3D printing of cellular materials for advanced electrochemical energy storage and conversion.

3D printing, an advanced layer-by-layer assembly technology, is an ideal platform for building architectures with customized geometries and controllable microstructures. Bio-inspired cellular material is one of most representative 3D-printed architectures, and attracting growing attention compared to block counterparts. The integration of 3D printing and cellular materials offer massive advantages and opens up great opportunities in diverse application fields, particularly in electrochemical energy storage and conversion (EESC). This article gives a comprehensive overview of 3D-printed cellular materials for advanced EESC. It begins with an introduction of advanced 3D printing techniques for cellular material fabrication, followed by the corresponding material design principles. Recent advances in 3D-printed cellular materials for EESC applications, including rechargeable batteries, supercapacitors and electrocatalysts are then summarized and discussed. Finally, current trends and challenges along with in-depth future perspectives are provided.

[1]  Xiaobo Ji,et al.  Anions induced evolution of Co3X4 (X = O, S, Se) as sodium-ion anodes: The influences of electronic structure, morphology, electrochemical property , 2018, Nano Energy.

[2]  Alida Mazzoli,et al.  Selective laser sintering in biomedical engineering , 2012, Medical & Biological Engineering & Computing.

[3]  P. Taberna,et al.  Materials for supercapacitors: When Li-ion battery power is not enough , 2018 .

[4]  F. Béguin,et al.  Electrochemical energy storage in ordered porous carbon materials , 2005 .

[5]  A. Kashani,et al.  Additive manufacturing (3D printing): A review of materials, methods, applications and challenges , 2018, Composites Part B: Engineering.

[6]  Ziyang Dai,et al.  Versatile MnO2/CNT Putty‐Like Composites for High‐Rate Lithium‐Ion Batteries , 2018 .

[7]  G. Cao,et al.  3D printing-based cellular microelectrodes for high-performance asymmetric quasi-solid-state micro-pseudocapacitors , 2020, Journal of Materials Chemistry A.

[8]  D. Dowling,et al.  Evaluation of the mechanical performance of polymer parts fabricated using a production scale multi jet fusion printing process , 2018, Additive Manufacturing.

[9]  Shuai Chang,et al.  High loading accessible active sites via designable 3D-printed metal architecture towards promoting electrocatalytic performance , 2019, Journal of Materials Chemistry A.

[10]  Steven D. Lacey,et al.  Toward garnet electrolyte–based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface , 2017, Science Advances.

[11]  Y. Jiao,et al.  Heteroatom-Doped Transition Metal Electrocatalysts for Hydrogen Evolution Reaction , 2019, ACS Energy Letters.

[12]  Yi Cui,et al.  Materials for lithium-ion battery safety , 2018, Science Advances.

[13]  Kang Zhang,et al.  3D printing of functional biomaterials for tissue engineering. , 2016, Current opinion in biotechnology.

[14]  Wenhua Zuo,et al.  Bismuth oxide: a versatile high-capacity electrode material for rechargeable aqueous metal-ion batteries , 2016 .

[15]  David E.J. Armstrong,et al.  Hybrid electrolytes with 3D bicontinuous ordered ceramic and polymer microchannels for all-solid-state batteries , 2018 .

[16]  Zhe Wang,et al.  Laminated Object Manufacturing of 3D‐Printed Laser‐Induced Graphene Foams , 2018, Advanced materials.

[17]  W. Wang,et al.  3D direct writing fabrication of electrodes for electrochemical storage devices , 2017 .

[18]  S. Dou,et al.  Three dimensional cellular architecture of sulfur doped graphene: self-standing electrode for flexible supercapacitors, lithium ion and sodium ion batteries , 2017 .

[19]  Grzegorz Milczarek,et al.  Renewable Cathode Materials from Biopolymer/Conjugated Polymer Interpenetrating Networks , 2012, Science.

[20]  Shoushan Fan,et al.  Self‐assembly of 3D Carbon Nanotube Sponges: A Simple and Controllable Way to Build Macroscopic and Ultralight Porous Architectures , 2017, Advanced materials.

[21]  Xiaoyu Zheng,et al.  Additive manufacturing of complex micro-architected graphene aerogels , 2018 .

[22]  Maher F. El-Kady,et al.  Graphene for batteries, supercapacitors and beyond , 2016 .

[23]  Jonghyun Park,et al.  3D printed hierarchically-porous microlattice electrode materials for exceptionally high specific capacity and areal capacity lithium ion batteries , 2018, Additive Manufacturing.

