Invited article: the fast readout low noise camera as a versatile x-ray detector for time resolved dispersive extended x-ray absorption fine structure and diffraction studies of dynamic problems in materials science, chemistry, and catalysis.

Originally conceived and developed at the European Synchrotron Radiation Facility (ESRF) as an "area" detector for rapid x-ray imaging studies, the fast readout low noise (FReLoN) detector of the ESRF [J.-C. Labiche, ESRF Newsletter 25, 41 (1996)] has been demonstrated to be a highly versatile and unique detector. Charge coupled device (CCD) cameras at present available on the public market offer either a high dynamic range or a high readout speed. A compromise between signal dynamic range and readout speed is always sought. The parameters of the commercial cameras can sometimes be tuned, in order to better fulfill the needs of specific experiments, but in general these cameras have a poor duty cycle (i.e., the signal integration time is much smaller than the readout time). In order to address scientific problems such as time resolved experiments at the ESRF, a FReLoN camera has been developed by the Instrument Support Group at ESRF. This camera is a low noise CCD camera that combines high dynamic range, high readout speed, accuracy, and improved duty cycle in a single image. In this paper, we show its application in a quasi-one-dimensional sense to dynamic problems in materials science, catalysis, and chemistry that require data acquisition on a time scale of milliseconds or a few tens of milliseconds. It is demonstrated that in this mode the FReLoN can be applied equally to the investigation of rapid changes in long range order (via diffraction) and local order (via energy dispersive extended x-ray absorption fine structure) and in situations of x-ray hardness and flux beyond the capacity of other detectors.

[1]  A. Dent,et al.  Identification of the surface species responsible for N2O formation from the chemisorption of NO on Rh/alumina. , 2007, Physical chemistry chemical physics : PCCP.

[2]  G. Vaughan,et al.  Self-propagating high-temperature synthesis of TiC–WC composite materials , 2006 .

[3]  Paola Coan,et al.  Evaluation of imaging performance of a taper optics CCD; FReLoN' camera designed for medical imaging. , 2006, Journal of synchrotron radiation.

[4]  A. Dent,et al.  Rapid monitoring of the nature and interconversion of supported catalyst phases and of their influence upon performance: CO oxidation to CO2 by gamma-Al2O3 supported Rh catalysts. , 2006, Chemistry.

[5]  B. Weckhuysen,et al.  Synchrotron radiation effects on catalytic systems as probed with a combined in-situ UV-vis/XAFS spectroscopic setup. , 2005, The journal of physical chemistry. B.

[6]  G. Vaughan,et al.  Time-resolved XRD study of TiC–TiB2 composites obtained by SHS , 2004 .

[7]  F. Schotte,et al.  Visualizing chemical reactions in solution by picosecond x-ray diffraction. , 2004, Physical review letters.

[8]  Q. Pankhurst,et al.  Self propagating high temperature synthesis of magnesium zinc ferrites (MgxZn1−xFe2O3): thermal imaging and time resolved X-ray diffraction experiments , 2004 .

[9]  A. Suzuki,et al.  Time scale and elementary steps of CO-induced disintegration of surface rhodium clusters. , 2003, Angewandte Chemie.

[10]  A. Dent,et al.  Rapid phase fluxionality as the determining factor in activity and selectivity of highly dispersed, Rh/Al2O3 in deNOx catalysis. , 2002, Angewandte Chemie.

[11]  G. Vaughan,et al.  TiC-NiAl composites obtained by SHS: a time-resolved XRD study , 2002 .

[12]  A. Terry,et al.  In‐Situ time‐resolved X‐ray diffraction: The current state of the art , 2002 .

[13]  M. Abu‐Omar,et al.  Deactivation of Methylrhenium Trioxide−Peroxide Catalysts by Diverse and Competing Pathways , 1996 .

[14]  A. Al-Ajlouni,et al.  Epoxidation of Styrenes by Hydrogen Peroxide As Catalyzed by Methylrhenium Trioxide , 1995 .

[15]  J. Espenson,et al.  Kinetics and Mechanism of Oxidation of Anilines by Hydrogen Peroxide As Catalyzed by Methylrhenium Trioxide , 1995 .

[16]  J. Espenson,et al.  OXIDATION OF ORGANIC SULFIDES BY ELECTROPHILICALLY-ACTIVATED HYDROGEN PEROXIDE : THE CATALYTIC ABILITY OF METHYLRHENIUM TRIOXIDE , 1994 .

[17]  G. Graham,et al.  Why Rhodium in Automotive Three-Way Catalysts? , 1994 .

[18]  K. Taylor Nitric oxide catalysis in automotive exhaust systems , 1993 .

[19]  W. Herrmann,et al.  Methyltrioxorhenium as Catalyst for Olefin Oxidation , 1991 .

[20]  H. Komber,et al.  Methyltrioxorhenium as Catalyst for Olefin Metathesis , 1991 .

[21]  F. Deorsola,et al.  In situ synthesis of TiC–TiB2–hBN–SiC composites through SHS , 2004 .

[22]  Ryuhei Uehara,et al.  Solar hydrogen generation with H2O/ZnO/MnFe2O4 system , 2004 .

[23]  M. Abu‐Omar,et al.  Oxidations of ER3 (E = P, As, or Sb) by Hydrogen Peroxide: Methylrhenium Trioxide as Catalyst , 1995 .

[24]  J. B. Holt,et al.  Combustion and plasma synthesis of high-temperature materials , 1990 .