  Combining polyhydroxyalkanoates with nanokeratin to develop novel biopackaging structures , 2016 .

[24]  R. Popovitz‐Biro,et al.  Impact of injection‐molding processing parameters on the electrical, mechanical, and thermal properties of thermoplastic/carbon nanotube nanocomposites , 2011 .

[25]  J. Gérard,et al.  Influence of the intercalated cations on the surface energy of montmorillonites: consequences for the morphology and gas barrier properties of polyethylene/montmorillonites nanocomposites. , 2007, Journal of colloid and interface science.

[26]  M. Rong,et al.  Surface modification of nanoscale fillers for improving properties of polymer nanocomposites: A review , 2006 .

[27]  C. Holtz,et al.  The Emptying Behaviour of Highly Viscous Liquids. Part II: Development of Test Methods and Evaluation of Untreated and Coated Films , 2012 .

[28]  K. Seo,et al.  Candle-based process for creating a stable superhydrophobic surface , 2014 .

[29]  Yihu Song,et al.  A Facile, Multifunctional, Transparent, and Superhydrophobic Coating Based on a Nanoscale Porous Structure Spontaneously Assembled from Branched Silica Nanoparticles , 2015 .

[30]  H. Dai,et al.  Narrow graphene nanoribbons from carbon nanotubes , 2009, Nature.

[31]  M. Weaver,et al.  Thin-film permeation-barrier technology for flexible organic light-emitting devices , 2004, IEEE Journal of Selected Topics in Quantum Electronics.

[32]  G. Groeninckx,et al.  Features, Questions and Future Challenges in Layered Silicates Clay Nanocomposites with Semicrystalline Polymer Matrices , 2008 .

[33]  A. J. Hill,et al.  Ultrapermeable, Reverse-Selective Nanocomposite Membranes , 2002, Science.

[34]  S. Nair,et al.  Supercapacitor electrodes using nanoscale activated carbon from graphite by ball milling , 2012 .

[35]  R. Menini,et al.  Production of superhydrophobic polymer fibers with embedded particles using the electrospinning technique , 2008 .

[36]  Keld Alstrup Jensen,et al.  Sanding dust from nanoparticle-containing paints: Physical characterisation , 2009 .

[37]  Richard W. Siegel,et al.  Mechanical properties of nanophase TiO_2 as determined by nanoindentation , 1990 .

[38]  A. Hart,et al.  Exposure to nanoscale particles and fibers during machining of hybrid advanced composites containing carbon nanotubes , 2009 .

[39]  Kurt Straif,et al.  Carcinogenicity of fluoro-edenite, silicon carbide fibres and whiskers, and carbon nanotubes. , 2014, The Lancet. Oncology.

[40]  Andrea Lazzeri,et al.  Properties of Whey-Protein-Coated Films and Laminates as Novel Recyclable Food Packaging Materials with Excellent Barrier Properties , 2012 .

[41]  B. van Ravenzwaay,et al.  Comparative inhalation toxicity of multi-wall carbon nanotubes, graphene, graphite nanoplatelets and low surface carbon black , 2013, Particle and Fibre Toxicology.

[42]  L. Robeson,et al.  Polymer nanotechnology: Nanocomposites , 2008 .

[43]  Craig J Hawker,et al.  General Strategies for Nanoparticle Dispersion , 2006, Science.

[44]  C. Tanford Macromolecules , 1994, Nature.

[45]  J. Galy,et al.  Effect of sub-micron silica fillers on the mechanical performances of epoxy-based composites , 2007 .

[46]  N. Nuraje,et al.  Study of superhydrophobic electrospun nanocomposite fibers for energy systems. , 2011, Langmuir : the ACS journal of surfaces and colloids.

[47]  Richard W. Siegel,et al.  Exploring Mesoscopia: The Bold New World of Nanostructures , 1993 .

[48]  Roham Rafiee,et al.  On the tensile behavior of an embedded carbon nanotube in polymer matrix with non-bonded interphase region , 2010 .

[49]  R. Das,et al.  Manufacturing and characterization of multifunctional polymer-reduced graphene oxide nanocomposites , 2015 .

[50]  H. Allcock,et al.  Poly[bis(2,2,2-trifluoroethoxy)phosphazene] superhydrophobic nanofibers. , 2005, Langmuir : the ACS journal of surfaces and colloids.

[51]  R. Gavara,et al.  Study of the influence of water sorption in pure components and binary blends of high barrier ethylene–vinyl alcohol copolymer and amorphous polyamide and nylon-containing ionomer , 2001 .

[52]  A. Isayev,et al.  Continuous Mixing and Compounding of Polymer/Filler and Polymer/Polymer Mixtures with the Aid of Ultrasound , 2003 .

[53]  Anatol Jaworek,et al.  Micro- and nanoparticle production by electrospraying , 2007 .

[54]  Gareth H. McKinley,et al.  Droplet mobility on lubricant-impregnated surfaces , 2013 .

[55]  T. V. Duncan,et al.  Release of engineered nanomaterials from polymer nanocomposites: the effect of matrix degradation. , 2015, ACS applied materials & interfaces.

[56]  Garth L. Wilkes,et al.  Organic/Inorganic Hybrid Network Materials by the Sol−Gel Approach , 1996 .

[57]  T. Hirth,et al.  The Emptying Behavior of Highly Viscous Liquids. Part I: Polymeric Surfaces and Plasma Coatings , 2012 .

[58]  L. Catherine Brinson,et al.  Simulation of interphase percolation and gradients in polymer nanocomposites , 2009 .