[24]  Wei Xia,et al.  Metal–organic frameworks and their derived nanostructures for electrochemical energy storage and conversion , 2015 .

[25]  Husam N. Alshareef,et al.  All Pseudocapacitive MXene‐RuO2 Asymmetric Supercapacitors , 2018 .

[26]  Tian Li,et al.  Graphene Oxide‐Based Electrode Inks for 3D‐Printed Lithium‐Ion Batteries , 2016, Advanced materials.

[27]  Colin F. Dickens,et al.  Combining theory and experiment in electrocatalysis: Insights into materials design , 2017, Science.

[28]  Juergen Biener,et al.  Toward digitally controlled catalyst architectures: Hierarchical nanoporous gold via 3D printing , 2018, Science Advances.

[29]  Xiaoyu Zheng,et al.  Multiscale metallic metamaterials. , 2016, Nature materials.

[30]  S. Agarwal,et al.  Low-Density Open Cellular Sponges as Functional Materials. , 2017, Angewandte Chemie.

[31]  Alexandra M. Golobic,et al.  Highly compressible 3D periodic graphene aerogel microlattices , 2015, Nature Communications.

[32]  Gabriel Popescu,et al.  High‐Resolution Projection Microstereolithography for Patterning of Neovasculature , 2016, Advanced healthcare materials.

[33]  D. Pech,et al.  Microsupercapacitors as miniaturized energy-storage components for on-chip electronics. , 2017, Nature nanotechnology.

[34]  Liangbing Hu,et al.  3D‐Printed Graphene Oxide Framework with Thermal Shock Synthesized Nanoparticles for Li‐CO2 Batteries , 2018, Advanced Functional Materials.

[35]  J. Lewis,et al.  Architected cellular ceramics with tailored stiffness via direct foam writing , 2017, Proceedings of the National Academy of Sciences.

[36]  W. Law,et al.  3D printed graphene/nickel electrodes for high areal capacitance electrochemical storage , 2019, Journal of Materials Chemistry A.

[37]  Bruce Dunn,et al.  Efficient storage mechanisms for building better supercapacitors , 2016, Nature Energy.

[38]  Keivan Davami,et al.  Additively-manufactured lightweight Metamaterials for energy absorption , 2018 .

[39]  John Wang,et al.  3D‐Printed MOF‐Derived Hierarchically Porous Frameworks for Practical High‐Energy Density Li–O2 Batteries , 2018, Advanced Functional Materials.

[40]  Jingguang G. Chen,et al.  Nanostructured electrodes for high-performance pseudocapacitors. , 2013, Angewandte Chemie.

[41]  Stephen Beirne,et al.  Three dimensional (3D) printed electrodes for interdigitated supercapacitors , 2014 .

[42]  K. Amine,et al.  Structure-dependent Performance of TiO 2 /C as Anode Material for Na-ion Batteries , 2018 .

[43]  A. Manthiram,et al.  Nanostructured Anatase Titania as a Cathode Catalyst for Li-CO2 Batteries. , 2018, ACS applied materials & interfaces.

[44]  L. Kou,et al.  Two‐Dimensional Metal Oxide Nanomaterials for Next‐Generation Rechargeable Batteries , 2017, Advanced materials.

[45]  Johan Schot,et al.  The roles of users in shaping transitions to new energy systems , 2016, Nature Energy.

[46]  Jun Liu,et al.  Mesoporous materials for energy conversion and storage devices , 2016 .

[47]  Kun Zhou,et al.  Boosting capacitive charge storage of 3D-printed micro-pseudocapacitors via rational holey graphene engineering , 2019 .

[48]  Jim P. Zheng,et al.  The Effect of Cathode and Anode Potentials on the Cycling Performance of Li-Ion Capacitors , 2013 .

[49]  Kathleen A. Schwarz,et al.  Direct visualization of sulfur cathodes: new insights into Li-S batteries via operando X-ray based methods. , 2018, Energy & environmental science.

[50]  Shlomo Magdassi,et al.  Novel Materials for 3D Printing by Photopolymerization , 2018, Advanced materials.

[51]  Zhenhai Xia,et al.  Design Principles for Heteroatom‐Doped Carbon Nanomaterials as Highly Efficient Catalysts for Fuel Cells and Metal–Air Batteries , 2015, Advanced materials.

