Nanospace-confined formation of flattened Sn sheets in pre-seeded graphenes for lithium ion batteries.

Flattened Sn sheets are prepared from the pre-seeded Sn salt in the interlayer nanospace of a graphene membrane, which acts as a template to shape Sn crystals and prevent the aggregation. The sandwich structure clamping Sn sheets accommodates the volume change during charge/discharge. We show that the hybrid possesses excellent rate performance and cycling stability as an anode for lithium ion batteries.

[1]  Jing Ning,et al.  Reduced Graphene Oxide‐Mediated Growth of Uniform Tin‐Core/Carbon‐Sheath Coaxial Nanocables with Enhanced Lithium Ion Storage Properties , 2012, Advanced materials.

[2]  Vincent S. Battaglia,et al.  Multilayer nanoassembly of Sn-nanopillar arrays sandwiched between graphene layers for high-capacity lithium storage , 2011 .

[3]  H. Dai,et al.  Ni(OH)2 nanoplates grown on graphene as advanced electrochemical pseudocapacitor materials. , 2010, Journal of the American Chemical Society.

[4]  Yan‐Bing He,et al.  The effect of graphene wrapping on the performance of LiFePO4 for a lithium ion battery , 2013 .

[5]  Lei Wang,et al.  Protein-inspired synthesis of SnO2 nanocrystals with controlled carbon nanocoating as anode materials for lithium-ion battery , 2013 .

[6]  Guangmin Zhou,et al.  Graphene-Wrapped Fe(3)O(4) Anode Material with Improved Reversible Capacity and Cyclic Stability for Lithium Ion Batteries , 2010 .

[7]  Yong Wang,et al.  Sn@CNT nanostructures rooted in graphene with high and fast Li-storage capacities. , 2011, ACS nano.

[8]  Qi-Hui Wu,et al.  Three-dimensional Sn-graphene anode for high-performance lithium-ion batteries. , 2013, Nanoscale.

[9]  P. G. Harrison Chemistry of tin , 1989 .

[10]  Hui‐Ming Cheng,et al.  Synthesis of graphene sheets with high electrical conductivity and good thermal stability by hydrogen arc discharge exfoliation. , 2009, ACS nano.

[11]  Qiang Zhang,et al.  A Three‐Dimensional Carbon Nanotube/Graphene Sandwich and Its Application as Electrode in Supercapacitors , 2010, Advanced materials.

[12]  Haihui Wang,et al.  Superior cycle performance of Sn@C/graphene nanocomposite as an anode material for lithium-ion batteries , 2011 .

[13]  Chunsheng Wang,et al.  Sponge-like porous carbon/tin composite anode materials for lithium ion batteries , 2012 .

[14]  Bei Wang,et al.  Sn/graphene nanocomposite with 3D architecture for enhanced reversible lithium storage in lithium ion batteries , 2009 .

[15]  Chunsheng Wang,et al.  Uniform nano-Sn/C composite anodes for lithium ion batteries. , 2013, Nano letters.

[16]  Yu‐Guo Guo,et al.  Tin Nanoparticles Impregnated in Nitrogen-Doped Graphene for Lithium-Ion Battery Anodes , 2013 .

[17]  Feng Li,et al.  Oxygen bridges between NiO nanosheets and graphene for improvement of lithium storage. , 2012, ACS nano.

[18]  Li-Jun Wan,et al.  Nanocarbon networks for advanced rechargeable lithium batteries. , 2012, Accounts of chemical research.

[19]  Qiang Zhang,et al.  Advanced Asymmetric Supercapacitors Based on Ni(OH)2/Graphene and Porous Graphene Electrodes with High Energy Density , 2012 .

[20]  Quan-hong Yang,et al.  A sandwich structure of graphene and nickel oxide with excellent supercapacitive performance , 2011 .

[21]  Wei Lv,et al.  A unique carbon with a high specific surface area produced by the carbonization of agar in the presence of graphene. , 2013, Chemical communications.

[22]  Ray P. S. Han,et al.  Robust and stable intercalated graphene encapsulation of tin nanorods for enhanced cycle and capacity performance for lithium storage , 2013 .

[23]  Yong Wang,et al.  Microwave-assisted synthesis of a Co3O4–graphene sheet-on-sheet nanocomposite as a superior anode material for Li-ion batteries , 2010 .

[24]  B. Chowdari,et al.  Metal oxides and oxysalts as anode materials for Li ion batteries. , 2013, Chemical reviews.

[25]  R. Li,et al.  Hierarchical nanostructured core-shell Sn@C nanoparticles embedded in graphene nanosheets: spectroscopic view and their application in lithium ion batteries. , 2013, Physical chemistry chemical physics : PCCP.

[26]  Wei Lv,et al.  Flexible and planar graphene conductive additives for lithium-ion batteries , 2010 .

[27]  Xianglong Li,et al.  Graphene‐Confined Sn Nanosheets with Enhanced Lithium Storage Capability , 2012, Advanced materials.

[28]  Lian Gao,et al.  Free-standing and binder-free lithium-ion electrodes based on robust layered assembly of graphene and Co3O4 nanosheets. , 2013, Nanoscale.

[29]  Yan‐Bing He,et al.  A graphene-based nanostructure with expanded ion transport channels for high rate Li-ion batteries. , 2012, Chemical communications.

[30]  R. Ruoff,et al.  Reduced graphene oxide/tin oxide composite as an enhanced anode material for lithium ion batteries prepared by homogenous coprecipitation , 2011 .

[31]  Jiaqi Huang,et al.  Annealing a graphene oxide film to produce a free standing high conductive graphene film , 2012 .

[32]  Weixiang Chen,et al.  In situ synthesis of MoS2/graphene nanosheet composites with extraordinarily high electrochemical performance for lithium ion batteries. , 2011, Chemical communications.