论文信息 - Reaction of xenon difluoride with indene in aqueous 1,2-dimethoxyethane and tetrahydrofuran

Reaction of xenon difluoride with indene in aqueous 1,2-dimethoxyethane and tetrahydrofuran

Xenon difluoride (XeF2) reacts with indene in 1,2-dimethoxyethane–water (90:10) to give cis- and trans-2-fluoro-1-hydroxyindans. Our data indicate that neither xenon oxide (XeO) nor hydroxyxenon fluoride (HOXeF) is an intermediate in this reaction even though XeO is a suspected intermediate from aqueous hydrolysis of XeF2.

[1] R. Richardson,et al. Regioselective Chemistry of Methoxyxenon Fluoride. , 1986 .

[2] L. E. Andrews,et al. Substitution and addition reactions of organic substrates with hypofluorous acid , 1985 .

[3] G. L. Cantrell,et al. Further studies on the synthesis of a-fluoro carbonyl compounds [1] , 1985 .

[4] B. Gipe,et al. Radical additions of xenon difluoride to cis- and trans-1-phenylpropenes: comparison with trichloramine and iodobenzene dichloride , 1982 .

[5] R. Filler. Reactions of Organic Compounds with Xenon Fluorides , 1978 .

[6] R. Bonnett,et al. The hydroxylation of aromatic compounds with hypofluorous acid , 1977 .

[7] Y. Osawa,et al. Oxofluorination--A New Bident Reaction of Perchloryl Fluoride , 1963 .