Rubidium hexafluoridoiridate(IV)
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Rb2[IrF6] possesses a framework structure constructed from Rb+ cations and [IrF6]2− complex anions. The cation is 12-coordinated by F atoms, forming a slightly distorted anticuboctahedron; the anion has the shape of an almost ideal octahedron. Rb, Ir and F atoms are located on special positions of 3m, \overline{3}m and m symmetry, respectively.
[1] B. Müller,et al. Einkristalluntersuchungen an LiMF6 (M = Rh, Ir), Li2RhF6 und K2IrF6 , 2002 .