[59]  A. Isayev,et al.  Ultrasonic treatment of polypropylene, polyamide 6, and their blends , 2006 .

[60]  Z. Shao,et al.  Superoleophobic cotton textiles. , 2009, Langmuir : the ACS journal of surfaces and colloids.

[61]  Vladimir V. Tsukruk,et al.  Graphene-polymer nanocomposites for structural and functional applications , 2014 .

[62]  Di Gao,et al.  Transparent superhydrophobic and highly oleophobic coatings. , 2010, Faraday discussions.

[63]  Jack F Douglas,et al.  Flow-induced properties of nanotube-filled polymer materials , 2004, Nature materials.

[64]  S. Kim,et al.  Crystallization Behaviors and Mechanical Properties of Poly(ethylene 2,6-naphthalate)/Multiwall Carbon Nanotube Nanocomposites , 2007 .

[65]  J. Beauchamp,et al.  International Organization for Standardization (ISO) , 2015 .

[66]  C. Brabec,et al.  Plastic Solar Cells , 2001 .

[67]  F. Ruffino,et al.  Metal-Polymer Nanocomposites: (Co-)Evaporation/(Co)Sputtering Approaches and Electrical Properties , 2015 .

[68]  Xiong Gong,et al.  New Architecture for High‐Efficiency Polymer Photovoltaic Cells Using Solution‐Based Titanium Oxide as an Optical Spacer , 2006 .

[69]  David P. Ziegler,et al.  Influence of montmorillonite layered silicate on plasticized poly(l-lactide) blown films , 2005 .

[70]  Donald R Paul,et al.  Effect of melt processing conditions on the extent of exfoliation in organoclay-based nanocomposites , 2001 .

[71]  P. Dubois,et al.  Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials , 2000 .

[72]  Amparo López-Rubio,et al.  Surfactant-aided electrospraying of low molecular weight carbohydrate polymers from aqueous solutions. , 2014, Carbohydrate polymers.

[73]  T. V. Duncan,et al.  Applications of nanotechnology in food packaging and food safety: Barrier materials, antimicrobials and sensors , 2011, Journal of Colloid and Interface Science.

[74]  A. Grumezescu,et al.  Efficient surface functionalization of wound dressings by a phytoactive nanocoating refractory to Candida albicans biofilm development , 2013, Biointerphases.

[75]  R. K. Shah,et al.  Effect of melt processing conditions on the morphology and properties of nylon 6 nanocomposites , 2007 .

[76]  R. Holbrook,et al.  Fate of graphene in polymer nanocomposite exposed to UV radiation , 2011 .

[77]  Zhi‐Kang Xu,et al.  ELECTROSPRAYING/ELECTROSPINNING OF POLY(γ-STEARYL-L-GLUTAMATE): FORMATION OF SURFACES WITH SUPERHYDROPHOBICITY , 2009 .

[78]  G. Choudalakis,et al.  Permeability of polymer/clay nanocomposites: A review , 2009 .

[79]  B. B. Khatua,et al.  Effect of Organoclay Platelets on Morphology of Nylon-6 and Poly(ethylene-ran-propylene) Rubber Blends , 2004 .

[80]  C. Ni,et al.  Structure and crystallization behavior of Nylon 66/multi-walled carbon nanotube nanocomposites at low carbon nanotube contents , 2007 .

[81]  Yang Yang,et al.  High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends , 2005 .

[82]  A. MacDiarmid,et al.  "Synthetic Metals": A Novel Role for Organic Polymers (Nobel Lecture). , 2001, Angewandte Chemie.

[83]  Luiz H. C. Mattoso,et al.  Improved barrier and mechanical properties of novel hydroxypropyl methylcellulose edible films with chitosan/tripolyphosphate nanoparticles , 2009 .

[84]  Carmen Sanchez Reig,et al.  Nanomaterials: a Map for Their Selection in Food Packaging Applications , 2014 .

[85]  Qiao-ling Hu,et al.  Antibacterial hybrid materials fabricated by nanocoating of microfibril bundles of cellulose substance with titania/chitosan/silver-nanoparticle composite films. , 2013, Journal of materials chemistry. B.

[86]  Michael Stevens,et al.  Harmonised FR regulations accelerate composites growth in public transportation , 2008 .

[87]  Derk Brouwer,et al.  Potential release scenarios for carbon nanotubes used in composites. , 2013, Environment international.

[88]  R. Pucha,et al.  Tensile modulus of carbon nanotube/polypropylene composites - A computational study based on experimental characterization , 2011 .

[89]  Kerry C. Huber,et al.  Edible films and coatings for food applications , 2009 .

[90]  F. Stan,et al.  Effect of processing parameters and strain rate on mechanical properties of carbon nanotube–filled polypropylene nanocomposites , 2014 .

[91]  M. Huskić,et al.  Comparison of the properties of clay polymer nanocomposites prepared by montmorillonite modified by silane and by quaternary ammonium salts , 2013 .

[92]  John Fahlteich Transparente Hochbarriereschichten auf flexiblen Substraten , 2010 .

[93]  R. Franz,et al.  Critical review of the migration potential of nanoparticles in food contact plastics , 2017 .

[94]  Dan Li,et al.  One‐Dimensional Conducting Polymer Nanostructures: Bulk Synthesis and Applications , 2009 .

[95]  R. Umer,et al.  Fillers and reinforcements for advanced nanocomposites , 2015 .

[96]  S. Scalese,et al.  Immobilization of nanomaterials in PMMA composites for photocatalytic removal of dyes, phenols and bacteria from water , 2016 .