[52]  Manpreet Kaur,et al.  Hierarchically Designed Electron Paths in 3D Printed Energy Storage Devices. , 2018, Langmuir : the ACS journal of surfaces and colloids.

[53]  N. Zheng,et al.  A Two-Dimensional Porous Carbon-Modified Separator for High-Energy-Density Li-S Batteries , 2017 .

[54]  Gordon G. Wallace,et al.  3D Printing for Electrocatalytic Applications , 2019, Joule.

[55]  Chee Kai Chua,et al.  Polymeric composites for powder-based additive manufacturing: Materials and applications , 2019, Progress in Polymer Science.

[56]  Arumugam Manthiram,et al.  Lithium battery chemistries enabled by solid-state electrolytes , 2017 .

[57]  Majid Beidaghi,et al.  Capacitive energy storage in micro-scale devices: recent advances in design and fabrication of micro-supercapacitors , 2014 .

[58]  Y. Bando,et al.  Metal–organic framework-derived one-dimensional porous or hollow carbon-based nanofibers for energy storage and conversion , 2018 .

[59]  Wim E Hennink,et al.  25th Anniversary Article: Engineering Hydrogels for Biofabrication , 2013, Advanced materials.

[60]  Yang Song,et al.  3D graphene-based hybrid materials: synthesis and applications in energy storage and conversion. , 2016, Nanoscale.

[61]  P. Bruce,et al.  A Reversible and Higher-Rate Li-O2 Battery , 2012, Science.

[62]  Johnson H. Y. Chung,et al.  Bio-ink properties and printability for extrusion printing living cells. , 2013, Biomaterials science.

[63]  Xiong Wen (David) Lou,et al.  Mixed Metal Sulfides for Electrochemical Energy Storage and Conversion , 2018 .

[64]  Christopher M. Spadaccini,et al.  3D‐Printed, Superelastic Polypyrrole–Graphene Electrodes with Ultrahigh Areal Capacitance for Electrochemical Energy Storage , 2018, Advanced Materials Technologies.

[65]  Chee Kai Chua,et al.  Fundamentals and applications of 3D printing for novel materials , 2017 .

[66]  Mariusz Twardowski,et al.  Sol‐Gel Inks for Direct‐Write Assembly of Functional Oxides , 2007 .

[67]  Ye Shi,et al.  Designing Hierarchically Nanostructured Conductive Polymer Gels for Electrochemical Energy Storage and Conversion , 2016 .

[68]  Michael C. McAlpine,et al.  3D Printed Functional and Biological Materials on Moving Freeform Surfaces , 2018, Advanced materials.

[69]  Woo Soo Kim,et al.  Three-dimensionally printed cellular architecture materials: perspectives on fabrication, material advances, and applications , 2017 .

[70]  James C. Weaver,et al.  Rational design of reconfigurable prismatic architected materials , 2017, Nature.

[71]  Ryan Wicker,et al.  Multiprocess 3D printing for increasing component functionality , 2016, Science.

[72]  Sang-Hoon Park,et al.  Morphology control of three-dimensional carbon nanotube macrostructures fabricated using ice-templating method , 2013, Journal of Porous Materials.

[73]  Kai Zhang,et al.  Nanostructured Mn-based oxides for electrochemical energy storage and conversion. , 2015, Chemical Society reviews.

[74]  Boyang Liu,et al.  Extrusion‐Based 3D Printing of Hierarchically Porous Advanced Battery Electrodes , 2018, Advanced materials.

[75]  Chia-Chin Chen,et al.  Decoupling electron and ion storage and the path from interfacial storage to artificial electrodes , 2018 .

[76]  S. L. Sing,et al.  Selective laser melting of lattice structures: A statistical approach to manufacturability and mechanical behavior , 2018 .

[77]  Sang-Hoon Park,et al.  Stamping of Flexible, Coplanar Micro‐Supercapacitors Using MXene Inks , 2018, Advanced Functional Materials.

[78]  X. Lou,et al.  Metal-Organic-Framework-Based Materials as Platforms for Renewable Energy and Environmental Applications , 2017 .

[79]  Di Zhang,et al.  Generalized 3D Printing of Graphene-Based Mixed-Dimensional Hybrid Aerogels. , 2018, ACS nano.

[80]  Liangbing Hu,et al.  Progress in 3D Printing of Carbon Materials for Energy‐Related Applications , 2017, Advanced materials.

[81]  Yi Cui,et al.  Promises and challenges of nanomaterials for lithium-based rechargeable batteries , 2016, Nature Energy.

