Pollutant lead reveals the pre‐Hellenistic occupation and ancient growth of Alexandria, Egypt

It is generally accepted that Alexandria ad Aegyptum was founded ex nihilo in 331 BC by Alexander the Great, rapidly growing into one of antiquity's most opulent economic and intellectual centers. However, ancient texts by Strabo (17.1.6) and Pliny (NH 5.11.62) suggest the existence of a pre‐Hellenistic settlement named Rhakotis. This literary evidence has fuelled contentious scholarly debate for decades. Here we present new geochemical data from Alexandria's ancient bay sediments, elucidating unequivocal proof for pollutant lead (Pb) input into the harbor during the Egyptian Old Kingdom (2686–2181 BC). A second contamination peak is detected during the Iron Age (1000–800 BC), at the end of the prosperous Ramesses reigns. These findings evidence thriving pre‐Hellenistic settlements in Alexandria. During the Greek and Roman periods, we expound the largest Pb pollution ever encountered in ancient city sediments with Pb levels twice as high as those measured in contemporary industrialized estuaries.

[1]  G. Roux,et al.  Provenance of silver artefacts from burial 27 at sidon , 2004 .

[2]  C. Morhange,et al.  Geochemical evidences of early anthropogenic activity in harbour sediments from Sidon , 2003 .

[3]  M. Saad,et al.  Total dissolved and particulate lead in the Western Harbor of Alexandria, a Mediterranean basin under stress. , 2003, Marine pollution bulletin.

[4]  G. Fosse,et al.  The use of Pb isotopes to differentiate between contemporary and ancient sources of pollution in Greece , 2001 .

[5]  J. Stanley,et al.  Nile flooding sank two ancient cities , 2001, Nature.

[6]  Jean-Philippe Goiran Recherches géomorphologiques dans la région littorale d'Alexandrie en Egypte , 2001 .

[7]  C. Hunt,et al.  An imperial legacy? An exploration of the environmental impact of ancient metal mining and smelting in southern Jordan , 2000 .

[8]  I. Thornton,et al.  Heavy metal distribution in sediment profiles of the Pearl River estuary, South China , 2000 .

[9]  M. Depauw Alexandria, the Building Yard , 2000 .

[10]  Jean-Philippe Goiran,et al.  Évolution des rivages d'Alexandrie à l'Holocène récent, marge occidentale du delta du Nil, Egypte , 2000 .

[11]  M. Krom,et al.  The characterisation of Saharan dusts and Nile particulate matter in surface sediments from the Levantine basin using Sr isotopes , 1999 .

[12]  Gloor,et al.  History of atmospheric lead deposition since 12,370 (14)C yr BP from a peat bog, jura mountains, switzerland , 1998, Science.

[13]  Huan Feng,et al.  Distribution of Heavy Metal and PCB Contaminants in the Sediments of an Urban Estuary: The Hudson River , 1998 .

[14]  N. Gale,et al.  LEAD ISOTOPE DATA FROM THE ISOTRACE LABORATORY, OXFORD: ARCHAEOMETRY DATA BASE 4, ORES FROM CYPRUS , 1997 .

[15]  N. Gale,et al.  LEAD ISOTOPE DATA FROM THE ISOTRACE LABORATORY, OXFORD: ARCHAEOMETRY DATA BASE 3, ORES FROM THE AEGEAN, PART 1 , 1996 .

[16]  A. Cundy,et al.  Heavy metal and hydrocarbon pollution in recent sediments from southampton water, southern England: a geochemical and isotopic study. , 1995, Environmental science & technology.

[17]  C. Gerber,et al.  Geochemistry of Holocene Sediments from the Nile Delta , 1995 .

[18]  I. Renberg,et al.  Pre-industrial atmospheric lead contamination detected in Swedish lake sediments , 1994, Nature.

[19]  M. Stuiver,et al.  Modeling Atmospheric 14C Influences and 14C Ages of Marine Samples to 10,000 BC , 1993, Radiocarbon: An International Journal of Cosmogenic Isotope Research.

[20]  I. L. Barnes,et al.  STATISTICAL EVALUATION OF THE PRESENTLY ACCUMULATED LEAD ISOTOPE DATA FROM ANATOLIA AND SURROUNDING REGIONS , 1992 .

[21]  I. L. Barnes,et al.  Stable Lead Isotope Studies of Central Taurus Ore Sources and Related Artifacts from Eastern Mediterranean Chalcolithic and Bronze Age Sites , 1991 .

[22]  John D. Baines,et al.  Cultural Atlas of Ancient Egypt , 1991 .

[23]  B. E. Davies,et al.  Trace metal accumulations in soils on and around ancient settlements in Greece. , 1990 .

[24]  C. Lawrence,et al.  Lead and lead poisoning in antiquity , 1985, Medical History.

[25]  C. Patterson,et al.  Changes of lead and barium with time in California off-shore basin sediments , 1982 .

[26]  C. Patterson,et al.  Chronological variations in concentrations and isotopic compositions of anthropogenic atmospheric lead in sediments of a remote subalpine pond , 1980 .

[27]  J. Oates Early hydraulic civilization in Egypt, a study in cultural ecology: By Karl W. Butzer. 1976. Chicago and London: University of Chicago Press. xv + 134 pp. 4 tables, 14 figures. £1·90 , 1978 .

[28]  K. Butzer,et al.  Flood Plain Archeology. (Book Reviews: Prehistory of the Nile Valley; Early Hydraulic Civilization in Egypt. A Study in Cultural Ecology) , 1977 .

[29]  K. Butzer,et al.  Early hydraulic civilization in Egypt , 1976 .

[30]  T. J. Chow,et al.  Lead Pollution: Records in Southern California Coastal Sediments , 1973, Science.