[97]  Qihua Wang,et al.  Nonisothermal Crystallization Kinetics of Nylon 66/Montmorillonite Nanocomposites , 2007 .

[98]  A. Clearfield,et al.  Barrier properties of model epoxy nanocomposites , 2008 .

[99]  D. Tomasko,et al.  Supercritical fluid applications in polymer nanocomposites , 2003 .

[100]  Andreas Benz,et al.  Fundamental Investigations Regarding Barrier Properties of Grafted PVOH Layers , 2012 .

[101]  Horst-Christian Langowski,et al.  Studies on the barrier performance and adhesion strength of novel barrier films for vacuum insulation panels , 2014 .

[102]  W. Bock,et al.  Nanocoating Enhanced Optical Fiber Sensors , 2010 .

[103]  V. U. Novikov,et al.  Modeling of the Interphase of Polymer-Matrix Composites: Determination of Its Structure and Mechanical Properties , 2002 .

[104]  L. Nicolais,et al.  Isothermal crystallization in PCL/clay nanocomposites investigated with thermal and rheometric methods , 2004 .

[105]  Edward L Cussler,et al.  Polydisperse flakes in barrier films , 2004 .

[106]  J. Nam,et al.  Rheological, morphological, mechanical, and barrier properties of PP/EVOH blends , 2001 .

[107]  Junbiao Peng,et al.  High-performance polymer heterojunction solar cells of a polysilafluorene derivative , 2008 .

[108]  Jonghwan Suhr,et al.  Combined numerical/experimental investigation of particle diameter and interphase effects on coefficient of thermal expansion and young's modulus of SiO2/epoxy nanocomposites , 2012 .

[109]  S. Ray,et al.  Crystallization Behavior and Morphology of Biodegradable Polylactide/ Layered Silicate Nanocomposite , 2003 .

[110]  Ming Liu,et al.  Immobilized polymer layers on spherical nanoparticles , 2010 .

[111]  G. Boiteux,et al.  Polylactide/montmorillonite nanocomposites: Structure, dielectric, viscoelastic and thermal properties , 2007 .

[112]  T. V. Duncan,et al.  Release of engineered nanomaterials from polymer nanocomposites: diffusion, dissolution, and desorption. , 2015, ACS applied materials & interfaces.

[113]  M. Cho,et al.  Multiscale homogenization modeling for thermal transport properties of polymer nanocomposites with Kapitza thermal resistance , 2013 .

[114]  R. Pethrick,et al.  Synthesis and characterization of nylon 6/clay nanocomposites prepared by ultrasonication and in situ polymerization , 2008 .

[115]  R. Prud’homme,et al.  Thickness dependence of free‐standing thin films , 2007 .

[116]  Q. Fu,et al.  Compatibilization of Immiscible Poly(propylene)/Polystyrene Blends Using Clay , 2003 .

[117]  Cai‐Feng Wang,et al.  Fabrication of superhydrophobic TPU film for oil–water separation based on electrospinning route , 2011 .

[118]  T. Darmanin,et al.  Chemical and physical pathways for the preparation of superoleophobic surfaces and related wetting theories. , 2014, Chemical reviews.

[119]  L. Cena,et al.  Characterization and Control of Airborne Particles Emitted During Production of Epoxy/Carbon Nanotube Nanocomposites , 2011, Journal of occupational and environmental hygiene.

[120]  D. R. Paul,et al.  Nanocomposites formed from linear low density polyethylene and organoclays , 2004 .

[121]  Bumjoon J. Kim,et al.  Free-standing nanocomposite multilayers with various length scales, adjustable internal structures, and functionalities. , 2009, Journal of the American Chemical Society.

[122]  L. Mattoso,et al.  Nanocomposite edible films from mango puree reinforced with cellulose nanofibers. , 2009, Journal of food science.

[123]  Wolfgang Kaiser Kunststoffchemie für Ingenieure , 2005 .

[124]  R. Shekhar,et al.  Chitosan nanocoating on cotton textile substrate using layer-by-layer self-assembly technique , 2011 .

[125]  Weiqi Wang,et al.  Crystallization and orientation of syndiotactic polystyrene in nanorods , 2007 .

[126]  Cai‐Feng Wang,et al.  Controllable synthesis of new polymerizable macrosurfactants via CCTP and RAFT techniques and investigation of their performance in emulsion polymerization. , 2010, Langmuir : the ACS journal of surfaces and colloids.

[127]  A. Okada,et al.  Twenty Years of Polymer‐Clay Nanocomposites , 2006 .

[128]  Tianxi Liu,et al.  Crystallization and melting behavior of polyester/clay nanocomposites , 2004 .

[129]  M. Frounchi,et al.  Oxygen Barrier LDPE/LLDPE/Organoclay Nano‐Composite Films for Food Packaging , 2008 .

[130]  R. Gavara,et al.  Improving packaged food quality and safety. Part 2: Nanocomposites , 2005, Food additives and contaminants.

[131]  Andre K. Geim,et al.  The rise of graphene. , 2007, Nature materials.

[132]  C. Macosko,et al.  Graphene/Polymer Nanocomposites , 2010 .

[133]  Yiu-Wing Mai,et al.  Multiple melting and crystallization of nylon‐66/montmorillonite nanocomposites , 2003 .

[134]  M. Schmid,et al.  Permeation of water vapour, nitrogen, oxygen and carbon dioxide through whey protein isolate based films and coatings—Permselectivity and activation energy , 2015 .

[135]  Garry Rumbles,et al.  Pathways for the degradation of organic photovoltaic P3HT:PCBM based devices , 2008 .