[82]  Martin Pumera,et al.  3D-printing technologies for electrochemical applications. , 2016, Chemical Society reviews.

[83]  Mark K. Debe,et al.  Electrocatalyst approaches and challenges for automotive fuel cells , 2012, Nature.

[84]  Yang Shao-Horn,et al.  Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis , 2015 .

[85]  Dan Li,et al.  Multifunctional Cellular Materials Based on 2D Nanomaterials: Prospects and Challenges , 2018, Advanced materials.

[86]  L. F. Arenas,et al.  3D-printed porous electrodes for advanced electrochemical flow reactors: A Ni/stainless steel electrode and its mass transport characteristics , 2017 .

[87]  X. Tao,et al.  Fully Controllable Design and Fabrication of Three-Dimensional Lattice Supercapacitors. , 2018, ACS applied materials & interfaces.

[88]  Xiaocong Tian,et al.  3D-printed interdigitated graphene framework as superior support of metal oxide nanostructures for remarkable micro-pseudocapacitors , 2019, Electrochimica Acta.

[89]  A. Cheetham,et al.  MOF-derived nanohybrids for electrocatalysis and energy storage: current status and perspectives. , 2018, Chemical communications.

[90]  Yingchun Lyu,et al.  Rechargeable Li/CO2–O2 (2 : 1) battery and Li/CO2 battery , 2014 .

[91]  R. Meneghello,et al.  Powder-based 3D printing for bone tissue engineering. , 2016, Biotechnology advances.

[92]  Bin Li,et al.  Continuously 3D printed quantum dot-based electrodes for lithium storage with ultrahigh capacities , 2018 .

[93]  Amir Ameli,et al.  Functional Polymers and Nanocomposites for 3D Printing of Smart Structures and Devices. , 2018, ACS applied materials & interfaces.

[94]  M. El‐Kady,et al.  3D Freeze‐Casting of Cellular Graphene Films for Ultrahigh‐Power‐Density Supercapacitors , 2016, Advanced materials.

[95]  Ming Liu,et al.  In Situ Synthesis of a Hierarchical All‐Solid‐State Electrolyte Based on Nitrile Materials for High‐Performance Lithium‐Ion Batteries , 2015 .

[96]  Tie-hu Li,et al.  3D printing well organized porous iron-nickel/polyaniline nanocages multiscale supercapacitor , 2018, Journal of Alloys and Compounds.

[97]  J. Lewis,et al.  Device fabrication: Three-dimensional printed electronics , 2015, Nature.

[98]  Yonggang Yao,et al.  Ultra‐Thick, Low‐Tortuosity, and Mesoporous Wood Carbon Anode for High‐Performance Sodium‐Ion Batteries , 2016 .

[99]  J. Lewis,et al.  3D‐Printing of Lightweight Cellular Composites , 2014, Advanced materials.

[100]  D. Aurbach,et al.  Redox Mediators for Li–O2 Batteries: Status and Perspectives , 2018, Advanced materials.

[101]  Ahmed Hussein,et al.  Evaluations of cellular lattice structures manufactured using selective laser melting , 2012 .

[102]  Maria Farsari,et al.  Direct laser writing , 2015 .

[103]  Feng Zhang,et al.  3D Printing of Graphene Aerogels. , 2016, Small.

[104]  Jeffrey W Stansbury,et al.  3D printing with polymers: Challenges among expanding options and opportunities. , 2016, Dental materials : official publication of the Academy of Dental Materials.

[105]  Yayue Pan,et al.  Elevated‐Temperature 3D Printing of Hybrid Solid‐State Electrolyte for Li‐Ion Batteries , 2018, Advanced materials.

[106]  Huiling Yang,et al.  Flexible Asymmetric Micro‐Supercapacitors Based on Bi2O3 and MnO2 Nanoflowers: Larger Areal Mass Promises Higher Energy Density , 2015 .

[107]  Bin Ding,et al.  3D Printing of Tunable Energy Storage Devices with Both High Areal and Volumetric Energy Densities , 2018, Advanced Energy Materials.

[108]  J. Maier,et al.  Kinetics of Space Charge Storage in Composites , 2018 .

[109]  Qiang Zhang,et al.  A Review of Precious‐Metal‐Free Bifunctional Oxygen Electrocatalysts: Rational Design and Applications in Zn−Air Batteries , 2018, Advanced Functional Materials.

