Potential of used frying oil in paving material: solution to environmental pollution problem

The improper disposal of used frying oil (UFO) presents numerous ecological, environmental and municipal problems. Of great concern is the resultant blockage of municipal drainage systems and water treatment facilities, harm to wildlife when they become coated in it and detriment to aquatic life and ecosystems due to the depletion of the oxygen content in water bodies such as rivers and lakes that have become contaminated. Statistics show that in Trinidad and Tobago, in excess of one million liters of used cooking oil is collected annually from various restaurant chains. This paper investigated the potential of using UFO as a performance enhancing additive for road paving applications utilizing Trinidad Lake Asphalt (TLA) and Trinidad Petroleum Bitumen (TPB) as a mitigation strategy for improper UFO disposal. Modified blends containing various additions of UFO (2–10% wt) were prepared for the TLA and TPB asphaltic binders. Results demonstrated in terms of stiffness, increasing the dosage of UFO in TLA and TPB base binders resulted in a gradual decrease in stiffness (G* value decreased). In terms of elasticity, increasing the dosage of the UFO additive in TLA resulted in a general decrease in the elasticity of the blends indicated by an increase in phase angle or phase lag (δ). Increasing dosages of the UFO additive in TPB resulted in a significant decrease in δ where the most elastic blend was at the 6% UFO level. TLA and UFO-TLA modified blends exhibited significantly lower values of δ and higher values of G* confirming the superiority of the TLA material. Incorporation of the UFO in the blends led to a decrease in the rutting resistance and increase in the fatigue cracking resistance (decrease in G*/sinδ and G*sinδ, respectively). This study highlighted the potential for the reuse of UFO as an asphalt modifier capable of producing customized UFO modified asphaltic blends for special applications and confirms its feasibility as an environmentally attractive means of reusing the waste/hazardous UFO material locally.

[1]  B. Birgisson,et al.  Polymer modification of bitumen : Advances and challenges , 2014 .

[2]  S. Raghavan,et al.  Highly Viscoelastic Wormlike Micellar Solutions Formed by Cationic Surfactants with Long Unsaturated Tails , 2001 .

[3]  Jerry D. Murphy,et al.  The impact of the life cycle analysis methodology on whether biodiesel produced from residues can meet the EU sustainability criteria for biofuel facilities constructed after 2017 , 2011 .

[4]  Bashir Sajo Mienda,et al.  Waste Cooking oil: A Resourceful Waste for Lipase Catalysed Biodiesel Production , 2014 .

[5]  José A. Navas,et al.  Polycyclic aromatic hydrocarbons in frying oils and snacks. , 2006, Journal of food protection.

[6]  R. Elliott,et al.  Characteristics of elastomeric and plastomeric binders in contact with natural asphalts , 2008 .

[7]  B. A. Conway,et al.  The effects of laforin, malin, Stbd1, and Ptg deficiencies on heart glycogen levels in Pompe disease mouse models , 2015 .

[8]  Majid Zargar,et al.  Investigation of the possibility of using waste cooking oil as a rejuvenating agent for aged bitumen. , 2012, Journal of hazardous materials.

[9]  THE EFFECT OF PARTICLE SIZE AND CONCENTRATION OF CRUMB RUBBER ON THE RUTTING AND FATIGUE CRACKING RESISTANCE OF TRINIDAD LAKE ASPHALT AND PETROLEUM BITUMEN , 2006 .

[10]  R. Maharaj,et al.  Mechanistic Enhancement of Asphaltic Materials Using Fly Ash , 2016 .

[11]  C. Maharaj,et al.  The Effect of Polyethylene Terephthalate Particle Size and Concentration on the Properties of Asphalt and Bitumen as An Additive , 2015 .

[12]  Rupesh R. Pudi Biodiesel Production , 2016 .

[13]  Diesel Fuel from Used Frying Oil , 2014, TheScientificWorldJournal.

[14]  M. El-Fadel,et al.  Strategies for vehicle waste-oil management: a case study , 2001 .

[15]  L. Goonewardene,et al.  Effects of feeding added protein and fat on feedlot performance and carcass quality in large frame steers , 1994 .

[16]  L. Oyekunle Certain Relationships between Chemical Composition and Properties of Petroleum Asphalts from Different Origin , 2006 .

[17]  N. Bianchi,et al.  Release of Polycyclic Aromatic Hydrocarbons and Heavy Metals from Rubber Crumb in Synthetic Turf Fields: Preliminary Hazard Assessment for Athletes , 2014 .

[18]  P. F. D. C. Neto,et al.  Produção de biocombustível alternativo ao óleo diesel através da transesterificação de óleo de soja usado em frituras , 2000 .

[19]  William F. Hunt,et al.  Implementation and Performance of Stormwater Best Management Practice Retrofits in Wilmington, NC , 2008 .

[21]  Chi-Tang Ho,et al.  Chemical reactions involved in the deep-fat frying of foods1 , 1978 .

[22]  Iqbal Marie,et al.  Promoting the use of crumb rubber concrete in developing countries. , 2008, Waste management.

[23]  L. Oyekunle,et al.  Influence of Chemical Composition on the Physical Characteristics of Paving Asphalts , 2007 .

[24]  Muhamad Nazri Borhan,et al.  The effects of used cylinder oil on asphalt mixes , 2009 .

[25]  M. Karim,et al.  Investigation on physical properties of waste cooking oil – Rejuvenated bitumen binder , 2012 .

[26]  Andreas Brekke,et al.  Environmental Impacts and Costs of Hydrotreated Vegetable Oils, Transesterified Lipids and Woody BTL—A Review , 2011 .

[27]  Qunwei Wang,et al.  Waste cooking oil as an energy resource: Review of Chinese policies , 2012 .

[28]  K. Anand,et al.  Effect of Micro and Nano Zinc Oxide on the Properties of Pre-Vulcanized Natural Rubber Latex Films , 2015 .

[29]  V. Rathod,et al.  Applications of Waste Cooking Oil Other Than Biodiesel: A Review , 2015 .

[30]  V. Gude,et al.  Biodiesel Production from Waste Cooking Oil Using Sulfuric Acid and Microwave Irradiation Processes , 2012 .

[31]  M. Azpilicueta,et al.  Estudio de la degradación de los aceites de oliva sometidos a fritura. I. Determinación estadística del parámetro que mejor cuantifica esta degradación , 1991 .

[32]  Stephen S. Chang,et al.  Chemical reactions involved in the deep fat frying of foods. II. Identification of acidic volatile decomposition products of corn oil , 1967 .