论文信息 - Temperature programmed retention indices: Calculation from isothermal data. Part 1: Theory

Temperature programmed retention indices: Calculation from isothermal data. Part 1: Theory

Summary Direct conversion of isothermal to temperature programmed indices is not possible. In this work it is shown that linear temperature programmed retention indices can only be calculated from isothermal retention data if the temperature dependence of both the distribution coefficients and the column dead time are taken into account. Procedures are described which allow calculation of retention temperatures and from these, accurate programmed retention indices. Within certain limits the initial oven temperature and programming rate can be chosen freely.The prerequisite forthis calculation

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