[136]  J. Huh,et al.  From homogeneous to heterogeneous nucleation of chain molecules under nanoscopic cylindrical confinement. , 2007, Physical review letters.

[137]  Qi Wang,et al.  Preparation of conductive polyaniline/nanosilica particle composites through ultrasonic irradiation , 2003 .

[138]  J. Nedeljković,et al.  Fabrication and Characterization of Silver−Polyvinyl Alcohol Nanocomposites , 2003 .

[139]  R. Oleschuk,et al.  Electrowetting on superhydrophobic natural (Colocasia) and synthetic surfaces based upon fluorinated silica nanoparticles , 2015 .

[140]  T. D. Fornes,et al.  Nylon 6 nanocomposites: the effect of matrix molecular weight , 2001 .

[141]  Suprakas Sinha Ray,et al.  POLYMER/LAYERED SILICATE NANOCOMPOSITES: A REVIEW FROM PREPARATION TO PROCESSING , 2003 .

[142]  Kwang-woo Kim,et al.  Crystalline Structures, Melting, and Crystallization of Linear Polyethylene in Cylindrical Nanopores , 2007 .

[143]  Petra Pötschke,et al.  Influence of injection molding parameters on the electrical resistivity of polycarbonate filled with multi-walled carbon nanotubes , 2008 .

[144]  이상욱,et al.  Food packing material having hydrophobicity, manufacturing method and mold thereof , 2011 .

[145]  N. Kotov,et al.  Molecularly engineered nanocomposites: layer-by-layer assembly of cellulose nanocrystals. , 2005, Biomacromolecules.

[146]  A. J. Zattera,et al.  Preparation and characterization of montmorillonite modified with 3-aminopropyltriethoxysilane , 2014 .

[147]  David Eckroth,et al.  The Wiley Encyclopedia of Packaging Technology , 1986 .

[148]  Horst-Christian Langowski,et al.  Permeation of Gases and Condensable Substances through Monolayer and Multilayer Structures , 2008 .

[149]  D. Cao,et al.  Polymer-nanoparticle interfacial behavior revisited: a molecular dynamics study. , 2011, Physical chemistry chemical physics : PCCP.

[150]  Elizabeth Wilson Self-Cleaning Solar Panels , 2010 .

[151]  Markus Schmid,et al.  Physical, Chemical and Biochemical Modifications of Protein-Based Films and Coatings: An Extensive Review , 2016, International journal of molecular sciences.

[152]  Rajesh Kumar,et al.  Surface modification of inorganic nanoparticles for development of organic–inorganic nanocomposites—A review , 2013 .

[153]  M. Shokrieh,et al.  Multiscale modeling for mechanical properties of carbon nanotube reinforced nanocomposites subjected to different types of loading , 2011 .

[154]  A. Busnaina,et al.  Convective assembly and dry transfer of nanoparticles using hydrophobic/hydrophilic monolayer templates. , 2009, Langmuir : the ACS journal of surfaces and colloids.

[155]  L. Lim,et al.  Nanotechnology development in food packaging: A review , 2014 .

[156]  R. Bharadwaj MODELING THE BARRIER PROPERTIES OF POLYMER-LAYERED SILICATE NANOCOMPOSITES , 2001 .

[157]  G. Marom,et al.  Improving the oxygen barrier properties of polyethylene terephthalate by graphite nanoplatelets , 2012 .

[158]  R. Clark,et al.  Electrohydrodynamic atomization: a versatile process for preparing materials for biomedical applications , 2008, Journal of biomaterials science. Polymer edition.

[159]  Yasukiyo Ueda,et al.  The Lowest Surface Free Energy Based on −CF3 Alignment , 1999 .

[160]  Ying‐Ling Liu,et al.  Flame‐retardant epoxy resins: An approach from organic–inorganic hybrid nanocomposites , 2001 .

[161]  K. Sirkar,et al.  Continuous polymer nanocoating on silica nanoparticles. , 2014, Langmuir : the ACS journal of surfaces and colloids.

[162]  Sushant Anand,et al.  Enhanced condensation on lubricant-impregnated nanotextured surfaces. , 2012, ACS nano.

[163]  A. Okada,et al.  Synthesis and properties of polyimide-clay hybrid films , 1997 .

[164]  Youmin Yu,et al.  Permeability, viscoelasticity, and flammability performances and their relationship to polymer nanocomposites , 2012 .

[165]  Mark Stumborg,et al.  Green composites reinforced with hemp nanocrystals in plasticized starch , 2008 .

[166]  Francesco Picchioni,et al.  Synthetic aspects and characterization of polypropylene-silica nanocomposites prepared via solid-state modification and sol-gel reactions , 2005 .

[167]  G. Shi,et al.  Conducting polymer nanomaterials: electrosynthesis and applications. , 2009, Chemical Society reviews.

[168]  J. Galy,et al.  Structural investigations of pyrogenic silica-epoxy composites: combining small-angle neutron scattering and transmission electron microscopy , 2007 .

[169]  Qingfeng Dong,et al.  Efficiency enhancement of polymer solar cells by incorporating a self-assembled layer of silver nanodisks , 2011 .

[170]  R. Piner,et al.  Mechanical properties of monolayer graphene oxide. , 2010, ACS nano.

[171]  Ryan,et al.  Polymer crystallization in 25-nm spheres , 2000, Physical review letters.

[172]  Gareth H. McKinley,et al.  Designing Superoleophobic Surfaces , 2007, Science.

[173]  S. Denbaars,et al.  Surface structured optical coatings with near-perfect broadband and wide-angle antireflective properties. , 2014, Nano letters.

