Effect of oxalic acid pretreatment of wood chips on manufacturing medium-density fiberboard

Abstract The main objective of this study was to evaluate the effect of oxalic acid (OA) wood chips pretreatment prior to refining, which is done to reduce energy used during the refining process. Selected mechanical and physical performances of medium-density fiberboard (MDF) – internal bonding (IB), modulus of elasticity (MOE), modulus of rupture (MOR), water absorption (WA) and thickness swelling (TS) – made from this OA-pretreated wood were tested and the effect of the OA treatment on carbohydrates investigated. The results showed that the OA treatment significantly reduced refining energy usage, and improved MDF dimensional stability and lightness. However, the OA treatment had a negative effect on the internal bonding strength of MDF panels. The amount of extracted carbohydrates was dramatically increased, up to 24 times, by the OA pretreatment. Carbohydrates extracted from wood chips could be a potential sustainable resource for biofuel or bio-based chemicals. This paper is a contribution to the so-called “value prior to pulping (VPP)” concept.

[1]  M. J. Effland Modified procedure to determine acid-insoluble lignin in wood and pulp. , 1977 .

[2]  Шуберт Ханс-Лудвиг,et al.  A method for producing pulp , 1997 .

[3]  M. Davis A Rapid Modified Method for Compositional Carbohydrate Analysis of Lignocellulosics by High pH Anion-Exchange Chromatography with Pulsed Amperometric Detection (HPAEC/PAD) , 1998 .

[4]  M. Sabourin,et al.  Oxalic acid pretreatment for mechanical pulping greatly improves paper strength while maintaining scattering power and reducing shives and triglycerides , 2003 .

[5]  G. Han,et al.  Development of high-performance UF-bonded reed and wheat straw medium-density fiberboard , 2001, Journal of Wood Science.

[6]  B. Kurek,et al.  Oxalic acid: a microbial metabolite of interest for the pulping industry. , 2004, Comptes rendus biologies.

[7]  Engin Derya Gezer,et al.  Mechanical and chemical behavior of spruce wood modified by heat , 2006 .

[8]  Gary M. Scott,et al.  From forest biomass to chemicals and energy... Biorefinery initiative in New York State , 2006 .

[9]  A. van Heiningen,et al.  Converting a kraft pulp mill into an integrated forest biorefinery. , 2006 .

[10]  B. Riedl,et al.  Dimensional stability of MDF panels produced from heat-treated fibres , 2006 .

[11]  J. Winandy,et al.  THERMAL DEGRADATION OF WOOD FIBERS DURING HOT-PRESSING OF MDF COMPOSITES: PART I. RELATIVE EFFECTS AND BENEFITS OF THERMAL EXPOSURE , 2007 .

[12]  W. Kenealy,et al.  Vapor-phase diethyl oxalate pretreatment of wood chips: Part 1. Energy savings and improved pulps , 2007 .

[13]  Mark F. Davis,et al.  Vapor-phase diethyl oxalate pretreatment of wood chips: Part 2. Release of hemicellulosic carbohydrates , 2007 .

[14]  D. Korkut,et al.  The effects of heat treatment on physical properties and surface roughness of red-bud maple (Acer trautvetteri Medw.) wood. , 2008, Bioresource technology.

[15]  E. Horn,et al.  WOOD-PLASTIC COMPOSITES USING THERMOMECHANICAL PULP MADE FROM OXALIC ACID-PRETREATED RED PINE CHIPS , 2008 .

[16]  Won-Joung Hwang,et al.  Combined effect of boron compounds and heat treatments on wood properties: Chemical and strength properties of wood , 2008 .

[17]  Shri Ramaswamy,et al.  Process modeling and analysis of pulp mill-based integrated biorefinery with hemicellulose pre-extraction for ethanol production: a comparative study. , 2010, Bioresource technology.

[18]  J. Y. Zhu,et al.  Woody biomass pretreatment for cellulosic ethanol production: Technology and energy consumption evaluation. , 2010, Bioresource technology.

[19]  Qiang Yang,et al.  Comparative study of SPORL and dilute-acid pretreatments of spruce for cellulosic ethanol production. , 2010, Bioresource technology.