Synthesis of homoleptic tris(organo-chelate)iridium(III) complexes by spontaneous ortho-metallation of electronrich olefin-derived N,N′-diarylcarbene ligands and the X-ray structures of fac-[6H3Me-p}3] and mer-6H3Me-p}2 {C6H4Me-p}Cl (a product of HCl cleavage) ☆