[174]  Sharifah Bee,et al.  SURFACTANT-ASSISTED BALL MILLING: A NOVEL ROUTE TO NOVEL MATERIALS WITH CONTROLLED NANOSTRUCTURE - A REVIEW , 2014 .

[175]  Qiming Liu,et al.  Plasmonic‐enhanced crystalline silicon/organic heterojunction cells by incorporating gold nanoparticles , 2014 .

[176]  M. Cho,et al.  Multiscale modeling of cross-linked epoxy nanocomposites to characterize the effect of particle size on thermal conductivity , 2011 .

[177]  J. Joines,et al.  Literature review on superhydrophobic self‐cleaning surfaces produced by electrospinning , 2012 .

[178]  Diamond-like carbon for data and beer storage , 2007 .

[179]  陈仕祥,et al.  Fe 2 O 3 /TiO 2 复合光催化剂的制备及其表征 , 2013 .

[180]  Sudipta Seal,et al.  One dimensional nanostructured materials , 2007 .

[181]  J. E. Mark,et al.  Simultaneous curing and filling of elastomers , 1984 .

[182]  Mario Schmidt,et al.  Stofftransport durch Schichtsysteme aus Polymeren und dünnen anorganischen Schichten , 2008 .

[183]  Zhi Qiao,et al.  Anatase-TiO2 Nanocoating of Li4Ti5O12 Nanorod Anode for Lithium-Ion Batteries. , 2014 .

[184]  S. Nguyen,et al.  Crumpled Graphene Nanosheets as Highly Effective Barrier Property Enhancers , 2010, Advanced materials.

[185]  M. Schmid,et al.  Determination Quantification of Molecular Interactions in Protein Films: A Review , 2014, Materials.

[186]  C. Hawker,et al.  Effect of Ideal, Organic Nanoparticles on the Flow Properties of Linear Polymers: Non-Einstein-like Behavior , 2005 .

[187]  Rupali Gangopadhyay and,et al.  Conducting Polymer Nanocomposites: A Brief Overview , 2000 .

[188]  Alan J. Heeger,et al.  Semiconducting Polymers: The Third Generation , 2010 .

[189]  A. Trapani,et al.  Characterization and cytocompatibility of an antibiotic/chitosan/cyclodextrins nanocoating on titanium implants. , 2014, Carbohydrate polymers.

[190]  ナノパーティクルテクノロジーハンドブック編集委員会,et al.  ナノパーティクルテクノロジーハンドブック = Nanoparticle technology handbook , 2006 .

[191]  A. Ryan,et al.  Modes of Crystallization in Block Copolymer Microdomains: Breakout, Templated, and Confined , 2002 .

[192]  H. Egelhaaf,et al.  1.20 – Plastic Solar Cells , 2012 .

[193]  M. Cho,et al.  Scale bridging method to characterize mechanical properties of nanoparticle/polymer nanocomposites , 2008 .

[194]  George Z. Papageorgiou,et al.  Dynamic mechanical and morphological studies of isotactic polypropylene/fumed silica nanocomposites with enhanced gas barrier properties , 2006 .

[195]  Sam S. Yoon,et al.  Antibacterial Activity and Photocatalysis of Electrosprayed Titania Films , 2012 .

[196]  Emmanuel P. Giannelis,et al.  Compatibilizing Poly(vinylidene fluoride)/Nylon-6 Blends with Nanoclay , 2007 .

[197]  Yongjin Li,et al.  Novel morphologies of poly(phenylene oxide) (PPO)/polyamide 6 (PA6) blend nanocomposites , 2004 .

[198]  Ning Li,et al.  Fabrication of electrospun polylactic acid nanofilm incorporating cinnamon essential oil/β-cyclodextrin inclusion complex for antimicrobial packaging. , 2016, Food chemistry.

[199]  C. Predescu,et al.  HYDROTHERMAL SYNTHESIS OF DOPED ZnO AND TiO2 NANOMATERIALS: OPPORTUNITIES FOR TEXTILE APPLICATIONS , 2014 .

[200]  Emmanuel P. Giannelis,et al.  Polymer Layered Silicate Nanocomposites , 1996 .

[201]  S. Ray,et al.  New polylactide/layered silicate nanocomposites. 5. Designing of materials with desired properties , 2003 .

[202]  R. Vaia,et al.  Lattice model of polymer melt intercalation in organically-modified layered silicates , 1997 .

[203]  G. Wilkes,et al.  Ceramers: Hybrid materials incorporating polymeric/oligomeric species with inorganic glasses by a sol-gel process , 1985 .

[204]  D. Bowman More than a Decade On: Mapping Today’s Regulatory and Policy Landscapes Following the Publication of Nanoscience and Nanotechnologies: Opportunities and Uncertainties , 2017 .

[205]  A. Müller,et al.  Homogeneous nucleation of the dispersed crystallisable component of immiscible polymer blends , 1994 .

[206]  H. Sugimura,et al.  Ultra-Water-Repellent Poly(ethylene terephthalate) Substrates , 2003 .

[207]  V. Zucolotto,et al.  Highly stable, edible cellulose films incorporating chitosan nanoparticles. , 2011, Journal of food science.

[208]  A. M. van der Zande,et al.  Impermeable atomic membranes from graphene sheets. , 2008, Nano letters.

[209]  Pinshane Y. Huang,et al.  Grains and grain boundaries in single-layer graphene atomic patchwork quilts , 2010, Nature.

[210]  Paula Gould EU funding bonanza begins , 2003 .

