A practical application of wavelet moment method on the quantitative analysis of Shuanghuanglian oral liquid based on three-dimensional fingerprint spectra.

The overlapping and shifts of peaks and noise signals appear mostly in high performance liquid chromatography (HPLC) experiments. A practical application of wavelet moment method on the quantitative analysis of the main active components in Shuanghuanglian oral liquid samples was presented based on the determination of HPLC coupled with photodiode array detector (PAD). The wavelet moments were calculated from the divided regions in the grayscale images of three-dimensional (3D) HPLC-PAD fingerprint spectra according to the target peak(s), and then used to establish linear models, respectively. The correlation coefficients (R) were more than 0.9980 within the test ranges. The intra- and inter-day variations were less than 1.13% and 1.10%, respectively. The recovery ranged from 96.2% to 102.7%. The overall LODs and LOQs were less than 0.2 μg/mL and 0.7 μg/mL, respectively. Our study indicated that wavelet moment approach could defuse the overlapping and shifts of peaks and noise signals in the chromatographic determination owing to its multi-resolution and inherently invariance properties. Thus the analytical time was shortened, and the obtained results were reliable and accurate.

[1]  H. Zhai,et al.  The application of digital image recognition to the analysis of two-dimensional fingerprints. , 2010, Analytica chimica acta.

[2]  Yi-Zeng Liang,et al.  Peak alignment using wavelet pattern matching and differential evolution. , 2011, Talanta.

[3]  H. Zhai,et al.  Simultaneous Quantitative Analysis of Three Compounds Using Three-Dimensional Fluorescence Spectra Based on Digital Image Techniques , 2012, Journal of Fluorescence.

[4]  Andrea D. Magrì,et al.  Fast analysis of 4 phenolic acids in olive oil by HPLC-DAD and chemometrics , 2011 .

[5]  Richard G. Brereton,et al.  Two-way, unfolded three-way and three-mode partial least squares calibration of diode array HPLC chromatograms for the quantitation of low-level pharmaceutical impurities , 1999 .

[6]  Marcelo M Sena,et al.  N-way PLS applied to simultaneous spectrophotometric determination of acetylsalicylic acid, paracetamol and caffeine. , 2004, Journal of pharmaceutical and biomedical analysis.

[7]  J. Lu,et al.  Rapid method for simultaneous determination of flavonoid, saponins and polyacetylenes in folium ginseng and radix ginseng by pressurized liquid extraction and high-performance liquid chromatography coupled with diode array detection and mass spectrometry. , 2009, Journal of chromatography. A.

[8]  Mingyu Lu,et al.  A robust digital audio watermarking scheme using wavelet moment invariance , 2011, J. Syst. Softw..

[9]  Wei Guan,et al.  Aircraft recognition in infrared image using wavelet moment invariants , 2009, Image Vis. Comput..

[10]  H. Zhai,et al.  A simple approach to quantitative analysis using three-dimensional spectra based on selected Zernike moments. , 2013, The Analyst.

[11]  Xiao Yun Zhang,et al.  An application of wavelet moments to the similarity analysis of three-dimensional fingerprint spectra obtained by high-performance liquid chromatography coupled with diode array detector. , 2014, Food chemistry.

[12]  Runhe Shi,et al.  Ensemble and enhanced PM10 concentration forecast model based on stepwise regression and wavelet analysis , 2013 .

[13]  Shizhong Chen,et al.  Simultaneous qualitative and quantitative analysis of phenolic acids and flavonoids for the quality control of Apocynum venetum L. leaves by HPLC-DAD-ESI-IT-TOF-MS and HPLC-DAD. , 2013, Journal of pharmaceutical and biomedical analysis.

[14]  Marc De Loose,et al.  Trends in quality in the analytical laboratory. II. Analytical method validation and quality assurance , 2004 .

[15]  Hai-Long Wu,et al.  Quantitative analysis of triazine herbicides in environmental samples by using high performance liquid chromatography and diode array detection combined with second-order calibration based on an alternating penalty trilinear decomposition algorithm. , 2010, Analytica chimica acta.

[16]  O. Gennari,et al.  A Simple HPLC-DAD Method for the Analysis of Melamine in Protein Supplements: Validation Using the Accuracy Profiles , 2013 .

[17]  Hai-Long Wu,et al.  Fast HPLC-DAD quantification of nine polyphenols in honey by using second-order calibration method based on trilinear decomposition algorithm. , 2013, Food chemistry.

[18]  L. Rodriguez-Saona,et al.  Rapid analysis of sugars in fruit juices by FT-NIR spectroscopy. , 2001, Carbohydrate research.

[19]  J. Ruan,et al.  Simultaneous determination of 10 active components in traditional Chinese medicine "YIGONG" capsule by RP-HPLC-DAD. , 2008, Journal of pharmaceutical and biomedical analysis.

[20]  R. Yu,et al.  Simultaneous determination of pre-emergence herbicides in environmental samples using HPLC-DAD combined with second-order calibration based on self-weighted alternating trilinear decomposition algorithm , 2012 .

[21]  Yongjiang Wu,et al.  Quantitative analysis combined with chromatographic fingerprint for comprehensive evaluation of Danhong injection using HPLC-DAD. , 2013, Journal of pharmaceutical and biomedical analysis.

[22]  Esmail Babolian,et al.  Wavelet moment method for solving Fredholm integral equations of the first kind , 2007, Appl. Math. Comput..

[23]  Y. Wang,et al.  Simultaneous determination of nine ginsenosides in functional foods by high performance liquid chromatography with diode array detector detection , 2010 .

[24]  Xiangyang Wang,et al.  Invariant image watermarking using multi-scale Harris detector and wavelet moments , 2010, Comput. Electr. Eng..

[25]  Hai-Long Wu,et al.  Fast analysis of synthetic antioxidants in edible vegetable oil using trilinear component modeling of liquid chromatography-diode array detection data. , 2012, Journal of chromatography. A.

[26]  Dinggang Shen,et al.  Discriminative wavelet shape descriptors for recognition of 2-D patterns , 1999, Pattern Recognit..