Bis(μ-disulfur dinitrido)bis[diphenyltin(IV)]

The title compound, [Sn2(C6H5)4(N2S2)2], exists as a centrosymmetric binuclear dimer with the SnIV centres in distorted trigonal bipyramidal geometry and a central Sn2N2 core.

[1]  David J. Williams,et al.  Solid-state structures of platinum–sulphur–nitrogen stacking compounds: [Pt(S2N2)(PMe2Ph)2], [Pt(S2N2H)(PMe2Ph)2]Cl, [Pt(S2N2H)(PMe2Ph)2]PF6, and [Pd(S2N2H)(PMe2Ph)2]BF4 , 1988 .

[2]  A. Slawin,et al.  The Synthesis of [{n-Bu2Sn(S2N2)}2] and its use in the preparation of Organometallic Iridium Sulfur Nitrogen Complexes , 2002 .

[3]  P. Bates,et al.  The preparation and characterisation of (disulphur dinitrido)bis(phosphine) complexes, [M(S2N2)(PR3)2](M = Pt, PR3= PMe3, PMe2PH, PMePh2, PPh3, PEt3, PPrn3, PBun3, or ½Ph2PCH2CH2PPh2; M = Pd, PR3=½Ph2PCH2CH2PPh2). X-Ray crystal structure of [Pt(S2N2)(PMe3)2] , 1986 .

[4]  Alexandra M. Z. Slawin,et al.  Bis(diphenyl­methyl­phosphine-κP)(disulfurdinitrido-κ2N,S)platinum(II) dichloro­methane solvate , 2007 .

[5]  A. Slawin,et al.  N-Metallation of MS2N2 rings. X-ray crystal structures of [(η5-C5Me5)Ir(S2N2)Au(PPh3)][ClO4], [{(η5-C5Me5)Ir(S2N2)Au}2(μ2-dppm)][ClO4]2 and [Au(dppeS-P)Cl]2 , 2003 .

[6]  A. Slawin,et al.  (1η5-Cyclo­penta­dien­yl)(μ-disulfur dinitrido)(triphenyl­phosphino-2κP)cobalt(II)gold(I) perchlorate , 2006 .

[7]  David J. Williams,et al.  Binuclear, nitrogen-bridged complexes of disulphurdinitride, [M(S 2N2)(PPh3)]2·CH2Cl2(M = Pd, Pt) , 1985 .

[8]  J. Woollins,et al.  The preparation and structure of complexes containing simple sulphur-nitrogen ligands , 1986 .

[9]  David J. Williams,et al.  The preparation and crystal structures of platinum stacking compounds containing the S2N2H– ligand: [Pt(S2N2H)(PMe3)2][PF6] and [Pt(S2N2H)(PMe2Ph)2][BF4] , 1986 .

[10]  F. Edelmann,et al.  Preparation and X-ray crystal structure of (Ph3P)2PtS2N2·C7H8: a reinvestigation of the reaction of S4N4H4 with (Ph3P)4Pt , 1986 .

[11]  David J. Williams,et al.  The preparation and X-ray structure of (disulphurdinitrido)bis(triphenylphosphine) platinum(II)—tetrachloroform solvate, Pt(S2N2)(PPh3)2·4CHCl3 , 1985 .

[12]  G. Sheldrick A short history of SHELX. , 2008, Acta crystallographica. Section A, Foundations of crystallography.