[211]  Jong-Whan Rhim,et al.  Natural Biopolymer-Based Nanocomposite Films for Packaging Applications , 2007, Critical reviews in food science and nutrition.

[212]  M. Cho,et al.  Nonlinear multiscale modeling approach to characterize elastoplastic behavior of CNT/polymer nanocomposites considering the interphase and interfacial imperfection , 2013 .

[213]  Michael C. Böhm,et al.  Interface of Grafted and Ungrafted Silica Nanoparticles with a Polystyrene Matrix: Atomistic Molecular Dynamics Simulations , 2011 .

[214]  M. C. Branciforti,et al.  Rheological, mechanical and transport properties of blown films of high density polyethylene nanocomposites , 2008 .

[215]  Hongkai Wu,et al.  γ-Radiation synthesis of poly(acrylic acid)–metal nanocomposites , 1998 .

[216]  R. Krishnamoorti,et al.  Nonlinear viscoelastic properties of layered-silicate-based intercalated nanocomposites , 2003 .

[217]  J. Tsai,et al.  Characterizing Mechanical Properties of Particulate Nanocomposites Using Micromechanical Approach , 2008 .

[218]  J. Youngblood,et al.  Self‐Cleaning and Next Generation Anti‐Fog Surfaces and Coatings , 2008 .

[219]  Andrij Holian,et al.  Effect of MWCNT size, carboxylation, and purification on in vitro and in vivo toxicity, inflammation and lung pathology , 2013, Particle and Fibre Toxicology.

[220]  D. M. Lincoln,et al.  Isothermal Crystallization of Nylon-6/Montmorillonite Nanocomposites , 2004 .

[221]  O. Kamigaito What Can Be Improved by Nanometer Composites , 1991 .

[222]  Bharat Bhushan,et al.  Diversity of structure, morphology and wetting of plant surfaces , 2008 .

[223]  Johnny L. Worthy,et al.  Defining the lower and upper limit of the effective modulus of CNT/polypropylene composites through integration of modeling and experiments , 2013 .

[224]  P. Messersmith,et al.  Synthesis and Characterization of Layered Silicate-Epoxy Nanocomposites , 1994 .

[225]  S. Bose,et al.  Effect of functionalized graphene on the physical properties of linear low density polyethylene nanocomposites , 2012 .

[226]  R. Amal,et al.  Role of Nanoparticles in Photocatalysis , 1999 .

[227]  E. Fekete,et al.  Surface modification and characterization of particulate mineral fillers , 1990 .

[228]  K. Saito,et al.  Potential release of carbon nanotubes from their composites during grinding , 2013 .

[229]  Ultrasound aided extrusion process for preparation of polyolefin--clay nanocomposites , 2008 .

[230]  W. Johnson,et al.  Nanocrystalline metals prepared by high-energy ball milling , 1990 .

[231]  L. Castillo,et al.  Thermoplastic starch films reinforced with talc nanoparticles. , 2013, Carbohydrate polymers.

[232]  Fernão D. Magalhães,et al.  Effect of incorporation of graphene oxide and graphene nanoplatelets on mechanical and gas permeability properties of poly(lactic acid) films , 2013 .

[233]  T. Kurauchi,et al.  Swelling behavior of montmorillonite cation exchanged for ω-amino acids by ∊-caprolactam , 1993 .

[234]  H. Lee,et al.  Elastoplastic modeling of polymeric composites containing randomly located nanoparticles with an interface effect , 2013 .

[235]  Charles A. Bishop,et al.  Vacuum Deposition onto Webs, Films and Foils , 2006 .

[236]  A. Arora,et al.  Review: nanocomposites in food packaging. , 2010, Journal of food science.

[237]  E. Harth,et al.  Stretchable gas barrier achieved with partially hydrogen-bonded multilayer nanocoating. , 2014, Macromolecular rapid communications.

[238]  Bharat Bhushan,et al.  Micro- and nanoscale characterization of hydrophobic and hydrophilic leaf surfaces , 2006 .

[239]  Michael E. A. Warwick,et al.  Fe2O3–TiO2 nanosystems by a hybrid PE-CVD/ALD approach: controllable synthesis, growth mechanism, and photocatalytic properties , 2015 .

[240]  A. Gedanken,et al.  Preparation and characterization of nickel–polystyrene nanocomposite by ultrasound irradiation , 2002 .

[241]  M. Schmid,et al.  Storage time-dependent alteration of molecular interaction–property relationships of whey protein isolate-based films and coatings , 2015, Journal of Materials Science.

[242]  Ali Abas Wani,et al.  Food packaging materials , 2017 .

[243]  D. Kil,et al.  Synthesis of dispersed CaCO3 nanoparticles by the ultrafine grinding , 2009 .

[244]  Peter Wick,et al.  Carbon Nanotubes Released from an Epoxy-Based Nanocomposite: Quantification and Particle Toxicity. , 2015, Environmental science & technology.

[245]  M. Osman,et al.  Gas permeation properties of polyethylene-layered silicate nanocomposites , 2005 .

[246]  M. Kokabi,et al.  The role of interfacial interactions on the glass-transition and viscoelastic properties of silica/polystyrene nanocomposite , 2011 .

[247]  M. A. Tung,et al.  Oxygen Ingress in Plastic Retortable Packages during Thermal Processing and Storage , 1998 .

[248]  H. M. Azeredo Nanocomposites for food packaging applications , 2009 .

[249]  Lang Xu,et al.  In Situ Synthesis of Polymer−Clay Nanocomposites from Silicate Gels , 1998 .

