Synthesis and structure of a copper(I) complex with 1-aminopyrene: building of a 2D structure composed of stacking pyrene rings

The first copper(I) complex with aminopyrene [Cu(apyr)3]ClO4·MeOH is synthesized and characterized crystallographically; the most remarkable feature of the compound is its 2D structure connected through intra- and inter-molecular stacking of the aromatic rings.

[1]  S. Kitagawa,et al.  Synthesis, structures, and properties of the molecular assemblies of copper(I) and silver(I) complexes with phenazine. Novel donor-acceptor and huge polynuclear complexes , 1993 .

[2]  W. Schaefer,et al.  Preparation and characterization of a bis(pentaammineosmium(II)) pyrene complex , 1991 .

[3]  J. Tanaka,et al.  Crystal and electronic structures of radical salts of 2,7-bis(methylthio)-1,6-dithiapyrene(MTDTPY) and 2,7-bis(methylseleno)-1,6-dithiapyrene(MSDTPY). , 1990 .

[4]  A. Epstein,et al.  Ferromagnetic behavior of linear chain electron-transfer complexes. Decamethylferrocene electron-transfer salts of 2,5-disubstituted-7,7,8,8-tetracyano-p-quinodimethanes. Magnetic characterization of [Fe(C5Me5)2].cntdot.+[TCNQI2].cntdot.- and structures of [TCNQI2]n- (n = 0, 1, 2) , 1990 .

[5]  H. Masuda,et al.  Synthesis and structures of (2,9-dimethyl-1,10-phenanthroline)(acetonitrile)copper(I) perchlorate and hexafluorophosphate. A correlation between bond angles and bond distances in T- and Y-shaped three-coordinate copper(I) complexes , 1989 .

[6]  M. Sasaki,et al.  Methylthio- and ethanediyldithio-substituted 1,6-dithiapyrenes and their charge-transfer complexes: new organic molecular metals , 1987 .

[7]  T. Enoki,et al.  Novel peri-condensed Weitz-type donors: synthesis, physical properties, and crystal structures of 3,10-dithiaperylene (DTPR), 1,6-dithiapyrene (DTPY), and some of their CT complexes , 1986 .

[8]  M. Arakawa,et al.  Synthesis and antitumor activity of cis-platinum complexes of aromatic amines. , 1986, Chemical & pharmaceutical bulletin.

[9]  J. C. Barnes,et al.  Complexes of pyrene with 2,4,6-trinitroanisole. Studies of association in solution and the crystal structure of the 1:1 complex , 1984 .

[10]  L. D. Brown,et al.  Rational synthesis of unidimensional mixed valence solids. Structure-oxidation state-charge transport relationships in iodinated nickel and palladium bis(benzoquinone dioximates) , 1979 .

[11]  G. Grynkewich,et al.  Rational synthesis of unidimensional mixed valence solids. Structural, spectral, and electrical studies of charge distribution and transport in partially oxidized nickel and palladium bisdiphenylglyoximates , 1979 .

[12]  H. Kuroda,et al.  The refinement of the crystal structure of the pyrene–tetracyanoethylene complex , 1968 .

[13]  A. Camerman,et al.  The crystal and molecular structure of pyrene , 1965 .