Characterizing Time-Dependent Stability and Viscosity of Acid–Crude Emulsions for Matrix-Acidizing Applications

The process of matrix acidizing, while aiming at enhancing near-wellbore flow conditions, can result in damaging effects when acid–oil emulsions form. Understanding the behavior of these emulsions, especially when it comes to its stability and viscosity, is an essential step in the design of acid jobs that can lead to successful well productivity enhancement. In this study, we investigate the time-dependent nature of these emulsions using bottle tests and coreflooding experiments. The results of the work provide new insights into the formation of in situ emulsion. This has direct impact on the design of acid jobs in well stimulation treatments.

[1]  Z. Fan,et al.  An Efficient Method to Determine Wormhole Propagation During Matrix Acidizing , 2018 .

[2]  P. K. Kilpatrick Water-in-Crude Oil Emulsion Stabilization: Review and Unanswered Questions , 2012 .

[3]  M. Abdel-raouf,et al.  Factors Affecting the Stability of Crude Oil Emulsions , 2012 .

[4]  Xiuyu Wang,et al.  Role of Acid Components and Asphaltenes in Wyoming Water-in-Crude Oil Emulsions , 2011 .

[5]  A. Firoozabadi,et al.  Tuning size and electrostatics in non-polar colloidal asphaltene suspensions by polymeric adsorption , 2011 .

[6]  O. Mullins The asphaltenes. , 2011, Annual review of analytical chemistry.

[7]  J. Bullard,et al.  A comparison of viscosity-concentration relationships for emulsions. , 2009, Journal of colloid and interface science.

[8]  P. K. Kilpatrick,et al.  Dynamic Asphaltene−Resin Exchange at the Oil/Water Interface: Time-Dependent W/O Emulsion Stability for Asphaltene/Resin Model Oils† , 2007 .

[9]  O. Falode,et al.  Effects of Mixing Conditions, Oil Type and Aqueous Phase Composition on Some Crude Oil Emulsions , 2005 .

[10]  I. Hénaut,et al.  Crude Oil Emulsion Properties and Their Application to Heavy Oil Transportation , 2004 .

[11]  Hussein,et al.  Water-in-Hydrocarbon Emulsions Stabilized by Asphaltenes at Low Concentrations. , 2000, Journal of colloid and interface science.

[12]  Peter K. Kilpatrick,et al.  Effects of Asphaltene Solvency on Stability of Water-in-Crude-Oil Emulsions , 1997 .

[13]  A. Das,et al.  Concentrated emulsions. 3. Studies on the influence of continuous-phase viscosity, volume fraction, droplet size, and temperature on emulsion viscosity , 1992 .

[14]  D. D. Eley,et al.  Emulsions of water in asphaltene-containing oils 1. Droplet size distribution and emulsification rates , 1988 .

[15]  C. Radke,et al.  Flow mechanism of dilute, stable emulsions in porous media , 1984 .

[16]  T. J. Jones,et al.  Water-In-Crude Oil Emulsion Stability And Emulsion Destabilization By Chemical Demulsifiers , 1978 .

[17]  T. Yen,et al.  Macrostructures of the asphaltic fractions by various instrumental methods , 1967 .