Oxidation of solid thin films of neonicotinoid pesticides by gas phase hydroxyl radicals

Oxidation of thin films of three solid neonicotinoid pesticides by gas-phase OH radicals yields a variety of products primarily in the surface layers.

[1]  Shaoyou Lu,et al.  Human exposure to neonicotinoids and the associated health risks: A review. , 2022, Environment international.

[2]  Gabriele Giuseppe Distefano,et al.  The ubiquity of neonicotinoid contamination: Residues in seabirds with different trophic habits. , 2021, Environmental research.

[3]  Jianming Xu,et al.  Suspecting screening "known unknown" pesticides and transformation products in soil at pesticide manufacturing sites. , 2021, Science of the Total Environment.

[4]  Dong-mei Zhou,et al.  Extensive production of hydroxyl radicals during oxygenation of anoxic paddy soils: Implications to imidacloprid degradation. , 2021, Chemosphere.

[5]  A. Rohrbacher,et al.  Probing Matrix Effects on the Heterogeneous Photochemistry of Neonicotinoid Pesticides, Dinotefuran and Nitenpyram , 2021 .

[6]  D. Snow,et al.  Literature Review: Global Neonicotinoid Insecticide Occurrence in Aquatic Environments , 2020, Water.

[7]  G. Glauser,et al.  Residues of neonicotinoids in soil, water and people's hair: A case study from three agricultural regions of the Philippines. , 2020, The Science of the total environment.

[8]  W. Xia,et al.  A nationwide study of occurrence and exposure assessment of neonicotinoid insecticides and their metabolites in drinking water of China. , 2020, Water research.

[9]  Qingguo Huang,et al.  Transformation and removal of imidacloprid mediated by silver ferrite nanoparticle facilitated peroxymonosulfate activation in water: Reaction rates, products, and pathways. , 2020, Environmental pollution.

[10]  D. D. Nguyen,et al.  Imidacloprid degradation by electro-Fenton process using composite Fe3O4–Mn3O4 nanoparticle catalyst , 2020, Research on Chemical Intermediates.

[11]  Busra Sonmez Baghirzade,et al.  Imidacloprid elimination by O3 and O3/UV: kinetics study, matrix effect, and mechanism insight , 2020, Environmental Science and Pollution Research.

[12]  M. Shiraiwa,et al.  Unexpected formation of oxygen-free products and nitrous acid from the ozonolysis of the neonicotinoid nitenpyram , 2020, Proceedings of the National Academy of Sciences.

[13]  G. Malina,et al.  Fate of selected neonicotinoid insecticides in soil-water systems: Current state of the art and knowledge gaps. , 2020, Chemosphere.

[14]  Mickaël Henry,et al.  Neonicotinoid-induced mortality risk for bees foraging on oilseed rape nectar persists despite EU moratorium. , 2019, The Science of the total environment.

[15]  Yanhong Sun,et al.  Efficient visible-light photocatalytic degradation of imidacloprid and acetamiprid using a modified carbon nitride/tungstophosphoric acid composite induced by a nucleophilic addition reaction , 2019, Applied Surface Science.

[16]  Yongqing Zhang,et al.  Efficient degradation of imidacloprid in water through iron activated sodium persulfate , 2019, Chemical Engineering Journal.

[17]  L. Wojnárovits,et al.  Photocatalytic, photolytic and radiolytic elimination of imidacloprid from aqueous solution: Reaction mechanism, efficiency and economic considerations , 2019, Applied Catalysis B: Environmental.

[18]  Yang Deng,et al.  Influencing factors and kinetic studies of imidacloprid degradation by ozonation , 2019, Environmental technology.

[19]  A. Mostafavi,et al.  Photocatalytic degradation of imidacloprid using GO/Fe3O4/TiO2-NiO under visible radiation: Optimization by response level method , 2019, Polyhedron.

[20]  G. Glauser,et al.  A large-scale survey of house sparrows feathers reveals ubiquitous presence of neonicotinoids in farmlands. , 2019, The Science of the total environment.

[21]  O. Nielsen,et al.  Quantum Yields and N2O Formation from Photolysis of Solid Films of Neonicotinoids. , 2019, Journal of agricultural and food chemistry.