[250]  S. Qutubuddin,et al.  Gas barrier of polystyrene montmorillonite clay nanocomposites: Effect of mineral layer aggregation , 2007 .

[251]  P. Cinelli,et al.  State of the Art in the Development and Properties of Protein-Based Films and Coatings and Their Applicability to Cellulose Based Products: An Extensive Review , 2015 .

[252]  Shantikumar V. Nair,et al.  A review on ‘self-cleaning and multifunctional materials’ , 2014 .

[253]  L. Catherine Brinson,et al.  Reinforcing efficiency of nanoparticles: A simple comparison for polymer nanocomposites , 2008 .

[254]  Wilhelm Barthlott,et al.  Superhydrophobicity in perfection: the outstanding properties of the lotus leaf , 2011, Beilstein journal of nanotechnology.

[255]  Yi Hong,et al.  Plasmonic-enhanced polymer photovoltaic devices incorporating solution-processable metal nanoparticles , 2009 .

[256]  Peng Jiang,et al.  Scalable fabrication of superhydrophobic hierarchical colloidal arrays. , 2010, Journal of colloid and interface science.

[257]  Shanhui Fan,et al.  Light management for photovoltaics using high-index nanostructures. , 2014, Nature materials.

[258]  F. Müller-Plathe,et al.  Interface and Interphase Dynamics of Polystyrene Chains near Grafted and Ungrafted Silica Nanoparticles , 2012 .

[259]  C. Santeufemio,et al.  Characterization of Exposures To Nanoscale Particles and Fibers During Solid Core Drilling of Hybrid Carbon Nanotube Advanced Composites , 2010, International journal of occupational and environmental health.

[260]  H. Hahn,et al.  Processing of Iron Oxide-epoxy Vinyl Ester Nanocomposites , 2003 .

[261]  Darrell R Boverhof,et al.  A review and perspective of existing research on the release of nanomaterials from solid nanocomposites , 2014, Particle and Fibre Toxicology.

[262]  Su Chen,et al.  Facile Transformation of a Native Polystyrene (PS) Film into a Stable Superhydrophobic Surface via Sol–Gel Process , 2008 .

[263]  K. Dirscherl,et al.  Osteoblastic response to pectin nanocoating on titanium surfaces. , 2014, Materials science & engineering. C, Materials for biological applications.

[264]  Arthur D. Sherman,et al.  Atomic Layer Deposition: Principles, Characteristics, and Nanotechnology Applications , 2013 .

[265]  R. Vaia,et al.  Polymer Melt Intercalation in Organically-Modified Layered Silicates: Model Predictions and Experiment , 1997 .

[266]  B. Goderis,et al.  Crystallization behavior of polymer/montmorillonite nanocomposites. Part I. Intercalated poly(ethylene oxide)/montmorillonite nanocomposites , 2005 .

[267]  Q. Fu,et al.  Kinetics-controlled compatibilization of immiscible polypropylene/polystyrene blends using nano-SiO2 particles , 2004 .

[268]  J. Lagarón,et al.  High-barrier coated bacterial cellulose nanowhiskers films with reduced moisture sensitivity. , 2013, Carbohydrate polymers.

[269]  E. Manias Nanocomposites: stiffer by design. , 2007, Nature materials.

[270]  W. Wohlleben,et al.  On the lifecycle of nanocomposites: comparing released fragments and their in-vivo hazards from three release mechanisms and four nanocomposites. , 2011, Small.

[271]  J. Torkelson,et al.  Polymer–nanoparticle interfacial interactions in polymer nanocomposites: Confinement effects on glass transition temperature and suppression of physical aging , 2006 .

[272]  Doris Vollmer,et al.  Candle Soot as a Template for a Transparent Robust Superamphiphobic Coating , 2012, Science.

[273]  Min Woo Kim,et al.  Electrostatic spray deposition of transparent tungsten oxide thin-film photoanodes for solar water splitting , 2016 .

[274]  F. M. Peeters,et al.  Graphene: A perfect nanoballoon , 2008, 0810.4056.

[275]  A. S. Pouzada,et al.  Microstructure of PP/clay Nanocomposites Produced by Shear Induced Injection Moulding , 2012 .

[276]  Y. Si,et al.  A multifunctional transparent superhydrophobic gel nanocoating with self-healing properties. , 2015, Chemical communications.

[277]  Peter Sutter,et al.  Sub-50-nm self-assembled nanotextures for enhanced broadband antireflection in silicon solar cells , 2015, Nature Communications.

[278]  R. Ruoff,et al.  The chemistry of graphene oxide. , 2010, Chemical Society reviews.

[279]  Arthur A. Tracton Coatings Technology Handbook , 2005 .

[280]  Toshio Kurauchi,et al.  Synthesis of nylon 6-clay hybrid , 1993 .

[281]  Elodie Bugnicourt,et al.  Development of sub-micro structured composites based on an epoxy matrix and pyrogenic silica : mechanical behavior related to the interactions and morphology at multi-scale , 2005 .

[282]  Chien-Te Hsieh,et al.  Improvement of water and oil repellency on wood substrates by using fluorinated silica nanocoating , 2011 .

[283]  H.-C. Langowski Flexible Materialien mit ultrahohen Barriereeigenschaften . Flexible ultra high barrier materials , 2002 .

[284]  G. Fredrickson,et al.  BARRIER PROPERTIES OF ORIENTED DISK COMPOSITES , 1999 .

[285]  L. Nielsen Models for the Permeability of Filled Polymer Systems , 1967 .

