Evolving simple-to-apply models for estimating thermal conductivity of supercritical CO2

ABSTRACT Today, due to extensive applications of supercritical fluids technology in various chemical engineering process and industrial fields, predicting thermal conductivity of supercritical carbon dioxide is vital. In this research, two simple-to-apply models have been developed to estimate thermal conductivity of supercritical CO2 as a function of temperature, pressure and density over broad ranges. This research presents a predictive tool based on LSSVM to predict thermal conductivity of supercritical CO2. Genetic algorithm is employed to determine hyper-variables which are included in the LSSVM approach. In this regard, a set of accessible data containing 745 data points has been gathered from the previous published papers. Estimations are found to be in excellent agreement with reported data. Moreover, statistical analyses have been applied to evaluate the performance of two models. The obtained values of Mean Squared Error and R-Square were 7.415866, 0.9935 and 0.046527, 1.00 for the correlation and LSSVM model, respectively. The developed tools can be of immense practical value for chemical engineers to have a quick check of thermal conductivity of supercritical CO2 at an extensive range of conditions.

[1]  Mohammad Ali Ahmadi,et al.  Corrigendum to “Neural network based swarm concept for prediction asphaltene precipitation due to natural depletion” [J. Pet. Sci. Eng. 98–99 (2012) 40–49] , 2013 .

[2]  R. Duffey,et al.  Heat-Transfer Enhancement at Supercritical Pressures , 2007 .

[3]  Behzad Pouladi,et al.  Connectionist technique estimates H2S solubility in ionic liquids through a low parameter approach , 2015 .

[4]  J. Watson,et al.  Thermal conductivity of carbon dioxide in the temperature range 300–348 K and pressures up to 25 MPa , 1983 .

[5]  P. Buryan,et al.  Thermal Conductivity of Carbon Dioxide–Methane Mixtures at Temperatures Between 300 and 425 K and at Pressures up to 12 MPa , 2005 .

[6]  M. Mukhopadhyay Natural extracts using supercritical carbon dioxide , 2000 .

[7]  M. Ahmadi Prediction of asphaltene precipitation using artificial neural network optimized by imperialist competitive algorithm , 2011 .

[8]  Ali Elkamel,et al.  Recovery Rate of Vapor Extraction in Heavy Oil Reservoirs—Experimental, Statistical, and Modeling Studies , 2014 .

[9]  Alireza Baghban,et al.  Phase equilibrium modeling of semi-clathrate hydrates of seven commonly gases in the presence of TBAB ionic liquid promoter based on a low parameter connectionist technique , 2015 .

[10]  M. Ahmadi Neural network based unified particle swarm optimization for prediction of asphaltene precipitation , 2012 .

[11]  Ernesto Reverchon,et al.  Supercritical fluid extraction and fractionation of essential oils and related products , 1997 .

[12]  J. Sengers,et al.  Thermal Conductivity of Carbon Dioxide and Steam in the Supercritical Region , 1973 .

[13]  A. Bahadori,et al.  Predictive tool for an accurate estimation of carbon dioxide transport properties , 2010 .

[14]  K. E. Starling,et al.  Generalized multiparameter correlation for nonpolar and polar fluid transport properties , 1988 .

[15]  Mohammad Ali Ahmadi,et al.  Robust intelligent tool for estimating dew point pressure in retrograded condensate gas reservoirs: Application of particle swarm optimization , 2014 .

[16]  J. Watson,et al.  Thermal conductivity of argon, nitrogen and carbon dioxide at elevated temperatures and pressures , 1986 .

[17]  T. Zhao,et al.  An experimental investigation of convection heat transfer to supercritical carbon dioxide in miniature tubes , 2002 .

[18]  Vladimir Vapnik,et al.  Statistical learning theory , 1998 .

[19]  Howard J. M. Hanley,et al.  Prediction of transport properties. 2. Thermal conductivity of pure fluids and mixtures , 1983 .

[20]  Andy Pearson,et al.  ICR0021 CARBON DIOXIDE - NEW USES FOR AN OLD REFRIGERANT , 2005 .

[21]  Alireza Bahadori,et al.  Determination of oil well production performance using artificial neural network (ANN) linked to the particle swarm optimization (PSO) tool , 2015 .

[22]  Mohammad Ali Ahmadi,et al.  Connectionist approach estimates gas–oil relative permeability in petroleum reservoirs: Application to reservoir simulation , 2015 .

[23]  S. Guigard,et al.  Extraction of hydrocarbons from Athabasca oil sand slurry using supercritical carbon dioxide , 2015 .

[24]  S. Mayadevi Supercritical Carbon Dioxide , 2014 .

[25]  Mohammad Ali Ahmadi,et al.  Neural network based swarm concept for prediction asphaltene precipitation due to natural depletion , 2012 .

[26]  Fu-Hsiang Chen,et al.  Detecting biotechnology industry's earnings management using Bayesian network, principal component analysis, back propagation neural network, and decision tree , 2015 .

[27]  E. M. D. L. Ossa,et al.  Recovery of grape seed oil by liquid and supercritical carbon dioxide extraction: a comparison with conventional solvent extraction , 1996 .

[28]  Armin Hafner,et al.  Development of compact heat exchangers for CO2 air-conditioning systems☆ , 1998 .

[29]  A. Bahadori,et al.  Prediction of a solid desiccant dehydrator performance using least squares support vector machines algorithm , 2015 .

[30]  A. Bahadori,et al.  A least-squares support vector machine approach to predict temperature drop accompanying a given pressure drop for the natural gas production and processing systems , 2017 .

[31]  Ehsan Heidaryan,et al.  A novel correlation approach to estimate thermal conductivity of pure carbon dioxide in the supercritical region , 2012 .

[32]  F. Orr,et al.  Use of Carbon Dioxide in Enhanced Oil Recovery , 1984, Science.

[33]  Alireza Bahadori,et al.  Prediction performance of natural gas dehydration units for water removal efficiency using a least-square support vector machine , 2016 .

[34]  A. Amooey A simple correlation to predict thermal conductivity of supercritical carbon dioxide , 2014 .