[22]  C. Dong,et al.  Fluidized-bed Fenton treatment of imidacloprid: Optimization and degradation pathway , 2018, Sustainable Environment Research.

[23]  Yadong Li,et al.  Photodegradation of clothianidin and thiamethoxam in agricultural soils , 2018, Environmental Science and Pollution Research.

[24]  C. Lu,et al.  Potential human exposures to neonicotinoid insecticides: A review. , 2018, Environmental pollution.

[25]  D. Goulson,et al.  Environmental Risks and Challenges Associated with Neonicotinoid Insecticides. , 2018, Environmental science & technology.

[26]  Xiao-ming Shen,et al.  Human exposure to neonicotinoid insecticides and the evaluation of their potential toxicity: An overview. , 2018, Chemosphere.

[27]  B. Finlayson‐Pitts,et al.  Photochemistry of Solid Films of the Neonicotinoid Nitenpyram. , 2018, Environmental science & technology.

[28]  G. Glauser,et al.  A worldwide survey of neonicotinoids in honey , 2017, Science.

[29]  V. Fournier,et al.  Chronic exposure to neonicotinoids reduces honey bee health near corn crops , 2017, Science.

[30]  E. Genersch,et al.  Country-specific effects of neonicotinoid pesticides on honey bees and wild bees , 2017, Science.

[31]  D. Goulson,et al.  The environmental risks of neonicotinoid pesticides: a review of the evidence post 2013 , 2017, bioRxiv.

[32]  K. Riddellová,et al.  Distributions of imidacloprid, imidacloprid-olefin and imidacloprid-urea in green plant tissues and roots of rapeseed (Brassica napus) from artificially contaminated potting soil. , 2017, Pest management science.

[33]  David M. Cwiertny,et al.  Occurrence of Neonicotinoid Insecticides in Finished Drinking Water and Fate during Drinking Water Treatment , 2017 .

[34]  B. Finlayson‐Pitts,et al.  Photochemistry of Thin Solid Films of the Neonicotinoid Imidacloprid on Surfaces. , 2017, Environmental science & technology.

[35]  G. Lewis,et al.  Review of field and monitoring studies investigating the role of nitro-substituted neonicotinoid insecticides in the reported losses of honey bee colonies (Apis mellifera) , 2016, Ecotoxicology.

[36]  P. White,et al.  Modeling photodegradation kinetics of three systemic neonicotinoids—dinotefuran, imidacloprid, and thiamethoxam—in aqueous and soil environment , 2016, Environmental toxicology and chemistry.

[37]  A. Khataee,et al.  Electrochemical and photo-assisted electrochemical treatment of the pesticide imidacloprid in aqueous solution by the Fenton process: effect of operational parameters , 2016, Research on Chemical Intermediates.

[38]  A. Lagalante,et al.  Assessment of Imidacloprid and Its Metabolites in Foliage of Eastern Hemlock Multiple Years Following Treatment for Hemlock Woolly Adelgid, Adelges tsugae (Hemiptera: Adelgidae), in Forested Conditions , 2015, Journal of economic entomology.

[39]  J. Tooker,et al.  Large-scale deployment of seed treatments has driven rapid increase in use of neonicotinoid insecticides and preemptive pest management in US field crops. , 2015, Environmental science & technology.

[40]  D. Goulson,et al.  Bee declines driven by combined stress from parasites, pesticides, and lack of flowers , 2015, Science.

[41]  U. Pöschl,et al.  Multiphase chemical kinetics of OH radical uptake by molecular organic markers of biomass burning aerosols: humidity and temperature dependence, surface reaction, and bulk diffusion. , 2015, The journal of physical chemistry. A.

[42]  Hongyan Zhang,et al.  Photodegradation of Imidacloprid in Aqueous Solution by the Metal-Free Catalyst Graphitic Carbon Nitride using an Energy-Saving Lamp. , 2015, Journal of agricultural and food chemistry.

[43]  M. Liess,et al.  Neonicotinoid contamination of global surface waters and associated risk to aquatic invertebrates: a review. , 2015, Environment international.

[44]  C. Downs,et al.  Systemic insecticides (neonicotinoids and fipronil): trends, uses, mode of action and metabolites , 2014, Environmental Science and Pollution Research.