[110]  Lili Liu,et al.  Mo2C/CNT: An Efficient Catalyst for Rechargeable Li–CO2 Batteries , 2017 .

[111]  Tuomas P J Knowles,et al.  Amyloid Fibrils as Building Blocks for Natural and Artificial Functional Materials , 2016, Advanced materials.

[112]  M. Winter,et al.  Performance and cost of materials for lithium-based rechargeable automotive batteries , 2018 .

[113]  Aaron D. Price,et al.  Toward a remarkable Li-S battery via 3D printing , 2019, Nano Energy.

[114]  D. Dubal,et al.  Hybrid energy storage: the merging of battery and supercapacitor chemistries. , 2015, Chemical Society reviews.

[115]  Y. Jiao,et al.  Emerging Two-Dimensional Nanomaterials for Electrocatalysis. , 2018, Chemical reviews.

[116]  Di Wang,et al.  Evaluation of topology-optimized lattice structures manufactured via selective laser melting , 2018 .

[117]  M. Carvalho,et al.  The lithium-ion battery: State of the art and future perspectives , 2018, Renewable and Sustainable Energy Reviews.

[118]  Changyong Liu,et al.  Fabrication and Characterization of 3D-Printed Highly-Porous 3D LiFePO4 Electrodes by Low Temperature Direct Writing Process , 2017, Materials.

[119]  Jean-Marie Tarascon,et al.  Li-O2 and Li-S batteries with high energy storage. , 2011, Nature materials.

[120]  Pedro Gomez-Romero,et al.  Towards flexible solid-state supercapacitors for smart and wearable electronics. , 2018, Chemical Society reviews.

[121]  C. Li,et al.  Functional Differentiation of Three Pores for Effective Sulfur Confinement in Li-S Battery. , 2018, Small.

[122]  Taeghwan Hyeon,et al.  Hybrid Cellular Nanosheets for High-Performance Lithium-Ion Battery Anodes. , 2015, Journal of the American Chemical Society.

[123]  Tongchao Liu,et al.  Fundamental Understanding of Water‐Induced Mechanisms in Li–O2 Batteries: Recent Developments and Perspectives , 2018, Advanced materials.

[124]  Nicholas X. Fang,et al.  Projection micro-stereolithography using digital micro-mirror dynamic mask , 2005 .

[125]  S. Risse,et al.  Correlating Morphological Evolution of Li Electrodes with Degrading Electrochemical Performance of Li/LiCoO2 and Li/S Battery Systems: Investigated by Synchrotron X-ray Phase Contrast Tomography , 2018 .

[126]  L. Nazar,et al.  Advances in Li–S batteries , 2010 .

[127]  T. Schaedler,et al.  Architected Cellular Materials , 2016 .

[128]  J. A. Lewis Direct Ink Writing of 3D Functional Materials , 2006 .

[129]  Ke Ke,et al.  Nitrogen/sulfur dual-doped 3D reduced graphene oxide networks-supported CoFe2O4 with enhanced electrocatalytic activities for oxygen reduction and evolution reactions , 2016 .

[130]  Lin Xu,et al.  Vertically stacked holey graphene/polyaniline heterostructures with enhanced energy storage for on-chip micro-supercapacitors , 2016, Nano Research.

[131]  Y. Cohen,et al.  Strong, Light, Multifunctional Fibers of Carbon Nanotubes with Ultrahigh Conductivity , 2013, Science.

[132]  Edward Ghali,et al.  Electrocatalysis developments for hydrogen evolution reaction in alkaline solutions – A Review , 2015 .

[133]  Hong‐Jie Peng,et al.  A review of flexible lithium-sulfur and analogous alkali metal-chalcogen rechargeable batteries. , 2017, Chemical Society reviews.

[134]  Yongyao Xia,et al.  A Rechargeable Li-CO2 Battery with a Gel Polymer Electrolyte. , 2017, Angewandte Chemie.

[135]  Bin Li,et al.  3D Printing Sulfur Copolymer‐Graphene Architectures for Li‐S Batteries , 2018 .

[136]  Yi Cui,et al.  The path towards sustainable energy. , 2016, Nature materials.

[137]  Di Zhang,et al.  Architectured Leaf‐Inspired Ni0.33Co0.66S2/Graphene Aerogels via 3D Printing for High‐Performance Energy Storage , 2018, Advanced Functional Materials.

[138]  A. Polman,et al.  Photovoltaic materials: Present efficiencies and future challenges , 2016, Science.

