Direct photoetching of polymers using radiation of high energy density from a table-top extreme ultraviolet plasma source

In order to perform material interaction studies with intense extreme ultraviolet (EUV) radiation, a Schwarzschild mirror objective coated with Mo/Si multilayers was adapted to a compact laser-driven EUV plasma source utilizing a solid Au target. By 10× demagnified imaging of the plasma a maximum pulse energy density of ∼0.73 J/cm2 at a wavelength of 13.5 nm can be achieved in the image plane of the objective at a pulse duration of 8.8 ns. In this paper we present EUV photoetching rates measured for polymethyl methacrylate, polycarbonate, and polytetrafluoroethylene at various fluence levels. A linear dependence between etch depth and applied EUV pulse number could be observed without the necessity for any incubation pulses. By evaluating the slope of these data, etch rates were determined, revealing also a linear behavior for low fluences. A threshold energy density could not be observed. The slope of the linear etch regime as well as deviations from the linear trend at higher energy densities are discus...

[1]  S. Hooker,et al.  Laser ablation of polymeric materials at 157 nm , 1995 .

[2]  C. Peth,et al.  Characterization of gas targets for laser produced extreme ultraviolet plasmas with a Hartmann-Shack sensor , 2004 .

[3]  Donald W. Phillion,et al.  Soft x‐ray production from laser produced plasmas for lithography applications , 1993 .

[4]  Thomas Lippert,et al.  Chemical and spectroscopic aspects of polymer ablation: special features and novel directions. , 2003, Chemical reviews.

[5]  Armin Bayer,et al.  Direct photo-etching of poly"methyl methacrylate… using focused extreme ultraviolet radiation from a table-top laser-induced plasma source , 2007 .

[6]  Libor Juha,et al.  Ablation of organic polymers by 46.9-nm-laser radiation , 2005 .

[7]  Masanobu Ikeda,et al.  High-Rate Anisotropic Ablation and Deposition of Polytetrafluoroethylene Using Synchrotron Radiation Process , 1995 .

[8]  Sebastian Kranzusch,et al.  Spectral characterization of EUV radiation emitted from a laser-irradiated gas puff target , 2001 .

[9]  Takanori Katoh,et al.  Synchrotron Radiation Micromachining of Polymers to Produce High-Aspect-Ratio Microparts , 1996 .

[10]  J Ihlemann,et al.  Excimer laser micro machining: fabrication and applications of dielectric masks , 2000 .

[11]  D. Wesner,et al.  Processing of polymer surfaces by laser radiation , 1995 .

[12]  M. Bergh Interaction of Ultrashort X-ray Pulses with Material , 2007 .

[13]  Regina Soufli,et al.  Zirconium and niobium transmission data at wavelengths from 11-16 nm and 200-1200 nm , 2004, SPIE Optics + Photonics.

[14]  B. Rus,et al.  XUV-laser induced ablation of PMMA with nano-, pico-, and femtosecond pulses , 2005 .

[15]  Torsten Feigl,et al.  Formation and direct writing of color centers in LiF using a laser-induced extreme ultraviolet plasma in combination with a Schwarzschild objective , 2005 .

[16]  L. Laude,et al.  The ablation of polymers under excimer laser irradiation: the physics of the process and the polymer structure , 2001 .

[17]  Hiroyuki Niino,et al.  Direct micromachining of quartz glass plates using pulsed laser plasma soft x-rays , 2005 .

[18]  R. London,et al.  Characteristics of focused soft X-ray free-electron laser beam determined by ablation of organic molecular solids. , 2007, Optics express.

[19]  Tomas Mocek,et al.  Focusing a multimillijoule soft x-ray laser at 21 nm , 2006 .

[20]  Ken'ichiro Tanaka,et al.  Inner‐shell excitation and site specific fragmentation of poly(methylmethacrylate) thin film , 1994 .

[21]  Sylvain Lazare,et al.  Modification of polymer surfaces by far-ultraviolet radiation of low and high (laser) intensities , 1985 .

[22]  Hironari Yamada,et al.  High aspect ratio micromachining Teflon by direct exposure to synchrotron radiation , 1995 .

[23]  R. Srinivasan,et al.  Ablation of polymethyl methacrylate films by pulsed (ns) ultraviolet and infrared (9.17 μm) lasers: A comparative study by ultrafast imaging , 1993 .

[24]  H. Ikeura,et al.  Photon stimulated ion desorption studies using pulsed synchrotron radiation , 1995 .

[25]  T. Lippert Interaction of Photons with Polymers: From Surface Modification to Ablation , 2005 .

[26]  Bernd Schäfer,et al.  Investigation of the propagation characteristics of excimer lasers using a Hartmann–Shack sensor , 2000 .

[27]  Libor Juha,et al.  Strong temperature effect on X-ray photo-etching of polytetrafluoroethylene using a 10 Hz laser-plasma radiation source based on a gas puff target , 2006 .

[28]  R. H. Stulen,et al.  Diffraction-limited soft-x-ray projection imaging using a laser plasma source. , 1991, Optics letters.

[29]  M. Stuke,et al.  PHOTOFRAGMENTATION PATHWAYS OF A PMMA MODEL-COMPOUND UNDER UV EXCIMER LASER ABLATION CONDITIONS , 1990 .

[30]  Erik H. Anderson,et al.  Patterning a 50‐nm period grating using soft x‐ray spatial frequency multiplication , 1994 .

[31]  Armin Bayer,et al.  Direct photo-etching of PMMA by focused EUV radiation from a compact laser plasma source , 2008, SPIE LASE.

[32]  B. Schäfer,et al.  Determination of beam parameters and coherence properties of laser radiation by use of an extended Hartmann-Shack wave-front sensor. , 2002, Applied optics.

[33]  Sebastian Kranzusch,et al.  Spatial characterization of extreme ultraviolet plasmas generated by laser excitation of xenon gas targets , 2003 .