Atomic Ru Immobilized on Porous h-BN through Simple Vacuum Filtration for Highly Active and Selective CO2 Methanation

As CO2 emissions are sharply increasing, processes for converting CO2 into value-added products are becoming more desirable. Ruthenium-based catalysts are the most active for CO2 methanation; howev...

[1]  Xizhang Wang,et al.  The simplest construction of single-site catalysts by the synergism of micropore trapping and nitrogen anchoring , 2019, Nature Communications.

[2]  Jinwoo Lee,et al.  Versatile Strategy for Tuning ORR Activity of a Single Fe-N4 Site by Controlling Electron-Withdrawing/Donating Properties of a Carbon Plane. , 2019, Journal of the American Chemical Society.

[3]  P. Ajayan,et al.  Doping Nanoscale Graphene Domains Improves Magnetism in Hexagonal Boron Nitride , 2019, Advanced materials.

[4]  Shihao Wei,et al.  Single-Metal Atom Anchored on Boron Monolayer (β12) as an Electrocatalyst for Nitrogen Reduction into Ammonia at Ambient Conditions: A First-Principles Study , 2019, The Journal of Physical Chemistry C.

[5]  S. Bare,et al.  Low-Temperature Restructuring of CeO2-Supported Ru Nanoparticles Determines Selectivity in CO2 Catalytic Reduction. , 2018, Journal of the American Chemical Society.

[6]  H. Tahini,et al.  Electrocatalytic Reduction of Carbon Dioxide to Methane on Single Transition Metal Atoms Supported on a Defective Boron Nitride Monolayer: First Principle Study , 2018, Advanced Theory and Simulations.

[7]  Yadong Li,et al.  Temperature-Controlled Selectivity of Hydrogenation and Hydrodeoxygenation in the Conversion of Biomass Molecule by the Ru1/mpg-C3N4 Catalyst. , 2018, Journal of the American Chemical Society.

[8]  M. Shu,et al.  Achieving a Record‐High Yield Rate of 120.9 μgNH3  mgcat.−1  h−1 for N2 Electrochemical Reduction over Ru Single‐Atom Catalysts , 2018, Advanced materials.

[9]  Hyunjoo J. Lee,et al.  Fully Dispersed Rh Ensemble Catalyst To Enhance Low-Temperature Activity. , 2018, Journal of the American Chemical Society.

[10]  Y. Bando,et al.  Densely Interconnected Porous BN Frameworks for Multifunctional and Isotropically Thermoconductive Polymer Composites , 2018, Advanced Functional Materials.

[11]  Tao Zhang,et al.  Heterogeneous single-atom catalysis , 2018, Nature Reviews Chemistry.

[12]  Chun-Hua Yan,et al.  Low-Temperature CO2 Methanation over CeO2-Supported Ru Single Atoms, Nanoclusters, and Nanoparticles Competitively Tuned by Strong Metal–Support Interactions and H-Spillover Effect , 2018 .

[13]  K. M. Gupta,et al.  Catalytic amino acid production from biomass-derived intermediates , 2018, Proceedings of the National Academy of Sciences.

[14]  Yongfeng Hu,et al.  Carbon Nanosheets Containing Discrete Co-Nx-By-C Active Sites for Efficient Oxygen Electrocatalysis and Rechargeable Zn-Air Batteries. , 2018, ACS nano.

[15]  N. Zheng,et al.  Strategies for Stabilizing Atomically Dispersed Metal Catalysts , 2018 .

[16]  H. Fei,et al.  Single-Atomic Ruthenium Catalytic Sites on Nitrogen-Doped Graphene for Oxygen Reduction Reaction in Acidic Medium. , 2017, ACS nano.

[17]  Marco-Tulio F. Rodrigues,et al.  Carbon Dioxide Hydrogenation over a Metal-Free Carbon-Based Catalyst , 2017 .

[18]  J. Lauterbach,et al.  Supported Cobalt Nanorod Catalysts for Carbon Dioxide Hydrogenation , 2017 .

[19]  R. Si,et al.  Supported Rhodium Catalysts for Ammonia-Borane Hydrolysis: Dependence of the Catalytic Activity on the Highest Occupied State of the Single Rhodium Atoms. , 2017, Angewandte Chemie.

[20]  K. Jalama.  Carbon dioxide hydrogenation over nickel-, ruthenium-, and copper-based catalysts: Review of kinetics and mechanism , 2017 .

[21]  H. Yamashita,et al.  Isolated Single-Atomic Ru Catalyst Bound on a Layered Double Hydroxide for Hydrogenation of CO2 to Formic Acid , 2017 .

[22]  G. Somorjai,et al.  Copper Nanocrystals Encapsulated in Zr-based Metal-Organic Frameworks for Highly Selective CO2 Hydrogenation to Methanol. , 2016, Nano letters.

[23]  Mark D. Smith,et al.  (BB)-Carboryne Complex of Ruthenium: Synthesis by Double B–H Activation at a Single Metal Center , 2016, Journal of the American Chemical Society.

[24]  P. Ajayan,et al.  Pyridinic‐Nitrogen‐Dominated Graphene Aerogels with Fe–N–C Coordination for Highly Efficient Oxygen Reduction Reaction , 2016 .

