Cosolvent effects on the structure and thermoresponse of a polymer brush: PNIPAM in DMSO–water mixtures

Structural characterisation of thermoresponsive polymer brushes in binary DMSO–water mixtures reveals both LCST and UCST behaviour.

[1]  Stuart W. Prescott,et al.  From Hofmeister to hydrotrope: Effect of anion hydrocarbon chain length on a polymer brush. , 2022, Journal of colloid and interface science.

[2]  Stuart W. Prescott,et al.  refellips: A Python package for the analysis of variable angle spectroscopic ellipsometry data , 2022, SoftwareX.

[3]  Timothy J. Murdoch,et al.  Geometrical Confinement Modulates the Thermoresponse of a Poly(N-isopropylacrylamide) Brush , 2021 .

[4]  Stuart W. Prescott,et al.  Competitive specific ion effects in mixed salt solutions on a thermoresponsive polymer brush. , 2020, Journal of colloid and interface science.

[5]  E. Wanless,et al.  Effect of ionic strength and salt identity on poly(N-isopropylacrylamide) brush modified colloidal silica particles. , 2018, Journal of colloid and interface science.

[6]  Timothy J. Murdoch,et al.  Specific Anion Effects on the Internal Structure of a Poly(N-isopropylacrylamide) Brush , 2016 .

[7]  Martin Kröger,et al.  Poly(N-isopropylacrylamide) Phase Diagrams: Fifty Years of Research. , 2015, Angewandte Chemie.

[8]  Johannes Kiefer,et al.  Revisiting the Aqueous Solutions of Dimethyl Sulfoxide by Spectroscopy in the Mid- and Near-Infrared: Experiments and Car-Parrinello Simulations. , 2015, The journal of physical chemistry. B.

[9]  Z. Klemenkova,et al.  Elucidation of the Water–DMSO Mixing Process Based on an IR Study , 2015, Journal of Solution Chemistry.

[10]  K. Kremer,et al.  Polymer collapse in miscible good solvents is a generic phenomenon driven by preferential adsorption , 2014, Nature Communications.

[11]  V. Trappe,et al.  Hydrophobic hydration of poly-N-isopropyl acrylamide: a matter of the mean energetic state of water , 2014, Scientific Reports.

[12]  Guangzhao Zhang,et al.  Specific anion effect in water-nonaqueous solvent mixtures: interplay of the interactions between anion, solvent, and polymer. , 2013, The journal of physical chemistry. B.

[13]  B. Sumerlin,et al.  New directions in thermoresponsive polymers. , 2013, Chemical Society reviews.

[14]  N. Spencer,et al.  Impact of solvation on equilibrium conformation of polymer brushes in solvent mixtures , 2013 .

[15]  B. Bhushan,et al.  Smart polymer brushes and their emerging applications , 2012 .

[16]  Guangzhao Zhang,et al.  Insights into ion specificity in water-methanol mixtures via the reentrant behavior of polymer. , 2012, Langmuir : the ACS journal of surfaces and colloids.

[17]  M. Ward,et al.  Thermoresponsive Polymers for Biomedical Applications , 2011 .

[18]  F. Klose,et al.  The multipurpose time-of-flight neutron reflectometer “Platypus” at Australia's OPAL reactor , 2011 .

[19]  M. Lanagan,et al.  Dielectric Relaxation in Dimethyl Sulfoxide/Water Mixtures , 2010 .

[20]  Naoyuki Ishida,et al.  Effect of grafting density on phase transition behavior for poly(N-isopropylacryamide) brushes in aqueous solutions studied by AFM and QCM-D , 2010 .

[21]  A. Leipertz,et al.  Concentration-dependent hydrogen-bonding effects on the dimethyl sulfoxide vibrational structure in the presence of water, methanol, and ethanol. , 2010, Chemphyschem : a European journal of chemical physics and physical chemistry.

[22]  M. C. Stuart,et al.  Emerging applications of stimuli-responsive polymer materials. , 2010, Nature materials.

