Rapid thermally assisted donor-acceptor catenation.

Charged donor-acceptor [2]catenanes containing cyclobis(paraquat-p-phenylene) as the ring component can be synthesised in yields of up to 88% in under one hour by heating two precursors in the presence of macrocyclic polyether templates in N,N-dimethylformamide at 80 °C.

[1]  G. Schill Catenanes, Rotaxanes, and Knots , 2013 .

[2]  William R. Dichtel,et al.  High hopes: can molecular electronics realise its potential? , 2012, Chemical Society reviews.

[3]  Yajie Zhang,et al.  Novel self-assembled dynamic [2]catenanes interlocked by the quadruple hydrogen bonding ureidopyrimidinone motif , 2012 .

[4]  Douglas C. Friedman,et al.  Positive cooperativity in the template-directed synthesis of monodisperse macromolecules. , 2012, Journal of the American Chemical Society.

[5]  J. F. Stoddart,et al.  Mechanically Interlocked Molecules Assembled by π–π Recognition , 2012 .

[6]  J. F. Stoddart,et al.  Great expectations: can artificial molecular machines deliver on their promise? , 2012, Chemical Society reviews.

[7]  P. Beer,et al.  A [2]catenane displaying pirouetting motion triggered by debenzylation and locked by chloride anion recognition. , 2011, Chemistry.

[8]  Tanya K. Ronson,et al.  M3L2 metallo-cryptophanes: [2]catenane and simple cages. , 2011, Chemical communications.

[9]  Youssry Y. Botros,et al.  Mechanical bond formation by radical templation. , 2010, Angewandte Chemie.

[10]  J. F. Stoddart,et al.  A catenated strut in a catenated metal-organic framework. , 2010, Angewandte Chemie.

[11]  G. Pantoș,et al.  A water soluble donor-acceptor [2]catenane that can switch between a coplanar and a Gemini-sign conformation. , 2010, Angewandte Chemie.

[12]  J. F. Stoddart,et al.  Enabling tetracationic cyclophane production by trading templates , 2010 .

[13]  J. F. Stoddart,et al.  Polycatenation under thermodynamic control. , 2010, Angewandte Chemie.

[14]  J. F. Stoddart,et al.  Improved synthesis of 1,5-dinaphtho[38]crown-10 , 2010 .

[15]  J. F. Stoddart,et al.  Thermodynamic forecasting of mechanically interlocked switches. , 2009, Organic & biomolecular chemistry.

[16]  J. Sanders,et al.  Dynamic combinatorial synthesis of a catenane based on donor–acceptor interactions in water , 2009, Proceedings of the National Academy of Sciences.

[17]  J. F. Stoddart,et al.  The chemistry of the mechanical bond. , 2009, Chemical Society reviews.

[18]  J. F. Stoddart,et al.  The master of chemical topology. , 2009, Chemical Society reviews.

[19]  J. Fraser Stoddart,et al.  Big and little Meccano , 2008 .

[20]  J. F. Stoddart,et al.  Dynamic donor–acceptor [2]catenanes , 2007, Proceedings of the National Academy of Sciences.

[21]  Francesco Zerbetto,et al.  Synthetic molecular motors and mechanical machines. , 2007, Angewandte Chemie.

[22]  Bonnie A. Sheriff,et al.  A 160-kilobit molecular electronic memory patterned at 1011 bits per square centimetre , 2007, Nature.

[23]  G. Ercolani,et al.  Template effects in the formation of [2]pseudo-rotaxanes containing diazapyrenium units. , 2007, The Journal of organic chemistry.

[24]  P. Beer,et al.  Anion directed synthesis of a hydrogensulfate selective luminescent rotaxane. , 2005, Chemical communications.

[25]  M. Blanco,et al.  Transition‐Metal‐Templated Synthesis of Rotaxanes , 2003 .

[26]  G. Ercolani,et al.  Template effects and kinetic selection in the self-assembly of crown ether cyclobis(paraquat-p-phenylene) , 2000, Chemistry.

[27]  T. Swager,et al.  A Conducting Poly(cyclophane) and Its Poly([2]-catenane) , 2000 .

[28]  J. F. Stoddart,et al.  A [2]Catenane-Based Solid State Electronically Reconfigurable Switch , 2000 .

[29]  G. Ercolani,et al.  Spectacular Rate Enhancement in the Self-Assembly of a [2]Catenane , 1998 .

[30]  Vincenzo Balzani,et al.  A Chemically and Electrochemically Switchable [2]Catenane Incorporating a Tetrathiafulvalene Unit. , 1998, Angewandte Chemie.

[31]  David A. Leigh,et al.  Facile Synthesis and Solid-State Structure of a Benzylic Amide [2]Catenane† , 1995 .

[32]  M. Fujita,et al.  Quantitative self-assembly of a [2]catenane from two preformed molecular rings , 1994, Nature.

[33]  F. Vögtle,et al.  Multiring Catenanes with a Macrobicyclic Core , 1993 .

[34]  Harry L. Anderson,et al.  Expanding roles for templates in synthesis , 1993 .

[35]  F. Vögtle,et al.  One‐Step Synthesis of a Fourfold Functionalized Catenane , 1992 .

[36]  C. Hunter Synthesis and structure elucidation of a new [2]-catenane , 1992 .

[37]  Akira Harada,et al.  The molecular necklace: a rotaxane containing many threaded α-cyclodextrins , 1992, Nature.

[38]  D. H. Busch,et al.  Molecular organization, portal to supramolecular chemistry: Structural analysis of the factors associated with molecular organization in coordination and inclusion chemistry, including the coordination template effect , 1990 .

[39]  David J. Williams,et al.  A [2] Catenane Made to Order , 1989 .

[40]  David J. Williams,et al.  Cyclobis(paraquat‐p‐phenylene). A Tetracationic Multipurpose Receptor , 1988 .

[41]  David J. Williams,et al.  Isostructural, Alternately‐Charged Receptor Stacks. The Inclusion Complexes of Hydroquinone and Catechol Dimethyl Ethers with Cyclobis(paraquat‐p‐phenylene) , 1988 .

[42]  I. Harrison Preparation of rotaxanes by the statistical method , 1974 .

[43]  R. Wolovsky Interlocked ring systems obtained by the metathesis reaction of cyclododecene. Mass spectral evidence , 1970 .

[44]  E. Wasserman,et al.  THE PREPARATION OF INTERLOCKING RINGS: A CATENANE1 , 1960 .

[45]  J. F. Stoddart,et al.  The mechanical bond: a work of art. , 2012, Topics in current chemistry.

[46]  Douglas C. Friedman,et al.  Radically enhanced molecular recognition. , 2010, Nature chemistry.

[47]  J. F. Stoddart,et al.  A chemically and electrochemically switchable molecular shuttle , 1994, Nature.

[48]  David J. Williams,et al.  The complexation of tetrathiafulvalene by cyclobis(Paraquat-p-phenylene) , 1991 .

[49]  Jean-Pierre Sauvage,et al.  Une nouvelle famille de molecules : les metallo-catenanes , 1983 .