A new aspect of plasma-induced physical damage in three-dimensional scaled structures — Sidewall damage by stochastic straggling and sputtering

Increasing demands for higher performance LSIs require three dimensional (3D) structures such as a FinFET and 3D integration package, and a 3D NAND flash memory. We focused on damage creation mechanism in such structures during plasma etching-plasma-induced physical damage (PPD). Compared to PPD in planar FETs (e.g. Si recess), atomistic simulations predicted that, during etching of FinFETs, both “straggling” of impinging ions in the bulk and “sputtering” of species at the reacting surface created defects in the bulk fin. The damage layer formation in the fin structure was modeled on the basis of range theory. A molecular dynamics simulation was performed in a Si fin structure to verify the proposed mechanism. Created defect structures by these mechanisms were confirmed to play the role of a carrier trap site by a quantum mechanical calculation. The obtained results showed that ions with lighter masses and higher incident energies induced a larger amount of damage in the bulk fin. Since they are the intrinsic nature of plasma etching, both stochastic straggling and sputtering should be implemented in the PPD evaluation of 3D devices.

[1]  K. Eriguchi,et al.  Plasma-Induced Defect-Site Generation in Si Substrate and Its Impact on Performance Degradation in Scaled MOSFETs , 2009, IEEE Electron Device Letters.

[2]  K. Eriguchi,et al.  A new framework for performance prediction of advanced MOSFETs with plasma-induced recess structure and latent defect site , 2008, 2008 IEEE International Electron Devices Meeting.

[3]  Koji Eriguchi,et al.  Trade-Off Relationship between Si Recess and Defect Density Formed by Plasma-Induced Damage in Planar Metal–Oxide–Semiconductor Field-Effect Transistors and the Optimization Methodology , 2011, Japanese Journal of Applied Physics.

[4]  Zheng Guo,et al.  A 4.6 GHz 162 Mb SRAM Design in 22 nm Tri-Gate CMOS Technology With Integrated Read and Write Assist Circuitry , 2013, IEEE Journal of Solid-State Circuits.

[5]  C. Steinbrüchel Universal energy dependence of physical and ion-enhanced chemical etch yields at low ion energy , 1989 .

[6]  Weber,et al.  Computer simulation of local order in condensed phases of silicon. , 1985, Physical review. B, Condensed matter.

[7]  T. Hideki Intrinsic Point Defects in Crystalline Silicon , 2006 .

[8]  Yi-Hsuan Hsiao,et al.  A novel dual-channel 3D NAND flash featuring both N-channel and P-channel NAND characteristics for bit-alterable Flash memory and a new opportunity in sensing the stored charge in the WL space , 2013, 2013 IEEE International Electron Devices Meeting.

[9]  Koji Eriguchi,et al.  Model for Bias Frequency Effects on Plasma-Damaged Layer Formation in Si Substrates , 2010 .

[10]  Abraham,et al.  Molecular-dynamics study of self-interstitials in silicon. , 1987, Physical review. B, Condensed matter.

[11]  Koji Eriguchi,et al.  An interatomic potential model for molecular dynamics simulation of silicon etching by Br+-containing plasmas , 2008 .

[12]  Hiroshi Ishiwara,et al.  Theoretical Considerations on Lateral Spread of Implanted Ions , 1972 .

[13]  K. Eriguchi,et al.  Effects of Plasma-Induced Si Recess Structure on n-MOSFET Performance Degradation , 2009, IEEE Electron Device Letters.

[14]  L. Colombo Tight-Binding Theory of Native Point Defects in Silicon , 2002 .

[15]  Satoshi Hamaguchi,et al.  Molecular dynamics simulation of silicon and silicon dioxide etching by energetic halogen beams , 2001 .

[16]  Koji Eriguchi,et al.  Atomistic simulations of plasma process-induced Si substrate damage - Effects of substrate bias-power frequency , 2013, Proceedings of 2013 International Conference on IC Design & Technology (ICICDT).

[17]  C. Auth,et al.  A 22nm high performance and low-power CMOS technology featuring fully-depleted tri-gate transistors, self-aligned contacts and high density MIM capacitors , 2012, 2012 Symposium on VLSI Technology (VLSIT).

[18]  W. D. Wilson,et al.  Calculations of nuclear stopping, ranges, and straggling in the low-energy region , 1977 .

[19]  Mitsumasa Koyanagi,et al.  Heterogeneous 3D integration — Technology enabler toward future super-chip , 2013, 2013 IEEE International Electron Devices Meeting.

[20]  Koji Eriguchi,et al.  Quantitative and comparative characterizations of plasma process-induced damage in advanced metal-oxide-semiconductor devices , 2008 .

[21]  Michael A. Lieberman,et al.  Principles of Plasma Discharges and Materials Processing, 2nd Edition , 2003 .

[22]  Satoshi Hamaguchi,et al.  Reducing Damage to Si Substrates during Gate Etching Processes , 2008 .

[23]  J. Lindhard,et al.  RANGE CONCEPTS AND HEAVY ION RANGES (NOTES ON ATOMIC COLLISIONS, II) , 1963 .

[24]  P. Schultz,et al.  Theory of defect levels and the "band gap problem" in silicon. , 2006, Physical review letters.

[25]  A. Lichtenberg,et al.  Principles of Plasma Discharges and Materials Processing: Lieberman/Plasma 2e , 2005 .

[26]  S. Sze Semiconductor Devices: Physics and Technology , 1985 .