[23]  B. Nysten,et al.  Surface and bulk collapse transitions of thermoresponsive polymer brushes. , 2010, Langmuir : the ACS journal of surfaces and colloids.

[24]  Qiang Zhang,et al.  Polarizable force field for water-dimethyl sulfoxide systems: II properties of mixtures by molecular dynamics simulations , 2009 .

[25]  Xiao‐Qing Yang,et al.  Dielectric Properties of Binary Solvent Mixtures of Dimethyl Sulfoxide with Water , 2009, International journal of molecular sciences.

[26]  A. Soper,et al.  Investigations on the structure of dimethyl sulfoxide and acetone in aqueous solution. , 2007, The Journal of chemical physics.

[27]  Hideo Yamauchi,et al.  LCST and UCST behavior of poly(N-isopropylacrylamide) in DMSO/water mixed solvents studied by IR and micro-Raman spectroscopy. , 2007, The journal of physical chemistry. B.

[28]  Alain M. Jonas,et al.  Thermo-responsive polymer brushes with tunable collapse temperatures in the physiological range , 2007 .

[29]  J. Owrutsky,et al.  Vibrational spectroscopy and dynamics of azide ion in ionic liquid and dimethyl sulfoxide water mixtures. , 2007, The journal of physical chemistry. B.

[30]  Jean-François Lutz,et al.  Point by point comparison of two thermosensitive polymers exhibiting a similar LCST: is the age of poly(NIPAM) over? , 2006, Journal of the American Chemical Society.

[31]  Guangzhao Zhang,et al.  Reentrant behavior of poly(N-isopropylacrylamide) brushes in water-methanol mixtures investigated with a quartz crystal microbalance. , 2005, Langmuir : the ACS journal of surfaces and colloids.

[32]  J. Ávalos,et al.  Transport properties of dimethyl sulfoxide aqueous solutions , 2003 .

[33]  Barbara Kirchner,et al.  The secret of dimethyl sulfoxide-water mixtures. A quantum chemical study of 1DMSO-nwater clusters. , 2002, Journal of the American Chemical Society.

[34]  C. Díaz,et al.  Characterization of binary solvent mixtures of DMSO with water and other cosolvents. , 2001, The Journal of organic chemistry.

[35]  M. Bellissent-Funel,et al.  Single-particle dynamics in dimethyl–sulfoxide/water eutectic mixture by neutron scattering , 2000 .

[36]  M. Skaf,et al.  Molecular association between water and dimethyl sulfoxide in solution: A molecular dynamics simulation study , 1999 .

[37]  R. Ornstein,et al.  A Molecular Dynamics and Quantum Mechanics Analysis of the Effect of DMSO on Enzyme Structure and Dynamics: Subtilisin , 1996 .

[38]  A. Soper,et al.  Orientation of Water Molecules around Small Polar and Nonpolar Groups in Solution: A Neutron Diffraction and Computer Simulation Study , 1996 .

[39]  A. Soper,et al.  A neutron diffraction study of dimethyl sulphoxide–water mixtures , 1992 .

[40]  Toyoichi Tanaka,et al.  Reentrant phase transition in acrylamide-derivative copolymer gels , 1984 .

[41]  Surjit Singh,et al.  Self-association of dimethyl sulphoxide and its dipolar interactions with water: Raman spectral studies , 1984 .

[42]  Alessandro Bertoluzza,et al.  Raman and infrared study on the effects of dimethylsulphoxide (DMSO) on water structure , 1979 .

[43]  D. Rasmussen,et al.  Phase Diagram for the System Water–Dimethylsulphoxide , 1968, Nature.

[44]  J. Cowie,et al.  ASSOCIATION IN THE BINARY LIQUID SYSTEM DIMETHYL SULPHOXIDE – WATER , 1961 .

[45]  J. Lovelock,et al.  Prevention of Freezing Damage to Living Cells by Dimethyl Sulphoxide , 1959, Nature.