[25]  Wen-Hau Zhang,et al.  A Graphene Composite Material with Single Cobalt Active Sites: A Highly Efficient Counter Electrode for Dye-Sensitized Solar Cells. , 2016, Angewandte Chemie.

[26]  Fei Wang,et al.  Active Site Dependent Reaction Mechanism over Ru/CeO2 Catalyst toward CO2 Methanation. , 2016, Journal of the American Chemical Society.

[27]  V. Varshney,et al.  Thermal Conductivity of Wurtzite Zinc-Oxide from First-Principles Lattice Dynamics – a Comparative Study with Gallium Nitride , 2016, Scientific Reports.

[28]  P. Ajayan,et al.  Atomic cobalt on nitrogen-doped graphene for hydrogen generation , 2015, Nature Communications.

[29]  G. Somorjai,et al.  High-performance hybrid oxide catalyst of manganese and cobalt for low-pressure methanol synthesis , 2015, Nature Communications.

[30]  Vanessa N Yang,et al.  Isolated metal active site concentration and stability control catalytic CO2 reduction selectivity. , 2015, Journal of the American Chemical Society.

[31]  Yumin Liu,et al.  Highly dispersed Ru on K-doped meso–macroporous SiO2 for the preferential oxidation of CO in H2-rich gases , 2014 .

[32]  G. Somorjai,et al.  Combining in situ NEXAFS spectroscopy and CO₂ methanation kinetics to study Pt and Co nanoparticle catalysts reveals key insights into the role of platinum in promoted cobalt catalysis. , 2014, Journal of the American Chemical Society.

[33]  Jingguang G. Chen,et al.  Molybdenum carbide as alternative catalysts to precious metals for highly selective reduction of CO2 to CO. , 2014, Angewandte Chemie.

[34]  Ib Chorkendorff,et al.  Discovery of a Ni-Ga catalyst for carbon dioxide reduction to methanol. , 2014, Nature chemistry.

[35]  D. Allwood,et al.  Fabrication and luminescence of monolayered boron nitride quantum dots. , 2014, Small.

[36]  I. V. Grigorieva,et al.  Precise and Ultrafast Molecular Sieving Through Graphene Oxide Membranes , 2014, Science.

[37]  L. Kovarik,et al.  CO2 Reduction on Supported Ru/Al2O3 Catalysts: Cluster Size Dependence of Product Selectivity , 2013 .

[38]  D. Portehault,et al.  Porous boron nitride nanosheets for effective water cleaning , 2013, Nature Communications.

[39]  Kenji Watanabe,et al.  Thermal conductivity and phonon transport in suspended few-layer hexagonal boron nitride. , 2013, Nano letters.

[40]  B. P. Jelle,et al.  Thermal Conductivity of TiO2 Nanotubes , 2013 .

[41]  S. Dahl,et al.  Highly dispersed supported ruthenium oxide as an aerobic catalyst for acetic acid synthesis , 2012 .

[42]  Qiang Zhang,et al.  Structural rearrangements of Ru nanoparticles supported on carbon nanotubes under microwave irradiation. , 2011, Chemical communications.

[43]  Xiaofeng Yang,et al.  Single-atom catalysis of CO oxidation using Pt1/FeOx. , 2011, Nature chemistry.

[44]  Wei Wang,et al.  Recent advances in catalytic hydrogenation of carbon dioxide. , 2011, Chemical Society reviews.

[45]  A. Baldereschi,et al.  Hydrogen-Assisted Transformation of CO2 on Nickel: The Role of Formate and Carbon Monoxide , 2010 .

[46]  Eric W. McFarland,et al.  A highly dispersed Pd-Mg/SiO2 catalyst active for methanation of CO2 , 2009 .

[47]  T. Abe,et al.  CO2 methanation property of Ru nanoparticle-loaded TiO2 prepared by a polygonal barrel-sputtering method , 2009 .

[48]  J. Regalbuto,et al.  The synthesis of highly dispersed noble and base metals on silica via strong electrostatic adsorption: I. Amorphous silica , 2008 .

[49]  M. Kuśmierz.  Kinetic study on carbon dioxide hydrogenation over Ru/γ-Al2O3 catalysts , 2008 .

[50]  E. Lundgren,et al.  Understanding the structural deactivation of ruthenium catalysts on an atomic scale under both oxidizing and reducing conditions. , 2005, Angewandte Chemie.

[51]  Piotr Olszewski,et al.  Catalytic activity of the M/(3ZnO·ZrO2) system (M = Cu, Ag, Au) in the hydrogenation of CO2 to methanol , 2004 .

[52]  R. K. Toghiani,et al.  Partial oxidation of methane to H2 and CO over Rh/SiO2 and Ru/SiO2 catalysts , 2004 .

[53]  I. Nakamura,et al.  Structure-Dependent Kinetics for Synthesis and Decomposition of Formate Species over Cu(111) and Cu(110) Model Catalysts , 2001 .

[54]  H. Wise,et al.  Thermodynamic properties of surface carbon on ruthenium , 1983 .