[45]  C. Downs,et al.  Effects of neonicotinoids and fipronil on non-target invertebrates , 2014, Environmental Science and Pollution Research.

[46]  C. Krupke,et al.  Environmental fate and exposure; neonicotinoids and fipronil , 2014, Environmental Science and Pollution Research.

[47]  M. Oturan,et al.  Efficient removal of insecticide “imidacloprid” from water by electrochemical advanced oxidation processes , 2014, Environmental Science and Pollution Research.

[48]  D. Goulson REVIEW: An overview of the environmental risks posed by neonicotinoid insecticides , 2013 .

[49]  P. Trebše,et al.  Photocatalytic degradation with immobilised TiO(2) of three selected neonicotinoid insecticides: imidacloprid, thiamethoxam and clothianidin. , 2012, Chemosphere.

[50]  Denis Jacquemin,et al.  New insights on the molecular features and electrophysiological properties of dinotefuran, imidacloprid and acetamiprid neonicotinoid insecticides. , 2011, Bioorganic & medicinal chemistry.

[51]  L. Debrauwer,et al.  Ozonation of imidacloprid in aqueous solutions: reaction monitoring and identification of degradation products. , 2011, Journal of hazardous materials.

[52]  R. Nauen,et al.  Overview of the status and global strategy for neonicotinoids. , 2011, Journal of agricultural and food chemistry.

[53]  B. Finlayson‐Pitts,et al.  Hydroxyl radical quantum yields from isopropyl nitrite photolysis in air. , 2010, Environmental science & technology.

[54]  B. Finlayson‐Pitts,et al.  Reaction of gas phase OH with unsaturated self-assembled monolayers and relevance to atmospheric organic oxidations. , 2010, Physical chemistry chemical physics : PCCP.

[55]  U. Pöschl,et al.  Kinetic multi-layer model of aerosol surface and bulk chemistry (KM-SUB): the influence of interfacial transport and bulk diffusion on the oxidation of oleic acid by ozone , 2010 .

[56]  J. Frazier,et al.  High Levels of Miticides and Agrochemicals in North American Apiaries: Implications for Honey Bee Health , 2010, PloS one.

[57]  W. Schwack,et al.  Phototransformation of imidacloprid on isolated tomato fruit cuticles and on tomato fruits. , 2010, Journal of photochemistry and photobiology. B, Biology.

[58]  I. Poulios,et al.  Heterogeneous and homogeneous photocatalytic degradation of the insecticide imidacloprid in aqueous solutions , 2009 .

[59]  R. Nauen,et al.  Applied aspects of neonicotinoid uses in crop protection. , 2008, Pest management science.

[60]  W. Schwack,et al.  Photochemistry of imidacloprid in model systems. , 2008, Journal of agricultural and food chemistry.

[61]  G. Nickless,et al.  Night‐time NO3 and OH radical concentrations in the United Kingdom inferred from hydrocarbon measurements , 2008 .

[62]  C. Zaror,et al.  Imidacloprid oxidation by photo-Fenton reaction. , 2008, Journal of hazardous materials.

[63]  A. Fernández-Alba,et al.  Degradation of imidacloprid in water by photo-Fenton and TiO2 photocatalysis at a solar pilot plant: a comparative study. , 2001, Environmental science & technology.

[64]  Dake Yu,et al.  C−H Bond Dissociation Energies of Alkyl Amines: Radical Structures and Stabilization Energies§ , 1997 .

[65]  J. Casida,et al.  Interaction of Imidacloprid Metabolites and Analogs with the Nicotinic Acetylcholine Receptor of Mouse Brain in Relation to Toxicity , 1997 .

[66]  Roger Atkinson,et al.  Evaluated kinetic and photochemical data for atmospheric chemistry: Volume III - gas phase reactions of inorganic halogens , 2006 .

[67]  R. Atkinson A structure-activity relationship for the estimation of rate constants for the gas-phase reactions of OH radicals with organic compounds , 1987 .

[68]  Roger Atkinson,et al.  Kinetics and mechanisms of the gas-phase reactions of the hydroxyl radical with organic compounds under atmospheric conditions , 1986 .

[69]  A. Castelhano,et al.  Heats of formation and ionization potentials of some .alpha.-aminoalkyl radicals , 1983 .