Development of high power VRLA batteries using novel materials and processes

Abstract Nowadays UPS manufacturers demand batteries with very high specific power and relatively low specific energy, because most mains failures can be defined as “microfailures”, usually of the order of seconds. Due to this fact, it is not necessary to provide energy but power. Within a 3-year EU funded project, a new AGM valve-regulated lead–acid battery with weight and volume substantially reduced, as well as a substantial improvement in its reliability, is under development. These aspects can provide the achievement of a more efficient, safe and economic energy supply. Battery specific power is practically related to electrode area, so that its increase, and therefore an electrode thickness reduction, appear essential to achieve the project objectives. Furthermore, it is necessary to achieve a similar reduction in the conventional glass microfibre separator. But such thin material should have improved mechanical properties and can make the battery more prone to develop short circuits across the separator. In order to avoid this problem, a new microporous polyethylene membrane has been developed and tested, with excellent mechanical properties, high porosity and low pore size. For these reasons, the final separator configuration includes a combination of both materials, improved non-woven glass microfibre and the polyethylene membrane. Batteries are designed and assembled by Tudor (Exide Technologies) as battery manufacturer and will be tested in real conditions by MGE UPS Systems as end user. Daramic for the membrane and Bernard Dumas for the glass microfibre mat, have developed and supplied the separators, while the Inorganic Chemistry Department of Cordoba University carries out fundamental research studies on very thin electrodes.

[1]  W Böhnstedt,et al.  New developments in separators for valve-regulated lead–acid batteries , 1999 .

[2]  Jenn‐Shing Chen Development of VRLA batteries for high rate discharge applications , 2000 .

[3]  D. Linden Handbook Of Batteries , 2001 .

[4]  J. Morales,et al.  Spray pyrolysis as a method for preparing PbO coatings amenable to use in lead-acid batteries , 2002 .

[5]  P. T. Moseley,et al.  ALABC 2000 — the way ahead , 2001 .

[6]  Ramesh C. Bhardwaj,et al.  Lead acid battery with thin metal film (TMF®) technology for high power applications , 2000 .

[7]  W. Boehnstedt Challenges for automotive battery separator development , 1997 .

[8]  F. Trinidad,et al.  High power valve regulated lead-acid batteries for new vehicle requirements , 2001 .

[9]  M. Bassini,et al.  Effect of calcium, tin and silver contents in the positive grids of automotive batteries with respect to the grid manufacturing process , 1999 .

[10]  Robert F. Nelson,et al.  High-power batteries for the new 36/42 V automotive systems , 2002 .

[11]  H. Döring,et al.  Effect of compression on the behaviour of lead-acid batteries , 2001 .

[12]  A. L Ferreira A multi-layered approach for absorptive glass-mat separators , 1999 .

[13]  A Cooper The European ALABC IMPLAB project: final results and conclusions , 2002 .

[14]  R. D. Prengaman,et al.  In pursuit of high specific energy, high specific power valve-regulated lead-acid batteries , 2002 .

[15]  S. Dou,et al.  Electrochemical performance of nanocrystalline lead oxide in VRLA batteries , 2001 .