[286]  Xiaodong Cao,et al.  Comparative study on the films of poly(vinyl alcohol)/pea starch nanocrystals and poly(vinyl alcohol)/native pea starch , 2008 .

[287]  D. Brunel,et al.  Organo-lined alumina surface from covalent attachment of alkylphosphonate chains in aqueous solution , 2010 .

[288]  Y. Yoon,et al.  Effects of parylene buffer layer on flexible substrate in organic light emitting diode , 2006 .

[289]  C. Geraci,et al.  Evaluation of the Potential Airborne Release of Carbon Nanofibers During the Preparation, Grinding, and Cutting of Epoxy-Based Nanocomposite Material , 2012, Journal of occupational and environmental hygiene.

[290]  V. Mittal Optimization of Polymer Nanocomposite Properties , 2010 .

[291]  Characterization and Optical Absorption Properties of Plasmonic Nanostructured Thin Films , 2013 .

[292]  Robert Landsiedel,et al.  Elastic CNT-polyurethane nanocomposite: synthesis, performance and assessment of fragments released during use. , 2013, Nanoscale.

[293]  Polycarpos Pissis,et al.  Glass transition and molecular dynamics in poly(dimethylsiloxane)/silica nanocomposites , 2005 .

[294]  A. Boudenne,et al.  Effect of filler size on thermophysical and electrical behavior of nanocomposites based on expanded graphite nanoparticles filled in low-density polyethylene matrix , 2013 .

[295]  M. Cho,et al.  A scale-bridging method for nanoparticulate polymer nanocomposites and their nondilute concentration effect , 2009 .

[296]  A. A. Gusev,et al.  Rational Design of Nanocomposites for Barrier Applications , 2001 .

[297]  M. Cho,et al.  Multi-scale modeling of cross-linked epoxy nanocomposites , 2009 .

[298]  Sanat K. Kumar,et al.  Molecular underpinnings of the mechanical reinforcement in polymer nanocomposites (vol 40, pg 4059, 2007) , 2007 .

[299]  R. Vaia,et al.  Liquid crystal polymer nanocomposites : direct intercalation of thermotropic liquid crystalline polymers into layered silicates , 2001 .

[300]  J. Lopez‐Cuesta Flame-retardant polymer nanocomposites , 2012 .

[301]  P. Wick,et al.  Weathering of a carbon nanotube/epoxy nanocomposite under UV light and in water bath: impact on abraded particles. , 2015, Nanoscale.

[302]  M. Cho,et al.  Method of scale bridging for thermoelasticity of cross-linked epoxy/SiC nanocomposites at a wide range of temperatures , 2012 .

[303]  H. Fischer Polymer nanocomposites: from fundamental research to specific applications , 2003 .

[304]  D. L. Zhang,et al.  Processing of advanced materials using high-energy mechanical milling , 2004 .

[305]  M. Fabra,et al.  Use of the electrohydrodynamic process to develop active/bioactive bilayer films for food packaging applications , 2016 .

[306]  Yuying Yan,et al.  Characterisation of surface wettability based on nanoparticles. , 2012, Nanoscale.

[307]  Zhiqiang Gao,et al.  Stacked graphene–TiO2 photoanode via electrospray deposition for highly efficient dye-sensitized solar cells , 2015 .

[308]  이 익모,et al.  Nanomaterials , 2021, Bionanotechnology.

[309]  Kyung Hyun Choi,et al.  Direct patterning and electrospray deposition through EHD for fabrication of printed thin film transistors , 2011 .

[310]  M. Latorre,et al.  Recent Prospects in the Inline Monitoring of Nanocomposites and Nanocoatings by Optical Technologies , 2016, Nanomaterials.

[311]  M. Kotal,et al.  Polymer nanocomposites from modified clays: Recent advances and challenges , 2015 .

[312]  Emiliano Bilotti,et al.  Polymer nanocomposites based on needle‐like sepiolite clays: Effect of functionalized polymers on the dispersion of nanofiller, crystallinity, and mechanical properties , 2008 .

[313]  Harald Ade,et al.  Compatibilizing Bulk Polymer Blends by Using Organoclays , 2004 .

[314]  M. Fabra,et al.  Development of multilayer corn starch-based food packaging structures containing β-carotene by means of the electro-hydrodynamic processing , 2016 .

[315]  Defeng Wu,et al.  Morphology, Crystalline Structure and Isothermal Crystallization Kinetics of Polybutylene Terephthalate/Montmorillonite Nanocomposites , 2005 .

[316]  K. Wong,et al.  Nanotechnology impact on the automotive industry. , 2014, Recent patents on nanotechnology.

[317]  K. Noller,et al.  Water Repellence and Oxygen and Water Vapor Barrier of PVOH-Coated Substrates before and after Surface Esterification , 2014 .

[318]  Constantine D. Papaspyrides,et al.  A review on polymer–layered silicate nanocomposites , 2008 .

[319]  M. Cho,et al.  The glass transition and thermoelastic behavior of epoxy-based nanocomposites: A molecular dynamics study , 2011 .

[320]  Markus Antonietti,et al.  Sol−Gel Nanocoating: An Approach to the Preparation of Structured Materials , 2001 .

[321]  Xiaodong Hu,et al.  EFFECT OF INJECTION MOLDING PARAMETERS ON THE ELECTRICAL CONDUCTIVITY OF POLYCARBONATE/CARBON NANOTUBE NANOCOMPOSITES , 2007 .

[322]  Gholam Hossein Hamedi,et al.  Using energy parameters based on the surface free energy concept to evaluate the moisture susceptibility of hot mix asphalt , 2015 .