Rapid electrochemical screening methods for food safety and quality

This paper presents some examples of rapid, simple and cost effective screening methods that can be realized by the use of Screen Printed Electrodes (SPEs) coupled with portable and cheap instrumentation, for the monitoring of food safety and quality. When necessary, these SPEs have been modified with nanomaterials in order to improve their performance and then their analytic characteristics. Arsenic detection, for example, has been obtained with SPEs modified with of a composite of nanostructured Carbon Black and Au nanoparticles, while for the pesticide detection the SPEs were modified with Prussian Blue nanoparticles in addition to the enzyme Butyrylcholinesterase. In the case of immunosensors, a high sensitivity has been obtained making the entire immunological chain to happen on the surface of magnetic beads (MBs), finally collected on the surface of screen printed arrays with the aid of magnets located just under the working electrodes. Application to real samples demonstrates the effectiveness of such approaches.

[1]  Y. Long,et al.  Recent developments and applications of screen-printed electrodes in environmental assays--a review. , 2012, Analytica chimica acta.

[2]  Kazuo T. Suzuki,et al.  Arsenic round the world: a review. , 2002, Talanta.

[3]  Weiying Zhang,et al.  Nanomaterial-based biosensors for environmental and biological monitoring of organophosphorus pesticides and nerve agents , 2014 .

[4]  C. Bergh,et al.  Simultaneous selective detection of organophosphate and phthalate esters using gas chromatography with positive ion chemical ionization tandem mass spectrometry and its application to indoor air and dust. , 2010, Rapid communications in mass spectrometry : RCM.

[5]  G. Palleschi,et al.  Comparison of PCR, Electrochemical Enzyme-Linked Immunosorbent Assays, and the Standard Culture Method for Detecting Salmonella in Meat Products , 2004, Applied and Environmental Microbiology.

[6]  Danila Moscone,et al.  Hg2+ detection by measuring thiol groups with a highly sensitive screen-printed electrode modified with a nanostructured carbon black film , 2011 .

[7]  Yogeswaran Umasankar,et al.  Nanomaterials - Acetylcholinesterase Enzyme Matrices for Organophosphorus Pesticides Electrochemical Sensors: A Review , 2009, Sensors.

[8]  I. Cacciotti,et al.  Carbon black assisted tailoring of Prussian Blue nanoparticles to tune sensitivity and detection limit towards H2O2 by using screen-printed electrode , 2014 .

[9]  Jean-Louis Marty,et al.  Twenty years research in cholinesterase biosensors: from basic research to practical applications. , 2006, Biomolecular engineering.

[10]  Y. Kan,et al.  Palytoxin analogs from the dinoflagellate Ostreopsis siamensis. , 1995 .

[11]  Jonathan P. Metters,et al.  New directions in screen printed electroanalytical sensors: an overview of recent developments. , 2011, The Analyst.

[12]  Sara V. Flanagan,et al.  Arsenic in tube well water in Bangladesh: health and economic impacts and implications for arsenic mitigation. , 2012, Bulletin of the World Health Organization.

[13]  Miroslav Pohanka,et al.  Progress of biosensors based on cholinesterase inhibition. , 2009, Current medicinal chemistry.

[14]  Marion Koopmans,et al.  Foodborne viruses: an emerging problem , 2003, International Journal of Food Microbiology.

[15]  Sarit S. Agasti,et al.  Gold nanoparticles in chemical and biological sensing. , 2012, Chemical reviews.

[16]  J. Usall,et al.  Biopreservative methods to control the growth of foodborne pathogens on fresh-cut lettuce. , 2015, International journal of food microbiology.

[17]  G. Palleschi,et al.  Automatable Flow System for Paraoxon Detection with an Embedded Screen-Printed Electrode Tailored with Butyrylcholinesterase and Prussian Blue Nanoparticles , 2015 .

[18]  Danila Moscone,et al.  Carbon Black‐Modified Screen‐Printed Electrodes as Electroanalytical Tools , 2012 .

[19]  G. Palleschi,et al.  Development and application of an electrochemical plate coupled with immunomagnetic beads (ELIME) array for Salmonella enterica detection in meat samples. , 2009, Journal of agricultural and food chemistry.

[20]  A. Goldman,et al.  Atomic structure of acetylcholinesterase from Torpedo californica: a prototypic acetylcholine-binding protein , 1991, Science.

[21]  Danila Moscone,et al.  Biosensors based on cholinesterase inhibition for insecticides, nerve agents and aflatoxin B1 detection (review) , 2010 .

[22]  G. Palleschi,et al.  Stripping Analysis of As(III) by Means of Screen‐Printed Electrodes Modified with Gold Nanoparticles and Carbon Black Nanocomposite , 2014 .

[23]  G. Palleschi,et al.  Development of a haemolytic–enzymatic assay with mediated amperometric detection for palytoxin analysis: application to mussels , 2014, Analytical and Bioanalytical Chemistry.

[24]  M. A. Alonso-Lomillo,et al.  Recent developments in the field of screen-printed electrodes and their related applications. , 2007, Talanta.

[25]  Richard G Compton,et al.  Analytical methods for inorganic arsenic in water: a review. , 2004, Talanta.

[26]  F. Ventura,et al.  GC-MS quantification of organophosphorous pesticides extracted from XAD-2 sorbent tube and foam patch matrices , 2012 .

[27]  Kamil Kuca,et al.  Treatment of organophosphate intoxication using cholinesterase reactivators: facts and fiction. , 2007, Mini reviews in medicinal chemistry.

[28]  David A. Schultz,et al.  Plasmon resonant particles for biological detection. , 2003, Current opinion in biotechnology.

[29]  Hi Isoken Biofilm formation of Salmonella species isolated from fresh cabbage and spinach , 2015 .