Acidic attack of cement based materials under the common action of high, ambient temperature and pressure

Abstract The cement materials in geothermal bore holes used to be exposed to the acidic attack under the common action of ambient high, temperatures and pressure. As it is known the waters in the deep geothermal wells are usually very aggressive to the applied cementing materials. Acidic aggressivity used to be a dominating type. Therefore, in the interest of the ensuring of life service of the cementing material it should be high acidic resistant. But it is a crucial problem due to the fact that practically all-protective measurements like e.g. the choice of the cement, increased density of material and others are weak and insufficient. One presumption of the ensuring of acidic resistance of cementing material is the correct evaluation of cooperating factors conditioning its acidic resistance and the factors of the aggressivity of environment. Both are of complex character depending on several conditioning factors. This complexness, as a rule, is not taken into consideration. However, such an evaluation current in the practice is entirely unsatisfied and incorrect. Therefore, further factors should be taken into consideration. These are the subject of the presented paper showing also the complexness of the point at issue.

[1]  T. Sugama,et al.  Carbonation of calcium phosphate cements after long-term exposure to Na2CO3-laden water at 250°C , 1993 .

[2]  W H Harrison,et al.  CHEMICAL RESISTANCE OF CONCRETE , 1977 .

[3]  F. Lea The chemistry of cement and concrete , 1970 .

[4]  V. Zivica Experimental principles in the research of chemical resistance of cement based materials , 1998 .

[5]  D. Roy,et al.  The effect of superplasticizer molecular weight on its adsorption on, and dispersion of, cement , 1988 .

[6]  K. Luke Phase studies of pozzolanic stabilized calcium silicate hydrates at 180 °C , 2004 .

[7]  Chi Sun Poon,et al.  Experimental study of micro/macro crack development and stress-strain relations of cement-based composite materials at elevated temperatures , 2004 .

[8]  P. K. Mehta Studies on chemical resistance of low water/cement ratio concretes , 1985 .

[9]  V. Zivica,et al.  ACIDIC ATTACK OF CEMENT BASED MATERIALS—A REVIEW. PART 1. PRINCIPLE OF ACIDIC ATTACK , 2001 .

[10]  C. D. Pomeroy Rehabilitation of concrete structures , 1993 .

[11]  N. R. Short,et al.  Preliminary investigations into the supercritical carbonation of cement pastes , 2001 .

[12]  N. Robins,et al.  Borehole cements and the downhole environment—a review , 1986, Quarterly Journal of Engineering Geology.

[13]  D. D. Onan,et al.  Effects of Supercritical Carbon Dioxide on Well Cements , 1984 .

[14]  L. Hammett,et al.  Physical organic chemistry , 1940 .

[15]  L. E. Kukacka,et al.  Carbonation of geothermal grouts — Part 1: CO2 attack at 150°C , 1986 .

[16]  J. J. Beaudoin,et al.  Control of slump loss in superplasticized concrete , 1989 .

[17]  N. I. Fattuhi,et al.  The performance of cement paste and concrete subjected to sulphuric acid attack , 1988 .

[18]  B. Kutchko,et al.  Degradation of well cement by CO2 under geologic sequestration conditions. , 2007, Environmental science & technology.

[19]  L. D. Ceukelaire The effects of hydrochloric acid on mortar , 1992 .

[20]  P. Gegout,et al.  Effect of pH on the durability of cement pastes , 1992 .

[21]  A. Prebus,et al.  Crystal Chemistry of Hydrous Calcium Silicates: III, Morphology and Other Properties of Tobermorite and Related Phases , 1958 .

[22]  I. Richardson The calcium silicate hydrates , 2008 .

[23]  Nediljka Gaurina-Međimurec,et al.  CEMENT SLURRIES FOR GEOTHERMAL WELLS CEMENTING , 1994 .

[24]  J. Schulze Influence of water-cement ratio and cement content on the properties of polymer-modified mortars , 1999 .

[25]  G. Rao Role of water–binder ratio on the strength development in mortars incorporated with silica fume , 2001 .

[26]  V. Zivica,et al.  Acidic attack of cement-based materials—a review Part 2. Factors of rate of acidic attack and protective measures , 2002 .

[27]  B. Kutchko,et al.  CO2 reaction with hydrated class H well cement under geologic sequestration conditions: effects of flyash admixtures. , 2009, Environmental Science and Technology.

[28]  E.S.K. Fekpe Asphaltic concrete overlays on surface-treated pavements with lateritic gravel bases , 1992 .

[29]  J. Skalny,et al.  Pore structure and properties of materials: Proceedings of the RILEM-UIPAC International Symposium, Prague, September 1973. Edited by S. Modry. Preliminary Report - 2 Volumes (1973), Final Report - 4 Volumes (1974). Academia Prague. 2900 Pages; numerous illustrations, plates and tables , 1974 .

[30]  A. Jupe,et al.  Class H Cement Hydration at 180°C and High Pressure in the Presence of Added Silica , 2008 .

[31]  Omar Saeed Baghabra Al-Amoudi Studies on the evaluation of permeability and corrosion resisting characteristics of Portland pozzolan concrete , 1985 .

[32]  C. Hall,et al.  Synthesis of cement based CaO–Al2O3–SiO2–H2O (CASH) hydroceramics at 200 and 250 °C: Ex-situ and in-situ diffraction , 2007 .

[33]  H. Grube,et al.  DURABILITY OF CONCRETE STRUCTURES IN ACIDIC WATER , 1989 .

[34]  F. S. Rostásy,et al.  Changes of pore structure of cement mortars due to temperature , 1980 .

[35]  B. P. Hughes,et al.  Effect of acid attack on concrete with different admixtures or protective coatings , 1983 .

[36]  S. Türkel,et al.  Influence of various acids on the physico-mechanical properties of pozzolanic cement mortars , 2007 .