论文信息 - Homogeneous nucleation, growth and recrystallization of discharge products on electrodes

Homogeneous nucleation, growth and recrystallization of discharge products on electrodes

Abstract The early state of discharge of electrodes with an electrodissolution/precipitation mechanism is investigated. A theory is proposed for quasi-classical homogeneous nucleation and the subsequent growth. Based on this theory the radii distribution function was calculated for the diffusion-controlled growth of crystallites. Recrystallization was included. The nucleation overpotential was calculated as a function of time for discharges under various conditions.

W. Kappus | W. Kappus

[1] W. Kappus. Dependence of ion concentration on growth of crystallites formed during discharge of an idealized electrode , 1980 .

[2] V. S. Bagotzky. Power sources 7 : Edited by J. Thompson, published by Academic Press, London, 1979, 774 pp., £65.00 or $134.50. , 1980 .