Communication: Universal Markovian reduction of Brownian particle dynamics.

Non-Markovian processes can often be turned Markovian by enlarging the set of variables. Here we show, by an explicit construction, how this can be done for the dynamics of a Brownian particle obeying the generalized Langevin equation. Given an arbitrary bath spectral density J(0), we introduce an orthogonal transformation of the bath variables into effective modes, leading stepwise to a semi-infinite chain with nearest-neighbor interactions. The transformation is uniquely determined by J(0) and defines a sequence {J(n)}(n∈N) of residual spectral densities describing the interaction of the terminal chain mode, at each step, with the remaining bath. We derive a simple one-term recurrence relation for this sequence and show that its limit is the quasi-Ohmic expression provided by the Rubin model of dissipation. Numerical calculations show that, irrespective of the details of J(0), convergence is fast enough to be useful in practice for an effective Ohmic reduction of the dissipative dynamics.

[1]  Martin B. Plenio,et al.  Exact mapping between system-reservoir quantum models and semi-infinite discrete chains using orthogonal polynomials , 2010, 1006.4507.

[2]  Susana F Huelga,et al.  Entanglement and non-markovianity of quantum evolutions. , 2009, Physical review letters.

[3]  P. Hänggi,et al.  Markovian embedding of non-Markovian superdiffusion. , 2009, Physical review. E, Statistical, nonlinear, and soft matter physics.

[4]  Irene Burghardt,et al.  Effective-mode representation of non-Markovian dynamics: a hierarchical approximation of the spectral density. II. Application to environment-induced nonadiabatic dynamics. , 2009, The Journal of chemical physics.

[5]  Jyrki Piilo,et al.  Measure for the degree of non-markovian behavior of quantum processes in open systems. , 2009, Physical review letters.

[6]  Irene Burghardt,et al.  Effective-mode representation of non-Markovian dynamics: a hierarchical approximation of the spectral density. I. Application to single surface dynamics. , 2009, The Journal of chemical physics.

[7]  J Eisert,et al.  Assessing non-Markovian quantum dynamics. , 2007, Physical review letters.

[8]  Irene Burghardt,et al.  Short-time dynamics through conical intersections in macrosystems. , 2005, Physical review letters.

[9]  Francesco Petruccione,et al.  The Theory of Open Quantum Systems , 2002 .

[10]  U. Weiss Quantum Dissipative Systems , 1993 .

[11]  K. Lendi,et al.  Quantum Dynamical Semigroups and Applications , 1987 .

[12]  J. Onuchic,et al.  Effect of friction on electron transfer in biomolecules , 1985 .

[13]  A. Leggett Quantum tunneling in the presence of an arbitrary linear dissipation mechanism , 1984 .

[14]  P. Grigolini,et al.  Phonon thermal baths: A treatment in terms of reduced models , 1982 .

[15]  H. D. Miller,et al.  The Theory Of Stochastic Processes , 1977, The Mathematical Gazette.

[16]  M. Dupuis Moment and Continued Fraction Expansions of Time Autocorrelation Functions , 1967 .

[17]  H. Mori A Continued-Fraction Representation of the Time-Correlation Functions , 1965 .

[18]  R. Rubin,et al.  MOMENTUM AUTOCORRELATION FUNCTIONS AND ENERGY TRANSPORT IN HARMONIC CRYSTALS CONTAINING ISOTOPIC DEFECTS , 1963 .

[19]  F. Smithies,et al.  Singular Integral Equations , 1977 .