[139]  BenedettiTânia Machado,et al.  3D Printed Electrodes for Improved Gas Reactant Transport for Electrochemical Reactions , 2018 .

[140]  Xu Xu,et al.  Arbitrary Shape Engineerable Spiral Micropseudocapacitors with Ultrahigh Energy and Power Densities , 2015, Advanced materials.

[141]  M. Winter,et al.  Before Li Ion Batteries. , 2018, Chemical reviews.

[142]  Nasir Mahmood,et al.  Graphene-based nanocomposites for energy storage and conversion in lithium batteries, supercapacitors and fuel cells , 2014 .

[143]  Barry Berman,et al.  3D printing: the new industrial revolution , 2012, IEEE Engineering Management Review.

[144]  Guangyuan Zheng,et al.  Rechargeable Li–O2 batteries with a covalently coupled MnCo2O4–graphene hybrid as an oxygen cathode catalyst , 2012 .

[145]  M. Pumera,et al.  Self‐Contained Polymer/Metal 3D Printed Electrochemical Platform for Tailored Water Splitting , 2018 .

[146]  L. Wan,et al.  Revealing the Surface Effect of the Soluble Catalyst on Oxygen Reduction/Evolution in Li-O2 Batteries. , 2019, Journal of the American Chemical Society.

[147]  Howon Lee,et al.  Ultralight, ultrastiff mechanical metamaterials , 2014, Science.

[148]  M. Mehrali,et al.  A review on powder-based additive manufacturing for tissue engineering: selective laser sintering and inkjet 3D printing , 2015, Science and technology of advanced materials.

[149]  E. O. Olakanmi,et al.  A review on selective laser sintering/melting (SLS/SLM) of aluminium alloy powders: Processing, microstructure, and properties , 2015 .

[150]  David W. Rosen,et al.  Design for Additive Manufacturing of Cellular Structures , 2008 .

[151]  B. Dunn,et al.  Design and Mechanisms of Asymmetric Supercapacitors. , 2018, Chemical reviews.

[152]  Chang‐jun Liu,et al.  Three‐dimensional Printing for Catalytic Applications: Current Status and Perspectives , 2017 .

[153]  Chunzhen Yang,et al.  Determining the Facile Routes for Oxygen Evolution Reaction by In Situ Probing of Li-O2 Cells with Conformal Li2O2 Films. , 2018, Journal of the American Chemical Society.

[154]  Yang Zhao,et al.  A 3D-printed ultra-high Se loading cathode for high energy density quasi-solid-state Li–Se batteries , 2020 .

[155]  Jingyan Dong,et al.  Hybrid hierarchical fabrication of three-dimensional scaffolds , 2014 .

[156]  Bruno Scrosati,et al.  A sodium-ion battery exploiting layered oxide cathode, graphite anode and glyme-based electrolyte , 2016 .

[157]  MironovVladimir,et al.  Direct laser writing , 2015 .

[158]  Rashid K. Abu Al-Rub,et al.  Mechanical properties of 3D printed polymeric Gyroid cellular structures: Experimental and finite element study , 2019, Materials & Design.

[159]  Young Hee Lee,et al.  Enhanced electric double layer capacitance of graphite oxide intercalated by poly(sodium 4-styrensulfonate) with high cycle stability. , 2010, ACS nano.

[160]  Jun Lu,et al.  Metal–Air Batteries: Will They Be the Future Electrochemical Energy Storage Device of Choice? , 2017 .

[161]  H. Xia,et al.  Dual support ensuring high-energy supercapacitors via high-performance NiCo2S4@Fe2O3 anode and working potential enlarged MnO2 cathode , 2017 .

[162]  P. Yoo,et al.  Structurally Controlled Cellular Architectures for High‐Performance Ultra‐Lightweight Materials , 2018, Advanced materials.

[163]  F. Walsh,et al.  A Review of the Iron–Air Secondary Battery for Energy Storage , 2015 .

[164]  Kyeongjae Cho,et al.  2D MoS2 as an efficient protective layer for lithium metal anodes in high-performance Li–S batteries , 2018, Nature Nanotechnology.

[165]  Chee Kai Chua,et al.  Emerging 3D‐Printed Electrochemical Energy Storage Devices: A Critical Review , 2017 .

[166]  J. Lewis,et al.  3D Printing of Customized Li‐Ion Batteries with Thick Electrodes , 2018, Advanced materials.